Polyurethane-epoxy based azopolymers: Influence of chemical structure over photoinduced birefringence

Autores
Sáiz, Luciana María; Oyanguren, Patricia Angelica; Galante, Maria Jose
Año de publicación
2012
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A comparative study of the influence of the competitive reactions that can take place in epoxy-isocyanate based azo systems over optical behavior was developed. Diverse disperse red 19 (DR 19) azo urethane oligomers (PUs) were synthesized and characterized using size exclusion chromatography (SEC), Fourier transform infrared (FTIR), and UV-visible spectroscopy. Based on these urethane oligomers, epoxy-PU networks having isocyanurate and oxazolidone rings in their structures were prepared in different isocyanate/epoxy stoichiometric ratios, r = eq. NCO/eq. epoxy (0.5, 1, and 2). Photoinduced anisotropy, remnant birefringence and dichroism were measured for the resulting polymers and evaluated as function of their Tgs and chemical structures. Final materials exhibited very high values of maximum birefringence and RB being promised materials for using in optical storage information devices.
Fil: Sáiz, Luciana María. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Oyanguren, Patricia Angelica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Galante, Maria Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Materia
Polyurethane
Epoxy
Azopolymer
Optical Birefringence
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/43892
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Polyurethane-epoxy based azopolymers: Influence of chemical structure over photoinduced birefringenceSáiz, Luciana MaríaOyanguren, Patricia AngelicaGalante, Maria JosePolyurethaneEpoxyAzopolymerOptical Birefringencehttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2A comparative study of the influence of the competitive reactions that can take place in epoxy-isocyanate based azo systems over optical behavior was developed. Diverse disperse red 19 (DR 19) azo urethane oligomers (PUs) were synthesized and characterized using size exclusion chromatography (SEC), Fourier transform infrared (FTIR), and UV-visible spectroscopy. Based on these urethane oligomers, epoxy-PU networks having isocyanurate and oxazolidone rings in their structures were prepared in different isocyanate/epoxy stoichiometric ratios, r = eq. NCO/eq. epoxy (0.5, 1, and 2). Photoinduced anisotropy, remnant birefringence and dichroism were measured for the resulting polymers and evaluated as function of their Tgs and chemical structures. Final materials exhibited very high values of maximum birefringence and RB being promised materials for using in optical storage information devices.Fil: Sáiz, Luciana María. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Oyanguren, Patricia Angelica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Galante, Maria Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaElsevier Science2012-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/43892Sáiz, Luciana María; Oyanguren, Patricia Angelica; Galante, Maria Jose; Polyurethane-epoxy based azopolymers: Influence of chemical structure over photoinduced birefringence; Elsevier Science; Reactive & Functional Polymers; 72; 7-2012; 478-4851381-5148CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.reactfunctpolym.2012.04.010info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S1381514812001216info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:08:28Zoai:ri.conicet.gov.ar:11336/43892instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:08:28.4CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Polyurethane-epoxy based azopolymers: Influence of chemical structure over photoinduced birefringence
title Polyurethane-epoxy based azopolymers: Influence of chemical structure over photoinduced birefringence
spellingShingle Polyurethane-epoxy based azopolymers: Influence of chemical structure over photoinduced birefringence
Sáiz, Luciana María
Polyurethane
Epoxy
Azopolymer
Optical Birefringence
title_short Polyurethane-epoxy based azopolymers: Influence of chemical structure over photoinduced birefringence
title_full Polyurethane-epoxy based azopolymers: Influence of chemical structure over photoinduced birefringence
title_fullStr Polyurethane-epoxy based azopolymers: Influence of chemical structure over photoinduced birefringence
title_full_unstemmed Polyurethane-epoxy based azopolymers: Influence of chemical structure over photoinduced birefringence
title_sort Polyurethane-epoxy based azopolymers: Influence of chemical structure over photoinduced birefringence
dc.creator.none.fl_str_mv Sáiz, Luciana María
Oyanguren, Patricia Angelica
Galante, Maria Jose
author Sáiz, Luciana María
author_facet Sáiz, Luciana María
Oyanguren, Patricia Angelica
Galante, Maria Jose
author_role author
author2 Oyanguren, Patricia Angelica
Galante, Maria Jose
author2_role author
author
dc.subject.none.fl_str_mv Polyurethane
Epoxy
Azopolymer
Optical Birefringence
topic Polyurethane
Epoxy
Azopolymer
Optical Birefringence
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv A comparative study of the influence of the competitive reactions that can take place in epoxy-isocyanate based azo systems over optical behavior was developed. Diverse disperse red 19 (DR 19) azo urethane oligomers (PUs) were synthesized and characterized using size exclusion chromatography (SEC), Fourier transform infrared (FTIR), and UV-visible spectroscopy. Based on these urethane oligomers, epoxy-PU networks having isocyanurate and oxazolidone rings in their structures were prepared in different isocyanate/epoxy stoichiometric ratios, r = eq. NCO/eq. epoxy (0.5, 1, and 2). Photoinduced anisotropy, remnant birefringence and dichroism were measured for the resulting polymers and evaluated as function of their Tgs and chemical structures. Final materials exhibited very high values of maximum birefringence and RB being promised materials for using in optical storage information devices.
Fil: Sáiz, Luciana María. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Oyanguren, Patricia Angelica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Galante, Maria Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
description A comparative study of the influence of the competitive reactions that can take place in epoxy-isocyanate based azo systems over optical behavior was developed. Diverse disperse red 19 (DR 19) azo urethane oligomers (PUs) were synthesized and characterized using size exclusion chromatography (SEC), Fourier transform infrared (FTIR), and UV-visible spectroscopy. Based on these urethane oligomers, epoxy-PU networks having isocyanurate and oxazolidone rings in their structures were prepared in different isocyanate/epoxy stoichiometric ratios, r = eq. NCO/eq. epoxy (0.5, 1, and 2). Photoinduced anisotropy, remnant birefringence and dichroism were measured for the resulting polymers and evaluated as function of their Tgs and chemical structures. Final materials exhibited very high values of maximum birefringence and RB being promised materials for using in optical storage information devices.
publishDate 2012
dc.date.none.fl_str_mv 2012-07
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/43892
Sáiz, Luciana María; Oyanguren, Patricia Angelica; Galante, Maria Jose; Polyurethane-epoxy based azopolymers: Influence of chemical structure over photoinduced birefringence; Elsevier Science; Reactive & Functional Polymers; 72; 7-2012; 478-485
1381-5148
CONICET Digital
CONICET
url http://hdl.handle.net/11336/43892
identifier_str_mv Sáiz, Luciana María; Oyanguren, Patricia Angelica; Galante, Maria Jose; Polyurethane-epoxy based azopolymers: Influence of chemical structure over photoinduced birefringence; Elsevier Science; Reactive & Functional Polymers; 72; 7-2012; 478-485
1381-5148
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.reactfunctpolym.2012.04.010
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S1381514812001216
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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