Modeling gas solubilities in imidazolium based ionic liquids with the [Tf2N] anion using the GC-EoS
- Autores
- Pereda, Selva; Raeissi, Sona; Andreatta, Alfonsina Ester; Bottini, Susana Beatriz; Kroon, Maaike; Peters, Cor J.
- Año de publicación
- 2015
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The group contribution equation of state (GC-EoS) is extended to model gas solubilities in the homologous 1-alkyl-3-methylimidazolium bis(trifluoromethyl-sulfonyl) imide family. The gases considered in this work are CO2, CO, H2, CH4, and C2H6. The model parameters were estimated on the basis of 1400 experimental data points in the temperature range of 278-460 K and pressures up to 160 bars. A correlation is also presented to calculate the critical diameter, a characteristic parameter of the GC-EoS repulsive term, as a function of the ionic liquid molar volume. Density data is most often available for ionic liquids; hence, the correlation provides a predictive method for ionic liquids not included in the parameterization process. The new parameters were then used to predict the phase behavior of binary mixtures containing different solutes (including C3H8, C4H10, and C6H14) and ionic liquids with different chain lengths than those used in the parameterization process.
Fil: Pereda, Selva. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Raeissi, Sona. Shiraz University; Irán
Fil: Andreatta, Alfonsina Ester. Universidad Nacional de Córdoba; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahia Blanca. Planta Piloto de Ingeniería Química (I). Grupo Vinculado al Plapiqui - Investigación y Desarrollo en Tecnología Química; Argentina
Fil: Bottini, Susana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Kroon, Maaike. Eindhoven University of Technologie; Alemania. Technische Universiteit Eindhoven; Alemania
Fil: Peters, Cor J.. Technische Universiteit Eindhoven; Alemania. Eindhoven University of Technology; Alemania. The Petroleum Institute. Chemical Engineering Department - Abu Dhabi; Emiratos Arabes Unidos - Materia
-
1-Alkyl-3-Methylimidazolium Bis(Trifluoromethyl-Sulfonyl)Amide
1-Alkyl-3-Methylimidazolium Bis(Trifluoromethyl-Sulfonyl)Imide
Alkane
Co
Co2
Equation of State
Gc-Eos
Group Contribution
H2 - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/26490
Ver los metadatos del registro completo
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oai:ri.conicet.gov.ar:11336/26490 |
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network_name_str |
CONICET Digital (CONICET) |
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Modeling gas solubilities in imidazolium based ionic liquids with the [Tf2N] anion using the GC-EoSPereda, SelvaRaeissi, SonaAndreatta, Alfonsina EsterBottini, Susana BeatrizKroon, MaaikePeters, Cor J.1-Alkyl-3-Methylimidazolium Bis(Trifluoromethyl-Sulfonyl)Amide1-Alkyl-3-Methylimidazolium Bis(Trifluoromethyl-Sulfonyl)ImideAlkaneCoCo2Equation of StateGc-EosGroup ContributionH2https://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The group contribution equation of state (GC-EoS) is extended to model gas solubilities in the homologous 1-alkyl-3-methylimidazolium bis(trifluoromethyl-sulfonyl) imide family. The gases considered in this work are CO2, CO, H2, CH4, and C2H6. The model parameters were estimated on the basis of 1400 experimental data points in the temperature range of 278-460 K and pressures up to 160 bars. A correlation is also presented to calculate the critical diameter, a characteristic parameter of the GC-EoS repulsive term, as a function of the ionic liquid molar volume. Density data is most often available for ionic liquids; hence, the correlation provides a predictive method for ionic liquids not included in the parameterization process. The new parameters were then used to predict the phase behavior of binary mixtures containing different solutes (including C3H8, C4H10, and C6H14) and ionic liquids with different chain lengths than those used in the parameterization process.Fil: Pereda, Selva. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Raeissi, Sona. Shiraz University; IránFil: Andreatta, Alfonsina Ester. Universidad Nacional de Córdoba; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahia Blanca. Planta Piloto de Ingeniería Química (I). Grupo Vinculado al Plapiqui - Investigación y Desarrollo en Tecnología Química; ArgentinaFil: Bottini, Susana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Kroon, Maaike. Eindhoven University of Technologie; Alemania. Technische Universiteit Eindhoven; AlemaniaFil: Peters, Cor J.. Technische Universiteit Eindhoven; Alemania. Eindhoven University of Technology; Alemania. The Petroleum Institute. Chemical Engineering Department - Abu Dhabi; Emiratos Arabes UnidosElsevier Science2015-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/26490Pereda, Selva; Raeissi, Sona; Andreatta, Alfonsina Ester; Bottini, Susana Beatriz; Kroon, Maaike; et al.; Modeling gas solubilities in imidazolium based ionic liquids with the [Tf2N] anion using the GC-EoS; Elsevier Science; Fluid Phase Equilibria; 409; 10-2015; 408-4160378-3812CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0378381215301965info:eu-repo/semantics/altIdentifier/doi/10.1016/j.fluid.2015.10.037info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:56:27Zoai:ri.conicet.gov.ar:11336/26490instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:56:28.123CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Modeling gas solubilities in imidazolium based ionic liquids with the [Tf2N] anion using the GC-EoS |
title |
Modeling gas solubilities in imidazolium based ionic liquids with the [Tf2N] anion using the GC-EoS |
spellingShingle |
Modeling gas solubilities in imidazolium based ionic liquids with the [Tf2N] anion using the GC-EoS Pereda, Selva 1-Alkyl-3-Methylimidazolium Bis(Trifluoromethyl-Sulfonyl)Amide 1-Alkyl-3-Methylimidazolium Bis(Trifluoromethyl-Sulfonyl)Imide Alkane Co Co2 Equation of State Gc-Eos Group Contribution H2 |
title_short |
Modeling gas solubilities in imidazolium based ionic liquids with the [Tf2N] anion using the GC-EoS |
title_full |
Modeling gas solubilities in imidazolium based ionic liquids with the [Tf2N] anion using the GC-EoS |
title_fullStr |
Modeling gas solubilities in imidazolium based ionic liquids with the [Tf2N] anion using the GC-EoS |
title_full_unstemmed |
Modeling gas solubilities in imidazolium based ionic liquids with the [Tf2N] anion using the GC-EoS |
title_sort |
Modeling gas solubilities in imidazolium based ionic liquids with the [Tf2N] anion using the GC-EoS |
dc.creator.none.fl_str_mv |
Pereda, Selva Raeissi, Sona Andreatta, Alfonsina Ester Bottini, Susana Beatriz Kroon, Maaike Peters, Cor J. |
author |
Pereda, Selva |
author_facet |
Pereda, Selva Raeissi, Sona Andreatta, Alfonsina Ester Bottini, Susana Beatriz Kroon, Maaike Peters, Cor J. |
author_role |
author |
author2 |
Raeissi, Sona Andreatta, Alfonsina Ester Bottini, Susana Beatriz Kroon, Maaike Peters, Cor J. |
author2_role |
author author author author author |
dc.subject.none.fl_str_mv |
1-Alkyl-3-Methylimidazolium Bis(Trifluoromethyl-Sulfonyl)Amide 1-Alkyl-3-Methylimidazolium Bis(Trifluoromethyl-Sulfonyl)Imide Alkane Co Co2 Equation of State Gc-Eos Group Contribution H2 |
topic |
1-Alkyl-3-Methylimidazolium Bis(Trifluoromethyl-Sulfonyl)Amide 1-Alkyl-3-Methylimidazolium Bis(Trifluoromethyl-Sulfonyl)Imide Alkane Co Co2 Equation of State Gc-Eos Group Contribution H2 |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
The group contribution equation of state (GC-EoS) is extended to model gas solubilities in the homologous 1-alkyl-3-methylimidazolium bis(trifluoromethyl-sulfonyl) imide family. The gases considered in this work are CO2, CO, H2, CH4, and C2H6. The model parameters were estimated on the basis of 1400 experimental data points in the temperature range of 278-460 K and pressures up to 160 bars. A correlation is also presented to calculate the critical diameter, a characteristic parameter of the GC-EoS repulsive term, as a function of the ionic liquid molar volume. Density data is most often available for ionic liquids; hence, the correlation provides a predictive method for ionic liquids not included in the parameterization process. The new parameters were then used to predict the phase behavior of binary mixtures containing different solutes (including C3H8, C4H10, and C6H14) and ionic liquids with different chain lengths than those used in the parameterization process. Fil: Pereda, Selva. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina Fil: Raeissi, Sona. Shiraz University; Irán Fil: Andreatta, Alfonsina Ester. Universidad Nacional de Córdoba; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahia Blanca. Planta Piloto de Ingeniería Química (I). Grupo Vinculado al Plapiqui - Investigación y Desarrollo en Tecnología Química; Argentina Fil: Bottini, Susana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina Fil: Kroon, Maaike. Eindhoven University of Technologie; Alemania. Technische Universiteit Eindhoven; Alemania Fil: Peters, Cor J.. Technische Universiteit Eindhoven; Alemania. Eindhoven University of Technology; Alemania. The Petroleum Institute. Chemical Engineering Department - Abu Dhabi; Emiratos Arabes Unidos |
description |
The group contribution equation of state (GC-EoS) is extended to model gas solubilities in the homologous 1-alkyl-3-methylimidazolium bis(trifluoromethyl-sulfonyl) imide family. The gases considered in this work are CO2, CO, H2, CH4, and C2H6. The model parameters were estimated on the basis of 1400 experimental data points in the temperature range of 278-460 K and pressures up to 160 bars. A correlation is also presented to calculate the critical diameter, a characteristic parameter of the GC-EoS repulsive term, as a function of the ionic liquid molar volume. Density data is most often available for ionic liquids; hence, the correlation provides a predictive method for ionic liquids not included in the parameterization process. The new parameters were then used to predict the phase behavior of binary mixtures containing different solutes (including C3H8, C4H10, and C6H14) and ionic liquids with different chain lengths than those used in the parameterization process. |
publishDate |
2015 |
dc.date.none.fl_str_mv |
2015-10 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/26490 Pereda, Selva; Raeissi, Sona; Andreatta, Alfonsina Ester; Bottini, Susana Beatriz; Kroon, Maaike; et al.; Modeling gas solubilities in imidazolium based ionic liquids with the [Tf2N] anion using the GC-EoS; Elsevier Science; Fluid Phase Equilibria; 409; 10-2015; 408-416 0378-3812 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/26490 |
identifier_str_mv |
Pereda, Selva; Raeissi, Sona; Andreatta, Alfonsina Ester; Bottini, Susana Beatriz; Kroon, Maaike; et al.; Modeling gas solubilities in imidazolium based ionic liquids with the [Tf2N] anion using the GC-EoS; Elsevier Science; Fluid Phase Equilibria; 409; 10-2015; 408-416 0378-3812 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0378381215301965 info:eu-repo/semantics/altIdentifier/doi/10.1016/j.fluid.2015.10.037 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science |
publisher.none.fl_str_mv |
Elsevier Science |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1842269403282931712 |
score |
13.13397 |