Modeling gas solubilities in imidazolium based ionic liquids with the [Tf2N] anion using the GC-EoS

Autores
Pereda, Selva; Raeissi, Sona; Andreatta, Alfonsina Ester; Bottini, Susana Beatriz; Kroon, Maaike; Peters, Cor J.
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The group contribution equation of state (GC-EoS) is extended to model gas solubilities in the homologous 1-alkyl-3-methylimidazolium bis(trifluoromethyl-sulfonyl) imide family. The gases considered in this work are CO2, CO, H2, CH4, and C2H6. The model parameters were estimated on the basis of 1400 experimental data points in the temperature range of 278-460 K and pressures up to 160 bars. A correlation is also presented to calculate the critical diameter, a characteristic parameter of the GC-EoS repulsive term, as a function of the ionic liquid molar volume. Density data is most often available for ionic liquids; hence, the correlation provides a predictive method for ionic liquids not included in the parameterization process. The new parameters were then used to predict the phase behavior of binary mixtures containing different solutes (including C3H8, C4H10, and C6H14) and ionic liquids with different chain lengths than those used in the parameterization process.
Fil: Pereda, Selva. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Raeissi, Sona. Shiraz University; Irán
Fil: Andreatta, Alfonsina Ester. Universidad Nacional de Córdoba; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahia Blanca. Planta Piloto de Ingeniería Química (I). Grupo Vinculado al Plapiqui - Investigación y Desarrollo en Tecnología Química; Argentina
Fil: Bottini, Susana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Kroon, Maaike. Eindhoven University of Technologie; Alemania. Technische Universiteit Eindhoven; Alemania
Fil: Peters, Cor J.. Technische Universiteit Eindhoven; Alemania. Eindhoven University of Technology; Alemania. The Petroleum Institute. Chemical Engineering Department - Abu Dhabi; Emiratos Arabes Unidos
Materia
1-Alkyl-3-Methylimidazolium Bis(Trifluoromethyl-Sulfonyl)Amide
1-Alkyl-3-Methylimidazolium Bis(Trifluoromethyl-Sulfonyl)Imide
Alkane
Co
Co2
Equation of State
Gc-Eos
Group Contribution
H2
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/26490
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/26490
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Modeling gas solubilities in imidazolium based ionic liquids with the [Tf2N] anion using the GC-EoSPereda, SelvaRaeissi, SonaAndreatta, Alfonsina EsterBottini, Susana BeatrizKroon, MaaikePeters, Cor J.1-Alkyl-3-Methylimidazolium Bis(Trifluoromethyl-Sulfonyl)Amide1-Alkyl-3-Methylimidazolium Bis(Trifluoromethyl-Sulfonyl)ImideAlkaneCoCo2Equation of StateGc-EosGroup ContributionH2https://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The group contribution equation of state (GC-EoS) is extended to model gas solubilities in the homologous 1-alkyl-3-methylimidazolium bis(trifluoromethyl-sulfonyl) imide family. The gases considered in this work are CO2, CO, H2, CH4, and C2H6. The model parameters were estimated on the basis of 1400 experimental data points in the temperature range of 278-460 K and pressures up to 160 bars. A correlation is also presented to calculate the critical diameter, a characteristic parameter of the GC-EoS repulsive term, as a function of the ionic liquid molar volume. Density data is most often available for ionic liquids; hence, the correlation provides a predictive method for ionic liquids not included in the parameterization process. The new parameters were then used to predict the phase behavior of binary mixtures containing different solutes (including C3H8, C4H10, and C6H14) and ionic liquids with different chain lengths than those used in the parameterization process.Fil: Pereda, Selva. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Raeissi, Sona. Shiraz University; IránFil: Andreatta, Alfonsina Ester. Universidad Nacional de Córdoba; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahia Blanca. Planta Piloto de Ingeniería Química (I). Grupo Vinculado al Plapiqui - Investigación y Desarrollo en Tecnología Química; ArgentinaFil: Bottini, Susana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Kroon, Maaike. Eindhoven University of Technologie; Alemania. Technische Universiteit Eindhoven; AlemaniaFil: Peters, Cor J.. Technische Universiteit Eindhoven; Alemania. Eindhoven University of Technology; Alemania. The Petroleum Institute. Chemical Engineering Department - Abu Dhabi; Emiratos Arabes UnidosElsevier Science2015-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/26490Pereda, Selva; Raeissi, Sona; Andreatta, Alfonsina Ester; Bottini, Susana Beatriz; Kroon, Maaike; et al.; Modeling gas solubilities in imidazolium based ionic liquids with the [Tf2N] anion using the GC-EoS; Elsevier Science; Fluid Phase Equilibria; 409; 10-2015; 408-4160378-3812CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0378381215301965info:eu-repo/semantics/altIdentifier/doi/10.1016/j.fluid.2015.10.037info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:00:41Zoai:ri.conicet.gov.ar:11336/26490instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:00:41.505CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Modeling gas solubilities in imidazolium based ionic liquids with the [Tf2N] anion using the GC-EoS
title Modeling gas solubilities in imidazolium based ionic liquids with the [Tf2N] anion using the GC-EoS
spellingShingle Modeling gas solubilities in imidazolium based ionic liquids with the [Tf2N] anion using the GC-EoS
Pereda, Selva
1-Alkyl-3-Methylimidazolium Bis(Trifluoromethyl-Sulfonyl)Amide
1-Alkyl-3-Methylimidazolium Bis(Trifluoromethyl-Sulfonyl)Imide
Alkane
Co
Co2
Equation of State
Gc-Eos
Group Contribution
H2
title_short Modeling gas solubilities in imidazolium based ionic liquids with the [Tf2N] anion using the GC-EoS
title_full Modeling gas solubilities in imidazolium based ionic liquids with the [Tf2N] anion using the GC-EoS
title_fullStr Modeling gas solubilities in imidazolium based ionic liquids with the [Tf2N] anion using the GC-EoS
title_full_unstemmed Modeling gas solubilities in imidazolium based ionic liquids with the [Tf2N] anion using the GC-EoS
title_sort Modeling gas solubilities in imidazolium based ionic liquids with the [Tf2N] anion using the GC-EoS
dc.creator.none.fl_str_mv Pereda, Selva
Raeissi, Sona
Andreatta, Alfonsina Ester
Bottini, Susana Beatriz
Kroon, Maaike
Peters, Cor J.
author Pereda, Selva
author_facet Pereda, Selva
Raeissi, Sona
Andreatta, Alfonsina Ester
Bottini, Susana Beatriz
Kroon, Maaike
Peters, Cor J.
author_role author
author2 Raeissi, Sona
Andreatta, Alfonsina Ester
Bottini, Susana Beatriz
Kroon, Maaike
Peters, Cor J.
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv 1-Alkyl-3-Methylimidazolium Bis(Trifluoromethyl-Sulfonyl)Amide
1-Alkyl-3-Methylimidazolium Bis(Trifluoromethyl-Sulfonyl)Imide
Alkane
Co
Co2
Equation of State
Gc-Eos
Group Contribution
H2
topic 1-Alkyl-3-Methylimidazolium Bis(Trifluoromethyl-Sulfonyl)Amide
1-Alkyl-3-Methylimidazolium Bis(Trifluoromethyl-Sulfonyl)Imide
Alkane
Co
Co2
Equation of State
Gc-Eos
Group Contribution
H2
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The group contribution equation of state (GC-EoS) is extended to model gas solubilities in the homologous 1-alkyl-3-methylimidazolium bis(trifluoromethyl-sulfonyl) imide family. The gases considered in this work are CO2, CO, H2, CH4, and C2H6. The model parameters were estimated on the basis of 1400 experimental data points in the temperature range of 278-460 K and pressures up to 160 bars. A correlation is also presented to calculate the critical diameter, a characteristic parameter of the GC-EoS repulsive term, as a function of the ionic liquid molar volume. Density data is most often available for ionic liquids; hence, the correlation provides a predictive method for ionic liquids not included in the parameterization process. The new parameters were then used to predict the phase behavior of binary mixtures containing different solutes (including C3H8, C4H10, and C6H14) and ionic liquids with different chain lengths than those used in the parameterization process.
Fil: Pereda, Selva. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Raeissi, Sona. Shiraz University; Irán
Fil: Andreatta, Alfonsina Ester. Universidad Nacional de Córdoba; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahia Blanca. Planta Piloto de Ingeniería Química (I). Grupo Vinculado al Plapiqui - Investigación y Desarrollo en Tecnología Química; Argentina
Fil: Bottini, Susana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Kroon, Maaike. Eindhoven University of Technologie; Alemania. Technische Universiteit Eindhoven; Alemania
Fil: Peters, Cor J.. Technische Universiteit Eindhoven; Alemania. Eindhoven University of Technology; Alemania. The Petroleum Institute. Chemical Engineering Department - Abu Dhabi; Emiratos Arabes Unidos
description The group contribution equation of state (GC-EoS) is extended to model gas solubilities in the homologous 1-alkyl-3-methylimidazolium bis(trifluoromethyl-sulfonyl) imide family. The gases considered in this work are CO2, CO, H2, CH4, and C2H6. The model parameters were estimated on the basis of 1400 experimental data points in the temperature range of 278-460 K and pressures up to 160 bars. A correlation is also presented to calculate the critical diameter, a characteristic parameter of the GC-EoS repulsive term, as a function of the ionic liquid molar volume. Density data is most often available for ionic liquids; hence, the correlation provides a predictive method for ionic liquids not included in the parameterization process. The new parameters were then used to predict the phase behavior of binary mixtures containing different solutes (including C3H8, C4H10, and C6H14) and ionic liquids with different chain lengths than those used in the parameterization process.
publishDate 2015
dc.date.none.fl_str_mv 2015-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/26490
Pereda, Selva; Raeissi, Sona; Andreatta, Alfonsina Ester; Bottini, Susana Beatriz; Kroon, Maaike; et al.; Modeling gas solubilities in imidazolium based ionic liquids with the [Tf2N] anion using the GC-EoS; Elsevier Science; Fluid Phase Equilibria; 409; 10-2015; 408-416
0378-3812
CONICET Digital
CONICET
url http://hdl.handle.net/11336/26490
identifier_str_mv Pereda, Selva; Raeissi, Sona; Andreatta, Alfonsina Ester; Bottini, Susana Beatriz; Kroon, Maaike; et al.; Modeling gas solubilities in imidazolium based ionic liquids with the [Tf2N] anion using the GC-EoS; Elsevier Science; Fluid Phase Equilibria; 409; 10-2015; 408-416
0378-3812
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0378381215301965
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.fluid.2015.10.037
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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