Synergistic effects in magnetically recoverable nanocomposites of CuO nanoleaves with Fe3O4 nanoparticles for organic dye degradation

Autores
Londoño Calderón, César Leandro; Tancredi Gentili, Pablo; Menchaca Nal, Sandra; Francois, Nora; Pampillo, Laura Gabriela
Año de publicación
2025
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In this work, we report the synthesis and characterization of Fe3O4/CuO nanocomposites and demonstrate their catalytic efficiency towards the degradation of organic dyes. Single-crystalline Fe3O4 nanoparticles of 11 nm were obtained via coprecipitation and functionalized with β-alanine for colloidal stability and chemical affinity towards the CuO surface. The CuO nanoleaves were produced by sonochemical precipitation, resulting in nanostructures with average sizes of 1080, 286, and 15 nm in long, wide, and thick, respectively. Moreover, the nanoleaves are polycrystalline, with an average crystallite size of 16 nm, and with band-gap energy of 1.48 eV. The nanocomposites were prepared by mixing the two nanostructures in various ratios to study the effect of the composition on both properties and technological performance. Field emission scanning electron microscopy confirmed that the ratio of primary nanostructures was retained in the nanocomposites and showed that the exposed surface area of nanoleaves decreased with an increasing percentage of Fe3O4 nanoparticles. While the crystalline structure of the primary nanostructures remained unchanged, the band-gap energy increased to 1.78 eV. These nanocomposites demonstrated impressive catalytic efficiency, achieving nearly complete degradation of methyl orange with H2O2 assisted by ultrasonication. This high catalytic activity, coupled with ease of recovery and reuse, makes these nanocomposites a promising solution for water remediation applications.
Fil: Londoño Calderón, César Leandro. Universidad Autónoma de Manizales; Colombia
Fil: Tancredi Gentili, Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long". Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long"; Argentina
Fil: Menchaca Nal, Sandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; Argentina
Fil: Francois, Nora. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; Argentina
Fil: Pampillo, Laura Gabriela. Universidad de Buenos Aires. Facultad de Ingeniería. Departamento de Química. Grupo de Aplicaciones de Materiales Biocompatibles; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long". Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long"; Argentina
Materia
Magnetic nanoparticles
Nanoleaves
Cupric oxide
Magnetite
Nanocomposites
Catalytic degradation
Water remediation
Methyl orange
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/266479
Acceder
id CONICETDig_dcd5798a4040e23a6b600cc82d6c31e4
oai_identifier_str oai:ri.conicet.gov.ar:11336/266479
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Synergistic effects in magnetically recoverable nanocomposites of CuO nanoleaves with Fe3O4 nanoparticles for organic dye degradationLondoño Calderón, César LeandroTancredi Gentili, PabloMenchaca Nal, SandraFrancois, NoraPampillo, Laura GabrielaMagnetic nanoparticlesNanoleavesCupric oxideMagnetiteNanocompositesCatalytic degradationWater remediationMethyl orangehttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2In this work, we report the synthesis and characterization of Fe3O4/CuO nanocomposites and demonstrate their catalytic efficiency towards the degradation of organic dyes. Single-crystalline Fe3O4 nanoparticles of 11 nm were obtained via coprecipitation and functionalized with β-alanine for colloidal stability and chemical affinity towards the CuO surface. The CuO nanoleaves were produced by sonochemical precipitation, resulting in nanostructures with average sizes of 1080, 286, and 15 nm in long, wide, and thick, respectively. Moreover, the nanoleaves are polycrystalline, with an average crystallite size of 16 nm, and with band-gap energy of 1.48 eV. The nanocomposites were prepared by mixing the two nanostructures in various ratios to study the effect of the composition on both properties and technological performance. Field emission scanning electron microscopy confirmed that the ratio of primary nanostructures was retained in the nanocomposites and showed that the exposed surface area of nanoleaves decreased with an increasing percentage of Fe3O4 nanoparticles. While the crystalline structure of the primary nanostructures remained unchanged, the band-gap energy increased to 1.78 eV. These nanocomposites demonstrated impressive catalytic efficiency, achieving nearly complete degradation of methyl orange with H2O2 assisted by ultrasonication. This high catalytic activity, coupled with ease of recovery and reuse, makes these nanocomposites a promising solution for water remediation applications.Fil: Londoño Calderón, César Leandro. Universidad Autónoma de Manizales; ColombiaFil: Tancredi Gentili, Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long". Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long"; ArgentinaFil: Menchaca Nal, Sandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; ArgentinaFil: Francois, Nora. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; ArgentinaFil: Pampillo, Laura Gabriela. Universidad de Buenos Aires. Facultad de Ingeniería. Departamento de Química. Grupo de Aplicaciones de Materiales Biocompatibles; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long". Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long"; ArgentinaElsevier2025-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/266479Londoño Calderón, César Leandro; Tancredi Gentili, Pablo; Menchaca Nal, Sandra; Francois, Nora; Pampillo, Laura Gabriela; Synergistic effects in magnetically recoverable nanocomposites of CuO nanoleaves with Fe3O4 nanoparticles for organic dye degradation; Elsevier; Next Materials; 7; 4-2025; 1-92949-8228CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S2949822824002673info:eu-repo/semantics/altIdentifier/doi/10.1016/j.nxmate.2024.100370info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:36:37Zoai:ri.conicet.gov.ar:11336/266479instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:36:37.477CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Synergistic effects in magnetically recoverable nanocomposites of CuO nanoleaves with Fe3O4 nanoparticles for organic dye degradation
title Synergistic effects in magnetically recoverable nanocomposites of CuO nanoleaves with Fe3O4 nanoparticles for organic dye degradation
spellingShingle Synergistic effects in magnetically recoverable nanocomposites of CuO nanoleaves with Fe3O4 nanoparticles for organic dye degradation
Londoño Calderón, César Leandro
Magnetic nanoparticles
Nanoleaves
Cupric oxide
Magnetite
Nanocomposites
Catalytic degradation
Water remediation
Methyl orange
title_short Synergistic effects in magnetically recoverable nanocomposites of CuO nanoleaves with Fe3O4 nanoparticles for organic dye degradation
title_full Synergistic effects in magnetically recoverable nanocomposites of CuO nanoleaves with Fe3O4 nanoparticles for organic dye degradation
title_fullStr Synergistic effects in magnetically recoverable nanocomposites of CuO nanoleaves with Fe3O4 nanoparticles for organic dye degradation
title_full_unstemmed Synergistic effects in magnetically recoverable nanocomposites of CuO nanoleaves with Fe3O4 nanoparticles for organic dye degradation
title_sort Synergistic effects in magnetically recoverable nanocomposites of CuO nanoleaves with Fe3O4 nanoparticles for organic dye degradation
dc.creator.none.fl_str_mv Londoño Calderón, César Leandro
Tancredi Gentili, Pablo
Menchaca Nal, Sandra
Francois, Nora
Pampillo, Laura Gabriela
author Londoño Calderón, César Leandro
author_facet Londoño Calderón, César Leandro
Tancredi Gentili, Pablo
Menchaca Nal, Sandra
Francois, Nora
Pampillo, Laura Gabriela
author_role author
author2 Tancredi Gentili, Pablo
Menchaca Nal, Sandra
Francois, Nora
Pampillo, Laura Gabriela
author2_role author
author
author
author
dc.subject.none.fl_str_mv Magnetic nanoparticles
Nanoleaves
Cupric oxide
Magnetite
Nanocomposites
Catalytic degradation
Water remediation
Methyl orange
topic Magnetic nanoparticles
Nanoleaves
Cupric oxide
Magnetite
Nanocomposites
Catalytic degradation
Water remediation
Methyl orange
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv In this work, we report the synthesis and characterization of Fe3O4/CuO nanocomposites and demonstrate their catalytic efficiency towards the degradation of organic dyes. Single-crystalline Fe3O4 nanoparticles of 11 nm were obtained via coprecipitation and functionalized with β-alanine for colloidal stability and chemical affinity towards the CuO surface. The CuO nanoleaves were produced by sonochemical precipitation, resulting in nanostructures with average sizes of 1080, 286, and 15 nm in long, wide, and thick, respectively. Moreover, the nanoleaves are polycrystalline, with an average crystallite size of 16 nm, and with band-gap energy of 1.48 eV. The nanocomposites were prepared by mixing the two nanostructures in various ratios to study the effect of the composition on both properties and technological performance. Field emission scanning electron microscopy confirmed that the ratio of primary nanostructures was retained in the nanocomposites and showed that the exposed surface area of nanoleaves decreased with an increasing percentage of Fe3O4 nanoparticles. While the crystalline structure of the primary nanostructures remained unchanged, the band-gap energy increased to 1.78 eV. These nanocomposites demonstrated impressive catalytic efficiency, achieving nearly complete degradation of methyl orange with H2O2 assisted by ultrasonication. This high catalytic activity, coupled with ease of recovery and reuse, makes these nanocomposites a promising solution for water remediation applications.
Fil: Londoño Calderón, César Leandro. Universidad Autónoma de Manizales; Colombia
Fil: Tancredi Gentili, Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long". Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long"; Argentina
Fil: Menchaca Nal, Sandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; Argentina
Fil: Francois, Nora. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; Argentina
Fil: Pampillo, Laura Gabriela. Universidad de Buenos Aires. Facultad de Ingeniería. Departamento de Química. Grupo de Aplicaciones de Materiales Biocompatibles; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long". Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long"; Argentina
description In this work, we report the synthesis and characterization of Fe3O4/CuO nanocomposites and demonstrate their catalytic efficiency towards the degradation of organic dyes. Single-crystalline Fe3O4 nanoparticles of 11 nm were obtained via coprecipitation and functionalized with β-alanine for colloidal stability and chemical affinity towards the CuO surface. The CuO nanoleaves were produced by sonochemical precipitation, resulting in nanostructures with average sizes of 1080, 286, and 15 nm in long, wide, and thick, respectively. Moreover, the nanoleaves are polycrystalline, with an average crystallite size of 16 nm, and with band-gap energy of 1.48 eV. The nanocomposites were prepared by mixing the two nanostructures in various ratios to study the effect of the composition on both properties and technological performance. Field emission scanning electron microscopy confirmed that the ratio of primary nanostructures was retained in the nanocomposites and showed that the exposed surface area of nanoleaves decreased with an increasing percentage of Fe3O4 nanoparticles. While the crystalline structure of the primary nanostructures remained unchanged, the band-gap energy increased to 1.78 eV. These nanocomposites demonstrated impressive catalytic efficiency, achieving nearly complete degradation of methyl orange with H2O2 assisted by ultrasonication. This high catalytic activity, coupled with ease of recovery and reuse, makes these nanocomposites a promising solution for water remediation applications.
publishDate 2025
dc.date.none.fl_str_mv 2025-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/266479
Londoño Calderón, César Leandro; Tancredi Gentili, Pablo; Menchaca Nal, Sandra; Francois, Nora; Pampillo, Laura Gabriela; Synergistic effects in magnetically recoverable nanocomposites of CuO nanoleaves with Fe3O4 nanoparticles for organic dye degradation; Elsevier; Next Materials; 7; 4-2025; 1-9
2949-8228
CONICET Digital
CONICET
url http://hdl.handle.net/11336/266479
identifier_str_mv Londoño Calderón, César Leandro; Tancredi Gentili, Pablo; Menchaca Nal, Sandra; Francois, Nora; Pampillo, Laura Gabriela; Synergistic effects in magnetically recoverable nanocomposites of CuO nanoleaves with Fe3O4 nanoparticles for organic dye degradation; Elsevier; Next Materials; 7; 4-2025; 1-9
2949-8228
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S2949822824002673
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.nxmate.2024.100370
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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