Fabrication of surface-relief gratings on an azobenzene-containing epoxy-based polymer film using atomic force microscopy

Autores
Fernández, Raquel; Zalakain, Iñaki; Ramos, José Angel; Galante, Maria Jose; Oyanguren, Patricia Angelica; Mondragon, Iñaki
Año de publicación
2010
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Many studies have been reported on the photo-fabrication of surface-relief gratings (SRGs) in azo-polymer films using the interference of two laser beams of appropriate polarization. However, there are few reports in the literature concerning the electro-fabrication of SRGs on such types of polymer films. The goal of the work reported was the electro-patterning of an azobenzene-containing epoxy thermoplastic film. An epoxy-based polymer functionalized with an azo-chromophore was synthesized and characterized using thermal analysis. The reversible optical storage properties and photo-induced dichroism were studied. SRGs were fabricated on a film of the synthesized azobenzene-containing polymer using contact mode current-sensing atomic force microscopy which locally applied an electric field that aligned the azobenzene moieties. The anisotropic mass transport of the azo-polymer film was observed after applying an electric field. Additionally, the effect of the relief formation in the polymeric film surface was investigated by means of atomic force microscopy and electrostatic force microscopy. © 2010 Society of Chemical Industry.
Fil: Fernández, Raquel. Universidad del País Vasco; España
Fil: Zalakain, Iñaki. Universidad del País Vasco; España
Fil: Ramos, José Angel. Universidad del País Vasco; España
Fil: Galante, Maria Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Oyanguren, Patricia Angelica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Mondragon, Iñaki. Universidad del País Vasco; España
Materia
Atomic Force Microscopy
Azo-Polymer
Birefringence
Dichroism
Epoxy
Surface Relief Gratings
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/62413
Acceder
id CONICETDig_e2a9b52e3a874e50d2b741a10d41887b
oai_identifier_str oai:ri.conicet.gov.ar:11336/62413
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Fabrication of surface-relief gratings on an azobenzene-containing epoxy-based polymer film using atomic force microscopyFernández, RaquelZalakain, IñakiRamos, José AngelGalante, Maria JoseOyanguren, Patricia AngelicaMondragon, IñakiAtomic Force MicroscopyAzo-PolymerBirefringenceDichroismEpoxySurface Relief Gratingshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Many studies have been reported on the photo-fabrication of surface-relief gratings (SRGs) in azo-polymer films using the interference of two laser beams of appropriate polarization. However, there are few reports in the literature concerning the electro-fabrication of SRGs on such types of polymer films. The goal of the work reported was the electro-patterning of an azobenzene-containing epoxy thermoplastic film. An epoxy-based polymer functionalized with an azo-chromophore was synthesized and characterized using thermal analysis. The reversible optical storage properties and photo-induced dichroism were studied. SRGs were fabricated on a film of the synthesized azobenzene-containing polymer using contact mode current-sensing atomic force microscopy which locally applied an electric field that aligned the azobenzene moieties. The anisotropic mass transport of the azo-polymer film was observed after applying an electric field. Additionally, the effect of the relief formation in the polymeric film surface was investigated by means of atomic force microscopy and electrostatic force microscopy. © 2010 Society of Chemical Industry.Fil: Fernández, Raquel. Universidad del País Vasco; EspañaFil: Zalakain, Iñaki. Universidad del País Vasco; EspañaFil: Ramos, José Angel. Universidad del País Vasco; EspañaFil: Galante, Maria Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Oyanguren, Patricia Angelica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Mondragon, Iñaki. Universidad del País Vasco; EspañaJohn Wiley & Sons Ltd2010-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/62413Fernández, Raquel; Zalakain, Iñaki; Ramos, José Angel; Galante, Maria Jose; Oyanguren, Patricia Angelica; et al.; Fabrication of surface-relief gratings on an azobenzene-containing epoxy-based polymer film using atomic force microscopy; John Wiley & Sons Ltd; Polymer International; 59; 10; 10-2010; 1422-14270959-8103CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1002/pi.2885info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/full/10.1002/pi.2885info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:08:42Zoai:ri.conicet.gov.ar:11336/62413instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:08:42.71CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Fabrication of surface-relief gratings on an azobenzene-containing epoxy-based polymer film using atomic force microscopy
title Fabrication of surface-relief gratings on an azobenzene-containing epoxy-based polymer film using atomic force microscopy
spellingShingle Fabrication of surface-relief gratings on an azobenzene-containing epoxy-based polymer film using atomic force microscopy
Fernández, Raquel
Atomic Force Microscopy
Azo-Polymer
Birefringence
Dichroism
Epoxy
Surface Relief Gratings
title_short Fabrication of surface-relief gratings on an azobenzene-containing epoxy-based polymer film using atomic force microscopy
title_full Fabrication of surface-relief gratings on an azobenzene-containing epoxy-based polymer film using atomic force microscopy
title_fullStr Fabrication of surface-relief gratings on an azobenzene-containing epoxy-based polymer film using atomic force microscopy
title_full_unstemmed Fabrication of surface-relief gratings on an azobenzene-containing epoxy-based polymer film using atomic force microscopy
title_sort Fabrication of surface-relief gratings on an azobenzene-containing epoxy-based polymer film using atomic force microscopy
dc.creator.none.fl_str_mv Fernández, Raquel
Zalakain, Iñaki
Ramos, José Angel
Galante, Maria Jose
Oyanguren, Patricia Angelica
Mondragon, Iñaki
author Fernández, Raquel
author_facet Fernández, Raquel
Zalakain, Iñaki
Ramos, José Angel
Galante, Maria Jose
Oyanguren, Patricia Angelica
Mondragon, Iñaki
author_role author
author2 Zalakain, Iñaki
Ramos, José Angel
Galante, Maria Jose
Oyanguren, Patricia Angelica
Mondragon, Iñaki
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Atomic Force Microscopy
Azo-Polymer
Birefringence
Dichroism
Epoxy
Surface Relief Gratings
topic Atomic Force Microscopy
Azo-Polymer
Birefringence
Dichroism
Epoxy
Surface Relief Gratings
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Many studies have been reported on the photo-fabrication of surface-relief gratings (SRGs) in azo-polymer films using the interference of two laser beams of appropriate polarization. However, there are few reports in the literature concerning the electro-fabrication of SRGs on such types of polymer films. The goal of the work reported was the electro-patterning of an azobenzene-containing epoxy thermoplastic film. An epoxy-based polymer functionalized with an azo-chromophore was synthesized and characterized using thermal analysis. The reversible optical storage properties and photo-induced dichroism were studied. SRGs were fabricated on a film of the synthesized azobenzene-containing polymer using contact mode current-sensing atomic force microscopy which locally applied an electric field that aligned the azobenzene moieties. The anisotropic mass transport of the azo-polymer film was observed after applying an electric field. Additionally, the effect of the relief formation in the polymeric film surface was investigated by means of atomic force microscopy and electrostatic force microscopy. © 2010 Society of Chemical Industry.
Fil: Fernández, Raquel. Universidad del País Vasco; España
Fil: Zalakain, Iñaki. Universidad del País Vasco; España
Fil: Ramos, José Angel. Universidad del País Vasco; España
Fil: Galante, Maria Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Oyanguren, Patricia Angelica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Mondragon, Iñaki. Universidad del País Vasco; España
description Many studies have been reported on the photo-fabrication of surface-relief gratings (SRGs) in azo-polymer films using the interference of two laser beams of appropriate polarization. However, there are few reports in the literature concerning the electro-fabrication of SRGs on such types of polymer films. The goal of the work reported was the electro-patterning of an azobenzene-containing epoxy thermoplastic film. An epoxy-based polymer functionalized with an azo-chromophore was synthesized and characterized using thermal analysis. The reversible optical storage properties and photo-induced dichroism were studied. SRGs were fabricated on a film of the synthesized azobenzene-containing polymer using contact mode current-sensing atomic force microscopy which locally applied an electric field that aligned the azobenzene moieties. The anisotropic mass transport of the azo-polymer film was observed after applying an electric field. Additionally, the effect of the relief formation in the polymeric film surface was investigated by means of atomic force microscopy and electrostatic force microscopy. © 2010 Society of Chemical Industry.
publishDate 2010
dc.date.none.fl_str_mv 2010-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/62413
Fernández, Raquel; Zalakain, Iñaki; Ramos, José Angel; Galante, Maria Jose; Oyanguren, Patricia Angelica; et al.; Fabrication of surface-relief gratings on an azobenzene-containing epoxy-based polymer film using atomic force microscopy; John Wiley & Sons Ltd; Polymer International; 59; 10; 10-2010; 1422-1427
0959-8103
CONICET Digital
CONICET
url http://hdl.handle.net/11336/62413
identifier_str_mv Fernández, Raquel; Zalakain, Iñaki; Ramos, José Angel; Galante, Maria Jose; Oyanguren, Patricia Angelica; et al.; Fabrication of surface-relief gratings on an azobenzene-containing epoxy-based polymer film using atomic force microscopy; John Wiley & Sons Ltd; Polymer International; 59; 10; 10-2010; 1422-1427
0959-8103
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1002/pi.2885
info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/full/10.1002/pi.2885
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv John Wiley & Sons Ltd
publisher.none.fl_str_mv John Wiley & Sons Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1842270055691190272
score 13.13397

Publicaciones similares