Pd based membrane reactor for ultra pure hydrogen production through the dry reforming of methane. Experimental and modeling studies
- Autores
- Coronel, Leandro; Múnera Agudelo, John Fernando; Lombardo, Eduardo Agustin; Cornaglia, Laura Maria
- Año de publicación
- 2011
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- A dense Pd-Ag membrane reactor (MR) with 100% hydrogen selectivity packed with either Rh/La2O3 or Rh/La2O 3-SiO2 as catalysts was used to carry out the dry reforming of methane. The membrane reactor simulation was performed using a well-known reactor model. For this purpose, we employed the equations derived from complete kinetic studies of the dry reforming of methane reaction in connection with both catalysts. In addition, we developed the kinetic equation for the reverse water gas shift reaction (RWGS). The combination of detailed kinetic studies with the measured permeation flux for the Pd-Ag membrane allowed a complete comparison between experimental and simulated operation variables. The variables studied for both catalysts were methane conversion and hydrogen permeation as a function of the sweep gas flow rate. The correlation between methane conversion enhancement and hydrogen recovery confirmed that a good prediction was obtained with this model. The performance of two reactor configurations (membrane reactor and conventional fixed-bed reactor) and both co-current and counter-current flow modes were compared. The effect of various operating variables such as permeation area, sweep gas flow rate and feed composition upon conversion, product compositions and hydrogen recovery were analyzed.
Fil: Coronel, Leandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Múnera Agudelo, John Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Lombardo, Eduardo Agustin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Cornaglia, Laura Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina - Materia
-
Kinetic Equations
Membrane Reactor
Rh Catalysts - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/73490
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Pd based membrane reactor for ultra pure hydrogen production through the dry reforming of methane. Experimental and modeling studiesCoronel, LeandroMúnera Agudelo, John FernandoLombardo, Eduardo AgustinCornaglia, Laura MariaKinetic EquationsMembrane ReactorRh Catalystshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A dense Pd-Ag membrane reactor (MR) with 100% hydrogen selectivity packed with either Rh/La2O3 or Rh/La2O 3-SiO2 as catalysts was used to carry out the dry reforming of methane. The membrane reactor simulation was performed using a well-known reactor model. For this purpose, we employed the equations derived from complete kinetic studies of the dry reforming of methane reaction in connection with both catalysts. In addition, we developed the kinetic equation for the reverse water gas shift reaction (RWGS). The combination of detailed kinetic studies with the measured permeation flux for the Pd-Ag membrane allowed a complete comparison between experimental and simulated operation variables. The variables studied for both catalysts were methane conversion and hydrogen permeation as a function of the sweep gas flow rate. The correlation between methane conversion enhancement and hydrogen recovery confirmed that a good prediction was obtained with this model. The performance of two reactor configurations (membrane reactor and conventional fixed-bed reactor) and both co-current and counter-current flow modes were compared. The effect of various operating variables such as permeation area, sweep gas flow rate and feed composition upon conversion, product compositions and hydrogen recovery were analyzed.Fil: Coronel, Leandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Múnera Agudelo, John Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Lombardo, Eduardo Agustin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Cornaglia, Laura Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaElsevier Science2011-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/73490Coronel, Leandro; Múnera Agudelo, John Fernando; Lombardo, Eduardo Agustin; Cornaglia, Laura Maria; Pd based membrane reactor for ultra pure hydrogen production through the dry reforming of methane. Experimental and modeling studies; Elsevier Science; Applied Catalysis A: General; 400; 1-2; 6-2011; 185-1940926-860XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2011.04.030info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0926860X11002493info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:44:38Zoai:ri.conicet.gov.ar:11336/73490instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:44:38.767CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Pd based membrane reactor for ultra pure hydrogen production through the dry reforming of methane. Experimental and modeling studies |
title |
Pd based membrane reactor for ultra pure hydrogen production through the dry reforming of methane. Experimental and modeling studies |
spellingShingle |
Pd based membrane reactor for ultra pure hydrogen production through the dry reforming of methane. Experimental and modeling studies Coronel, Leandro Kinetic Equations Membrane Reactor Rh Catalysts |
title_short |
Pd based membrane reactor for ultra pure hydrogen production through the dry reforming of methane. Experimental and modeling studies |
title_full |
Pd based membrane reactor for ultra pure hydrogen production through the dry reforming of methane. Experimental and modeling studies |
title_fullStr |
Pd based membrane reactor for ultra pure hydrogen production through the dry reforming of methane. Experimental and modeling studies |
title_full_unstemmed |
Pd based membrane reactor for ultra pure hydrogen production through the dry reforming of methane. Experimental and modeling studies |
title_sort |
Pd based membrane reactor for ultra pure hydrogen production through the dry reforming of methane. Experimental and modeling studies |
dc.creator.none.fl_str_mv |
Coronel, Leandro Múnera Agudelo, John Fernando Lombardo, Eduardo Agustin Cornaglia, Laura Maria |
author |
Coronel, Leandro |
author_facet |
Coronel, Leandro Múnera Agudelo, John Fernando Lombardo, Eduardo Agustin Cornaglia, Laura Maria |
author_role |
author |
author2 |
Múnera Agudelo, John Fernando Lombardo, Eduardo Agustin Cornaglia, Laura Maria |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
Kinetic Equations Membrane Reactor Rh Catalysts |
topic |
Kinetic Equations Membrane Reactor Rh Catalysts |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
A dense Pd-Ag membrane reactor (MR) with 100% hydrogen selectivity packed with either Rh/La2O3 or Rh/La2O 3-SiO2 as catalysts was used to carry out the dry reforming of methane. The membrane reactor simulation was performed using a well-known reactor model. For this purpose, we employed the equations derived from complete kinetic studies of the dry reforming of methane reaction in connection with both catalysts. In addition, we developed the kinetic equation for the reverse water gas shift reaction (RWGS). The combination of detailed kinetic studies with the measured permeation flux for the Pd-Ag membrane allowed a complete comparison between experimental and simulated operation variables. The variables studied for both catalysts were methane conversion and hydrogen permeation as a function of the sweep gas flow rate. The correlation between methane conversion enhancement and hydrogen recovery confirmed that a good prediction was obtained with this model. The performance of two reactor configurations (membrane reactor and conventional fixed-bed reactor) and both co-current and counter-current flow modes were compared. The effect of various operating variables such as permeation area, sweep gas flow rate and feed composition upon conversion, product compositions and hydrogen recovery were analyzed. Fil: Coronel, Leandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina Fil: Múnera Agudelo, John Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina Fil: Lombardo, Eduardo Agustin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina Fil: Cornaglia, Laura Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina |
description |
A dense Pd-Ag membrane reactor (MR) with 100% hydrogen selectivity packed with either Rh/La2O3 or Rh/La2O 3-SiO2 as catalysts was used to carry out the dry reforming of methane. The membrane reactor simulation was performed using a well-known reactor model. For this purpose, we employed the equations derived from complete kinetic studies of the dry reforming of methane reaction in connection with both catalysts. In addition, we developed the kinetic equation for the reverse water gas shift reaction (RWGS). The combination of detailed kinetic studies with the measured permeation flux for the Pd-Ag membrane allowed a complete comparison between experimental and simulated operation variables. The variables studied for both catalysts were methane conversion and hydrogen permeation as a function of the sweep gas flow rate. The correlation between methane conversion enhancement and hydrogen recovery confirmed that a good prediction was obtained with this model. The performance of two reactor configurations (membrane reactor and conventional fixed-bed reactor) and both co-current and counter-current flow modes were compared. The effect of various operating variables such as permeation area, sweep gas flow rate and feed composition upon conversion, product compositions and hydrogen recovery were analyzed. |
publishDate |
2011 |
dc.date.none.fl_str_mv |
2011-06 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/73490 Coronel, Leandro; Múnera Agudelo, John Fernando; Lombardo, Eduardo Agustin; Cornaglia, Laura Maria; Pd based membrane reactor for ultra pure hydrogen production through the dry reforming of methane. Experimental and modeling studies; Elsevier Science; Applied Catalysis A: General; 400; 1-2; 6-2011; 185-194 0926-860X CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/73490 |
identifier_str_mv |
Coronel, Leandro; Múnera Agudelo, John Fernando; Lombardo, Eduardo Agustin; Cornaglia, Laura Maria; Pd based membrane reactor for ultra pure hydrogen production through the dry reforming of methane. Experimental and modeling studies; Elsevier Science; Applied Catalysis A: General; 400; 1-2; 6-2011; 185-194 0926-860X CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2011.04.030 info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0926860X11002493 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science |
publisher.none.fl_str_mv |
Elsevier Science |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613405118300160 |
score |
13.070432 |