Criteria for the selection of the scan rate in the evaluation of the kinetic parameters of the hydrogen oxidation reaction by a potentiodynamic sweep

Autores
Marozzi, Carlos Alberto; Gennero, Maria Rosa; Chialvo, Abel Cesar
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The use of the current density values obtained from a voltammetric sweep at a slow scan rate jvs(η) in place of those of a steady state polarization jss(η) for the determination of the kinetic parameters of the hydrogen oxidation reaction (hor) on a rotating disc electrode was analyzed. Three sets of kinetic parameters similar to those evaluated previously for the noble metals Pt, Ir and Rh, used as electrocatalysts for this reaction, at three different rotation rates (100, 3600 and 10000 rpm) and four different scan rates (10-4, 10-3, 10-2 and 5  10-2 V s-1) were selected for this study. The determination of the hydrogen electrode reaction (HER) polarization resistance, around the equilibrium condition, was also investigated. Finally, the conditions in which the approximation jvs(η) = jss(η) can be considered valid were established for both, the polarization plot and the polarization resistance and practical criteria were established.
Fil: Marozzi, Carlos Alberto. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
Fil: Gennero, Maria Rosa. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
Fil: Chialvo, Abel Cesar. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
Materia
Hydrogen Oxidation Reaction
Voltammetric Sweep Criteria
Kinetic Parameters
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/44044
Acceder
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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Criteria for the selection of the scan rate in the evaluation of the kinetic parameters of the hydrogen oxidation reaction by a potentiodynamic sweepMarozzi, Carlos AlbertoGennero, Maria RosaChialvo, Abel CesarHydrogen Oxidation ReactionVoltammetric Sweep CriteriaKinetic Parametershttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The use of the current density values obtained from a voltammetric sweep at a slow scan rate jvs(η) in place of those of a steady state polarization jss(η) for the determination of the kinetic parameters of the hydrogen oxidation reaction (hor) on a rotating disc electrode was analyzed. Three sets of kinetic parameters similar to those evaluated previously for the noble metals Pt, Ir and Rh, used as electrocatalysts for this reaction, at three different rotation rates (100, 3600 and 10000 rpm) and four different scan rates (10-4, 10-3, 10-2 and 5  10-2 V s-1) were selected for this study. The determination of the hydrogen electrode reaction (HER) polarization resistance, around the equilibrium condition, was also investigated. Finally, the conditions in which the approximation jvs(η) = jss(η) can be considered valid were established for both, the polarization plot and the polarization resistance and practical criteria were established.Fil: Marozzi, Carlos Alberto. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; ArgentinaFil: Gennero, Maria Rosa. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; ArgentinaFil: Chialvo, Abel Cesar. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; ArgentinaElsevier Science Sa2015-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/44044Marozzi, Carlos Alberto; Gennero, Maria Rosa; Chialvo, Abel Cesar; Criteria for the selection of the scan rate in the evaluation of the kinetic parameters of the hydrogen oxidation reaction by a potentiodynamic sweep; Elsevier Science Sa; Journal of Electroanalytical Chemistry; 748; 7-2015; 61-691572-6657CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.jelechem.2015.04.012info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S1572665715001836info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:01:07Zoai:ri.conicet.gov.ar:11336/44044instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:01:07.869CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Criteria for the selection of the scan rate in the evaluation of the kinetic parameters of the hydrogen oxidation reaction by a potentiodynamic sweep
title Criteria for the selection of the scan rate in the evaluation of the kinetic parameters of the hydrogen oxidation reaction by a potentiodynamic sweep
spellingShingle Criteria for the selection of the scan rate in the evaluation of the kinetic parameters of the hydrogen oxidation reaction by a potentiodynamic sweep
Marozzi, Carlos Alberto
Hydrogen Oxidation Reaction
Voltammetric Sweep Criteria
Kinetic Parameters
title_short Criteria for the selection of the scan rate in the evaluation of the kinetic parameters of the hydrogen oxidation reaction by a potentiodynamic sweep
title_full Criteria for the selection of the scan rate in the evaluation of the kinetic parameters of the hydrogen oxidation reaction by a potentiodynamic sweep
title_fullStr Criteria for the selection of the scan rate in the evaluation of the kinetic parameters of the hydrogen oxidation reaction by a potentiodynamic sweep
title_full_unstemmed Criteria for the selection of the scan rate in the evaluation of the kinetic parameters of the hydrogen oxidation reaction by a potentiodynamic sweep
title_sort Criteria for the selection of the scan rate in the evaluation of the kinetic parameters of the hydrogen oxidation reaction by a potentiodynamic sweep
dc.creator.none.fl_str_mv Marozzi, Carlos Alberto
Gennero, Maria Rosa
Chialvo, Abel Cesar
author Marozzi, Carlos Alberto
author_facet Marozzi, Carlos Alberto
Gennero, Maria Rosa
Chialvo, Abel Cesar
author_role author
author2 Gennero, Maria Rosa
Chialvo, Abel Cesar
author2_role author
author
dc.subject.none.fl_str_mv Hydrogen Oxidation Reaction
Voltammetric Sweep Criteria
Kinetic Parameters
topic Hydrogen Oxidation Reaction
Voltammetric Sweep Criteria
Kinetic Parameters
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The use of the current density values obtained from a voltammetric sweep at a slow scan rate jvs(η) in place of those of a steady state polarization jss(η) for the determination of the kinetic parameters of the hydrogen oxidation reaction (hor) on a rotating disc electrode was analyzed. Three sets of kinetic parameters similar to those evaluated previously for the noble metals Pt, Ir and Rh, used as electrocatalysts for this reaction, at three different rotation rates (100, 3600 and 10000 rpm) and four different scan rates (10-4, 10-3, 10-2 and 5  10-2 V s-1) were selected for this study. The determination of the hydrogen electrode reaction (HER) polarization resistance, around the equilibrium condition, was also investigated. Finally, the conditions in which the approximation jvs(η) = jss(η) can be considered valid were established for both, the polarization plot and the polarization resistance and practical criteria were established.
Fil: Marozzi, Carlos Alberto. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
Fil: Gennero, Maria Rosa. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
Fil: Chialvo, Abel Cesar. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
description The use of the current density values obtained from a voltammetric sweep at a slow scan rate jvs(η) in place of those of a steady state polarization jss(η) for the determination of the kinetic parameters of the hydrogen oxidation reaction (hor) on a rotating disc electrode was analyzed. Three sets of kinetic parameters similar to those evaluated previously for the noble metals Pt, Ir and Rh, used as electrocatalysts for this reaction, at three different rotation rates (100, 3600 and 10000 rpm) and four different scan rates (10-4, 10-3, 10-2 and 5  10-2 V s-1) were selected for this study. The determination of the hydrogen electrode reaction (HER) polarization resistance, around the equilibrium condition, was also investigated. Finally, the conditions in which the approximation jvs(η) = jss(η) can be considered valid were established for both, the polarization plot and the polarization resistance and practical criteria were established.
publishDate 2015
dc.date.none.fl_str_mv 2015-07
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/44044
Marozzi, Carlos Alberto; Gennero, Maria Rosa; Chialvo, Abel Cesar; Criteria for the selection of the scan rate in the evaluation of the kinetic parameters of the hydrogen oxidation reaction by a potentiodynamic sweep; Elsevier Science Sa; Journal of Electroanalytical Chemistry; 748; 7-2015; 61-69
1572-6657
CONICET Digital
CONICET
url http://hdl.handle.net/11336/44044
identifier_str_mv Marozzi, Carlos Alberto; Gennero, Maria Rosa; Chialvo, Abel Cesar; Criteria for the selection of the scan rate in the evaluation of the kinetic parameters of the hydrogen oxidation reaction by a potentiodynamic sweep; Elsevier Science Sa; Journal of Electroanalytical Chemistry; 748; 7-2015; 61-69
1572-6657
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jelechem.2015.04.012
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S1572665715001836
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science Sa
publisher.none.fl_str_mv Elsevier Science Sa
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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