Kinetic Study of the Hydrogen Oxidation Reaction on Membrane Coated Electrodes. Part I: Theoretical Aspects

Autores
Marozzi, Carlos Alberto; Gennero, Maria Rosa; Chialvo, Abel Cesar
Año de publicación
2009
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A generalized theoretical analysis of the kinetics of the hydrogen oxidation reaction under the Volmer-Heyrovsky-Tafel mechanism on an electrode covered by polymeric films is presented. The treatment includes the diffusion of the molecular hydrogen through the electrolyte solution, as well as through the different layers and interfaces. On the light of the resulting expressions, the applicability of the Levich-Koutecky diagrams for the determination of the kinetic current densities was critically analyzed.
Fil: Marozzi, Carlos Alberto. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; Argentina
Fil: Gennero, Maria Rosa. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; Argentina
Fil: Chialvo, Abel Cesar. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; Argentina
Materia
HYDROGEN OXIDATION
MEMBRANE COATED ELECTRODE
KINETIC TREATMENT
LEVICH-KOUTECKY DIAGRAM
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/103897
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/103897
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Kinetic Study of the Hydrogen Oxidation Reaction on Membrane Coated Electrodes. Part I: Theoretical AspectsMarozzi, Carlos AlbertoGennero, Maria RosaChialvo, Abel CesarHYDROGEN OXIDATIONMEMBRANE COATED ELECTRODEKINETIC TREATMENTLEVICH-KOUTECKY DIAGRAMhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A generalized theoretical analysis of the kinetics of the hydrogen oxidation reaction under the Volmer-Heyrovsky-Tafel mechanism on an electrode covered by polymeric films is presented. The treatment includes the diffusion of the molecular hydrogen through the electrolyte solution, as well as through the different layers and interfaces. On the light of the resulting expressions, the applicability of the Levich-Koutecky diagrams for the determination of the kinetic current densities was critically analyzed.Fil: Marozzi, Carlos Alberto. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; ArgentinaFil: Gennero, Maria Rosa. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; ArgentinaFil: Chialvo, Abel Cesar. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; ArgentinaBentham Science Publishers2009-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/103897Marozzi, Carlos Alberto; Gennero, Maria Rosa; Chialvo, Abel Cesar; Kinetic Study of the Hydrogen Oxidation Reaction on Membrane Coated Electrodes. Part I: Theoretical Aspects; Bentham Science Publishers; The Open Electrochemistry Journal; 1; 9-2009; 49-551876-505XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://www.benthamscience.com/open/toelecj/info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:54:15Zoai:ri.conicet.gov.ar:11336/103897instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:54:15.372CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Kinetic Study of the Hydrogen Oxidation Reaction on Membrane Coated Electrodes. Part I: Theoretical Aspects
title Kinetic Study of the Hydrogen Oxidation Reaction on Membrane Coated Electrodes. Part I: Theoretical Aspects
spellingShingle Kinetic Study of the Hydrogen Oxidation Reaction on Membrane Coated Electrodes. Part I: Theoretical Aspects
Marozzi, Carlos Alberto
HYDROGEN OXIDATION
MEMBRANE COATED ELECTRODE
KINETIC TREATMENT
LEVICH-KOUTECKY DIAGRAM
title_short Kinetic Study of the Hydrogen Oxidation Reaction on Membrane Coated Electrodes. Part I: Theoretical Aspects
title_full Kinetic Study of the Hydrogen Oxidation Reaction on Membrane Coated Electrodes. Part I: Theoretical Aspects
title_fullStr Kinetic Study of the Hydrogen Oxidation Reaction on Membrane Coated Electrodes. Part I: Theoretical Aspects
title_full_unstemmed Kinetic Study of the Hydrogen Oxidation Reaction on Membrane Coated Electrodes. Part I: Theoretical Aspects
title_sort Kinetic Study of the Hydrogen Oxidation Reaction on Membrane Coated Electrodes. Part I: Theoretical Aspects
dc.creator.none.fl_str_mv Marozzi, Carlos Alberto
Gennero, Maria Rosa
Chialvo, Abel Cesar
author Marozzi, Carlos Alberto
author_facet Marozzi, Carlos Alberto
Gennero, Maria Rosa
Chialvo, Abel Cesar
author_role author
author2 Gennero, Maria Rosa
Chialvo, Abel Cesar
author2_role author
author
dc.subject.none.fl_str_mv HYDROGEN OXIDATION
MEMBRANE COATED ELECTRODE
KINETIC TREATMENT
LEVICH-KOUTECKY DIAGRAM
topic HYDROGEN OXIDATION
MEMBRANE COATED ELECTRODE
KINETIC TREATMENT
LEVICH-KOUTECKY DIAGRAM
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv A generalized theoretical analysis of the kinetics of the hydrogen oxidation reaction under the Volmer-Heyrovsky-Tafel mechanism on an electrode covered by polymeric films is presented. The treatment includes the diffusion of the molecular hydrogen through the electrolyte solution, as well as through the different layers and interfaces. On the light of the resulting expressions, the applicability of the Levich-Koutecky diagrams for the determination of the kinetic current densities was critically analyzed.
Fil: Marozzi, Carlos Alberto. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; Argentina
Fil: Gennero, Maria Rosa. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; Argentina
Fil: Chialvo, Abel Cesar. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; Argentina
description A generalized theoretical analysis of the kinetics of the hydrogen oxidation reaction under the Volmer-Heyrovsky-Tafel mechanism on an electrode covered by polymeric films is presented. The treatment includes the diffusion of the molecular hydrogen through the electrolyte solution, as well as through the different layers and interfaces. On the light of the resulting expressions, the applicability of the Levich-Koutecky diagrams for the determination of the kinetic current densities was critically analyzed.
publishDate 2009
dc.date.none.fl_str_mv 2009-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/103897
Marozzi, Carlos Alberto; Gennero, Maria Rosa; Chialvo, Abel Cesar; Kinetic Study of the Hydrogen Oxidation Reaction on Membrane Coated Electrodes. Part I: Theoretical Aspects; Bentham Science Publishers; The Open Electrochemistry Journal; 1; 9-2009; 49-55
1876-505X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/103897
identifier_str_mv Marozzi, Carlos Alberto; Gennero, Maria Rosa; Chialvo, Abel Cesar; Kinetic Study of the Hydrogen Oxidation Reaction on Membrane Coated Electrodes. Part I: Theoretical Aspects; Bentham Science Publishers; The Open Electrochemistry Journal; 1; 9-2009; 49-55
1876-505X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.benthamscience.com/open/toelecj/
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Bentham Science Publishers
publisher.none.fl_str_mv Bentham Science Publishers
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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