Effect of topology on the adhesive forces between electrospun polymer fibers studied using a T-peel test

Autores
Montini Ballarin, Florencia; Blackledge, Todd A.; Capitos Davis, Nicole L.; Frontini, Patricia Maria; Abraham, Gustavo Abel; Wong, Shing Chung
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Electrospinning provides an effective methodology to obtain high aspect ratio polymer fibers for biomimetic applications. In this article, we evaluate the effect of topology on adhesion between aligned fibers. Polycaprolactone is electrospun using two different setups: (i) a tip collector and (ii) a flat collector. The tip collector enables the fibers to self-align. When a fiber reaches the tip collector, the next fiber is repelled by the charge they carry, forcing the fibers to deposit in a parallel arrangement. The flat collector allows the fibers to deposit at random. The adhesion between the fiber mats is measured using a T-peel test. Adhesion strength (758.7 ± 211.7 kPa) changes marginally with the peeling rate and applied pressure on the membranes. Aligned fibers exhibit higher adhesion strength between the membranes in comparison to randomly oriented nonwovens (613.1 ± 79.9 kPa). The estimated Johnson–Kendall–Roberts contact energy (83.1 ± 32.5 mJ/m2) is consistent with the range of van der Waals adhesion forces. This work shows how the adhesion between two polymer membranes can be modulated by surface topology, based on a T-peel testing setup.
Fil: Montini Ballarin, Florencia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina
Fil: Blackledge, Todd A.. The University Of Akron (uoa);
Fil: Capitos Davis, Nicole L.. Center for Research and Technology; Estados Unidos
Fil: Frontini, Patricia Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina
Fil: Abraham, Gustavo Abel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina
Fil: Wong, Shing Chung. The University Of Akron (uoa);
Materia
Adhesion
Electrospinning
Nanofibers
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/2315
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/2315
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Effect of topology on the adhesive forces between electrospun polymer fibers studied using a T-peel testMontini Ballarin, FlorenciaBlackledge, Todd A.Capitos Davis, Nicole L.Frontini, Patricia MariaAbraham, Gustavo AbelWong, Shing ChungAdhesionElectrospinningNanofibershttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Electrospinning provides an effective methodology to obtain high aspect ratio polymer fibers for biomimetic applications. In this article, we evaluate the effect of topology on adhesion between aligned fibers. Polycaprolactone is electrospun using two different setups: (i) a tip collector and (ii) a flat collector. The tip collector enables the fibers to self-align. When a fiber reaches the tip collector, the next fiber is repelled by the charge they carry, forcing the fibers to deposit in a parallel arrangement. The flat collector allows the fibers to deposit at random. The adhesion between the fiber mats is measured using a T-peel test. Adhesion strength (758.7 ± 211.7 kPa) changes marginally with the peeling rate and applied pressure on the membranes. Aligned fibers exhibit higher adhesion strength between the membranes in comparison to randomly oriented nonwovens (613.1 ± 79.9 kPa). The estimated Johnson–Kendall–Roberts contact energy (83.1 ± 32.5 mJ/m2) is consistent with the range of van der Waals adhesion forces. This work shows how the adhesion between two polymer membranes can be modulated by surface topology, based on a T-peel testing setup.Fil: Montini Ballarin, Florencia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; ArgentinaFil: Blackledge, Todd A.. The University Of Akron (uoa);Fil: Capitos Davis, Nicole L.. Center for Research and Technology; Estados UnidosFil: Frontini, Patricia Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; ArgentinaFil: Abraham, Gustavo Abel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; ArgentinaFil: Wong, Shing Chung. The University Of Akron (uoa);John Wiley & Sons2013-03-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/2315Montini Ballarin, Florencia; Blackledge, Todd A.; Capitos Davis, Nicole L.; Frontini, Patricia Maria; Abraham, Gustavo Abel; et al.; Effect of topology on the adhesive forces between electrospun polymer fibers studied using a T-peel test; John Wiley & Sons; Polymer Engineering and Science; 53; 10; 8-3-2013; 2219-22270032-3888enginfo:eu-repo/semantics/altIdentifier/doi/10.1002/pen.23474info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/pen.23474/abstractinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T15:13:02Zoai:ri.conicet.gov.ar:11336/2315instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 15:13:02.429CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Effect of topology on the adhesive forces between electrospun polymer fibers studied using a T-peel test
title Effect of topology on the adhesive forces between electrospun polymer fibers studied using a T-peel test
spellingShingle Effect of topology on the adhesive forces between electrospun polymer fibers studied using a T-peel test
Montini Ballarin, Florencia
Adhesion
Electrospinning
Nanofibers
title_short Effect of topology on the adhesive forces between electrospun polymer fibers studied using a T-peel test
title_full Effect of topology on the adhesive forces between electrospun polymer fibers studied using a T-peel test
title_fullStr Effect of topology on the adhesive forces between electrospun polymer fibers studied using a T-peel test
title_full_unstemmed Effect of topology on the adhesive forces between electrospun polymer fibers studied using a T-peel test
title_sort Effect of topology on the adhesive forces between electrospun polymer fibers studied using a T-peel test
dc.creator.none.fl_str_mv Montini Ballarin, Florencia
Blackledge, Todd A.
Capitos Davis, Nicole L.
Frontini, Patricia Maria
Abraham, Gustavo Abel
Wong, Shing Chung
author Montini Ballarin, Florencia
author_facet Montini Ballarin, Florencia
Blackledge, Todd A.
Capitos Davis, Nicole L.
Frontini, Patricia Maria
Abraham, Gustavo Abel
Wong, Shing Chung
author_role author
author2 Blackledge, Todd A.
Capitos Davis, Nicole L.
Frontini, Patricia Maria
Abraham, Gustavo Abel
Wong, Shing Chung
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Adhesion
Electrospinning
Nanofibers
topic Adhesion
Electrospinning
Nanofibers
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Electrospinning provides an effective methodology to obtain high aspect ratio polymer fibers for biomimetic applications. In this article, we evaluate the effect of topology on adhesion between aligned fibers. Polycaprolactone is electrospun using two different setups: (i) a tip collector and (ii) a flat collector. The tip collector enables the fibers to self-align. When a fiber reaches the tip collector, the next fiber is repelled by the charge they carry, forcing the fibers to deposit in a parallel arrangement. The flat collector allows the fibers to deposit at random. The adhesion between the fiber mats is measured using a T-peel test. Adhesion strength (758.7 ± 211.7 kPa) changes marginally with the peeling rate and applied pressure on the membranes. Aligned fibers exhibit higher adhesion strength between the membranes in comparison to randomly oriented nonwovens (613.1 ± 79.9 kPa). The estimated Johnson–Kendall–Roberts contact energy (83.1 ± 32.5 mJ/m2) is consistent with the range of van der Waals adhesion forces. This work shows how the adhesion between two polymer membranes can be modulated by surface topology, based on a T-peel testing setup.
Fil: Montini Ballarin, Florencia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina
Fil: Blackledge, Todd A.. The University Of Akron (uoa);
Fil: Capitos Davis, Nicole L.. Center for Research and Technology; Estados Unidos
Fil: Frontini, Patricia Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina
Fil: Abraham, Gustavo Abel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina
Fil: Wong, Shing Chung. The University Of Akron (uoa);
description Electrospinning provides an effective methodology to obtain high aspect ratio polymer fibers for biomimetic applications. In this article, we evaluate the effect of topology on adhesion between aligned fibers. Polycaprolactone is electrospun using two different setups: (i) a tip collector and (ii) a flat collector. The tip collector enables the fibers to self-align. When a fiber reaches the tip collector, the next fiber is repelled by the charge they carry, forcing the fibers to deposit in a parallel arrangement. The flat collector allows the fibers to deposit at random. The adhesion between the fiber mats is measured using a T-peel test. Adhesion strength (758.7 ± 211.7 kPa) changes marginally with the peeling rate and applied pressure on the membranes. Aligned fibers exhibit higher adhesion strength between the membranes in comparison to randomly oriented nonwovens (613.1 ± 79.9 kPa). The estimated Johnson–Kendall–Roberts contact energy (83.1 ± 32.5 mJ/m2) is consistent with the range of van der Waals adhesion forces. This work shows how the adhesion between two polymer membranes can be modulated by surface topology, based on a T-peel testing setup.
publishDate 2013
dc.date.none.fl_str_mv 2013-03-08
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/2315
Montini Ballarin, Florencia; Blackledge, Todd A.; Capitos Davis, Nicole L.; Frontini, Patricia Maria; Abraham, Gustavo Abel; et al.; Effect of topology on the adhesive forces between electrospun polymer fibers studied using a T-peel test; John Wiley & Sons; Polymer Engineering and Science; 53; 10; 8-3-2013; 2219-2227
0032-3888
url http://hdl.handle.net/11336/2315
identifier_str_mv Montini Ballarin, Florencia; Blackledge, Todd A.; Capitos Davis, Nicole L.; Frontini, Patricia Maria; Abraham, Gustavo Abel; et al.; Effect of topology on the adhesive forces between electrospun polymer fibers studied using a T-peel test; John Wiley & Sons; Polymer Engineering and Science; 53; 10; 8-3-2013; 2219-2227
0032-3888
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1002/pen.23474
info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/pen.23474/abstract
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv John Wiley & Sons
publisher.none.fl_str_mv John Wiley & Sons
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846083278607482880
score 13.22299

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