Pd based membrane reactor for ultra pure hydrogen production through the dry reforming of methane. Experimental and modeling studies

Autores
Coronel, Leandro; Múnera Agudelo, John Fernando; Lombardo, Eduardo Agustin; Cornaglia, Laura Maria
Año de publicación
2011
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A dense Pd-Ag membrane reactor (MR) with 100% hydrogen selectivity packed with either Rh/La2O3 or Rh/La2O 3-SiO2 as catalysts was used to carry out the dry reforming of methane. The membrane reactor simulation was performed using a well-known reactor model. For this purpose, we employed the equations derived from complete kinetic studies of the dry reforming of methane reaction in connection with both catalysts. In addition, we developed the kinetic equation for the reverse water gas shift reaction (RWGS). The combination of detailed kinetic studies with the measured permeation flux for the Pd-Ag membrane allowed a complete comparison between experimental and simulated operation variables. The variables studied for both catalysts were methane conversion and hydrogen permeation as a function of the sweep gas flow rate. The correlation between methane conversion enhancement and hydrogen recovery confirmed that a good prediction was obtained with this model. The performance of two reactor configurations (membrane reactor and conventional fixed-bed reactor) and both co-current and counter-current flow modes were compared. The effect of various operating variables such as permeation area, sweep gas flow rate and feed composition upon conversion, product compositions and hydrogen recovery were analyzed.
Fil: Coronel, Leandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Múnera Agudelo, John Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Lombardo, Eduardo Agustin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Cornaglia, Laura Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Materia
Kinetic Equations
Membrane Reactor
Rh Catalysts
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/73490
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/73490
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Pd based membrane reactor for ultra pure hydrogen production through the dry reforming of methane. Experimental and modeling studiesCoronel, LeandroMúnera Agudelo, John FernandoLombardo, Eduardo AgustinCornaglia, Laura MariaKinetic EquationsMembrane ReactorRh Catalystshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A dense Pd-Ag membrane reactor (MR) with 100% hydrogen selectivity packed with either Rh/La2O3 or Rh/La2O 3-SiO2 as catalysts was used to carry out the dry reforming of methane. The membrane reactor simulation was performed using a well-known reactor model. For this purpose, we employed the equations derived from complete kinetic studies of the dry reforming of methane reaction in connection with both catalysts. In addition, we developed the kinetic equation for the reverse water gas shift reaction (RWGS). The combination of detailed kinetic studies with the measured permeation flux for the Pd-Ag membrane allowed a complete comparison between experimental and simulated operation variables. The variables studied for both catalysts were methane conversion and hydrogen permeation as a function of the sweep gas flow rate. The correlation between methane conversion enhancement and hydrogen recovery confirmed that a good prediction was obtained with this model. The performance of two reactor configurations (membrane reactor and conventional fixed-bed reactor) and both co-current and counter-current flow modes were compared. The effect of various operating variables such as permeation area, sweep gas flow rate and feed composition upon conversion, product compositions and hydrogen recovery were analyzed.Fil: Coronel, Leandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Múnera Agudelo, John Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Lombardo, Eduardo Agustin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Cornaglia, Laura Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaElsevier Science2011-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/73490Coronel, Leandro; Múnera Agudelo, John Fernando; Lombardo, Eduardo Agustin; Cornaglia, Laura Maria; Pd based membrane reactor for ultra pure hydrogen production through the dry reforming of methane. Experimental and modeling studies; Elsevier Science; Applied Catalysis A: General; 400; 1-2; 6-2011; 185-1940926-860XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2011.04.030info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0926860X11002493info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:13:28Zoai:ri.conicet.gov.ar:11336/73490instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:13:28.419CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Pd based membrane reactor for ultra pure hydrogen production through the dry reforming of methane. Experimental and modeling studies
title Pd based membrane reactor for ultra pure hydrogen production through the dry reforming of methane. Experimental and modeling studies
spellingShingle Pd based membrane reactor for ultra pure hydrogen production through the dry reforming of methane. Experimental and modeling studies
Coronel, Leandro
Kinetic Equations
Membrane Reactor
Rh Catalysts
title_short Pd based membrane reactor for ultra pure hydrogen production through the dry reforming of methane. Experimental and modeling studies
title_full Pd based membrane reactor for ultra pure hydrogen production through the dry reforming of methane. Experimental and modeling studies
title_fullStr Pd based membrane reactor for ultra pure hydrogen production through the dry reforming of methane. Experimental and modeling studies
title_full_unstemmed Pd based membrane reactor for ultra pure hydrogen production through the dry reforming of methane. Experimental and modeling studies
title_sort Pd based membrane reactor for ultra pure hydrogen production through the dry reforming of methane. Experimental and modeling studies
dc.creator.none.fl_str_mv Coronel, Leandro
Múnera Agudelo, John Fernando
Lombardo, Eduardo Agustin
Cornaglia, Laura Maria
author Coronel, Leandro
author_facet Coronel, Leandro
Múnera Agudelo, John Fernando
Lombardo, Eduardo Agustin
Cornaglia, Laura Maria
author_role author
author2 Múnera Agudelo, John Fernando
Lombardo, Eduardo Agustin
Cornaglia, Laura Maria
author2_role author
author
author
dc.subject.none.fl_str_mv Kinetic Equations
Membrane Reactor
Rh Catalysts
topic Kinetic Equations
Membrane Reactor
Rh Catalysts
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv A dense Pd-Ag membrane reactor (MR) with 100% hydrogen selectivity packed with either Rh/La2O3 or Rh/La2O 3-SiO2 as catalysts was used to carry out the dry reforming of methane. The membrane reactor simulation was performed using a well-known reactor model. For this purpose, we employed the equations derived from complete kinetic studies of the dry reforming of methane reaction in connection with both catalysts. In addition, we developed the kinetic equation for the reverse water gas shift reaction (RWGS). The combination of detailed kinetic studies with the measured permeation flux for the Pd-Ag membrane allowed a complete comparison between experimental and simulated operation variables. The variables studied for both catalysts were methane conversion and hydrogen permeation as a function of the sweep gas flow rate. The correlation between methane conversion enhancement and hydrogen recovery confirmed that a good prediction was obtained with this model. The performance of two reactor configurations (membrane reactor and conventional fixed-bed reactor) and both co-current and counter-current flow modes were compared. The effect of various operating variables such as permeation area, sweep gas flow rate and feed composition upon conversion, product compositions and hydrogen recovery were analyzed.
Fil: Coronel, Leandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Múnera Agudelo, John Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Lombardo, Eduardo Agustin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Cornaglia, Laura Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
description A dense Pd-Ag membrane reactor (MR) with 100% hydrogen selectivity packed with either Rh/La2O3 or Rh/La2O 3-SiO2 as catalysts was used to carry out the dry reforming of methane. The membrane reactor simulation was performed using a well-known reactor model. For this purpose, we employed the equations derived from complete kinetic studies of the dry reforming of methane reaction in connection with both catalysts. In addition, we developed the kinetic equation for the reverse water gas shift reaction (RWGS). The combination of detailed kinetic studies with the measured permeation flux for the Pd-Ag membrane allowed a complete comparison between experimental and simulated operation variables. The variables studied for both catalysts were methane conversion and hydrogen permeation as a function of the sweep gas flow rate. The correlation between methane conversion enhancement and hydrogen recovery confirmed that a good prediction was obtained with this model. The performance of two reactor configurations (membrane reactor and conventional fixed-bed reactor) and both co-current and counter-current flow modes were compared. The effect of various operating variables such as permeation area, sweep gas flow rate and feed composition upon conversion, product compositions and hydrogen recovery were analyzed.
publishDate 2011
dc.date.none.fl_str_mv 2011-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/73490
Coronel, Leandro; Múnera Agudelo, John Fernando; Lombardo, Eduardo Agustin; Cornaglia, Laura Maria; Pd based membrane reactor for ultra pure hydrogen production through the dry reforming of methane. Experimental and modeling studies; Elsevier Science; Applied Catalysis A: General; 400; 1-2; 6-2011; 185-194
0926-860X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/73490
identifier_str_mv Coronel, Leandro; Múnera Agudelo, John Fernando; Lombardo, Eduardo Agustin; Cornaglia, Laura Maria; Pd based membrane reactor for ultra pure hydrogen production through the dry reforming of methane. Experimental and modeling studies; Elsevier Science; Applied Catalysis A: General; 400; 1-2; 6-2011; 185-194
0926-860X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2011.04.030
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0926860X11002493
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846781542854033408
score 12.982451

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