Cupric Oxide Nanoleaves for the Oxidative Degradation of Methyl Orange without Heating or Light

Autores
Londoño Calderon, Cesar Leandro; Menchaca Nal, Sandra; Francois, Nora J.; Pampillo, Laura Gabriela; Froimowicz, Pablo
Año de publicación
2020
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Low-cost 2D cupric oxide nanoleaves (CuO NLs) arestraightforwardly synthesized at room temperature by precipitationvarying the addition method of the alkali. No further treatments arenecessary to obtain high purity NLs. The effect of the different additionmethods of alkali on the morphological, structural, vibrational, andoptical properties is studied by field emission scanning electronmicroscopy (FESEM), X-ray diffraction (XRD), and Fourier transforminfrared (FT-IR) and ultraviolet−visible (UV−vis) spectroscopies. NLsgrown by alkali addition in a dropwise manner are on average 281, 178,and 17 nm long, wide, and thick, respectively, and composed ofcrystallites of 14 nm corresponding to the crystallographic planes (1̅11)/(002) and (111)/(200). NLs obtained by this method agglomerateforming flower-like nanostructures, exhibiting indirect band gap energy of 1.21 eV. NLs grown by alkali addition in a one-stepmanner are on average significantly bigger, being 602, 219, and 26 nm long, wide, and thick, respectively, composed of crystallites of19 and 16 nm corresponding to the crystallographic planes (1̅11)/(002) and (111)/(200), respectively. These NLs agglomeraterandomly with no predominant form observed, exhibiting indirect band gap energy of 1.39 eV. The addition method of alkali doesnot influence the average crystallite size of NLs, whereas the microstrain distribution is sensitive to the initial concentration of OH−ions. Our results suggest that an indirect electronic transition between the valence and conduction bands might be more feasiblethan a direct one. NLs grown by the one-step method present the highest efficiency as catalyst toward catalytic oxidative degradationof the methyl orange dye with no heating and without the influence of light. Finally, this catalyst is easily recycled several timespreserving its high catalytic activity.
Fil: Londoño Calderon, Cesar Leandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; Argentina
Fil: Menchaca Nal, Sandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; Argentina
Fil: Francois, Nora J.. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; Argentina
Fil: Pampillo, Laura Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long". Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long"; Argentina
Fil: Froimowicz, Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; Argentina
Materia
CHEMICAL DESIGN
NANOPARTICLES
NANOLEAVES
CUPRIC OXIDE
CATALYTIC DEGRADATION
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/129631
Acceder
id CONICETDig_55c6ab650a2ddd61aa386b378c709f51
oai_identifier_str oai:ri.conicet.gov.ar:11336/129631
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Cupric Oxide Nanoleaves for the Oxidative Degradation of Methyl Orange without Heating or LightLondoño Calderon, Cesar LeandroMenchaca Nal, SandraFrancois, Nora J.Pampillo, Laura GabrielaFroimowicz, PabloCHEMICAL DESIGNNANOPARTICLESNANOLEAVESCUPRIC OXIDECATALYTIC DEGRADATIONhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Low-cost 2D cupric oxide nanoleaves (CuO NLs) arestraightforwardly synthesized at room temperature by precipitationvarying the addition method of the alkali. No further treatments arenecessary to obtain high purity NLs. The effect of the different additionmethods of alkali on the morphological, structural, vibrational, andoptical properties is studied by field emission scanning electronmicroscopy (FESEM), X-ray diffraction (XRD), and Fourier transforminfrared (FT-IR) and ultraviolet−visible (UV−vis) spectroscopies. NLsgrown by alkali addition in a dropwise manner are on average 281, 178,and 17 nm long, wide, and thick, respectively, and composed ofcrystallites of 14 nm corresponding to the crystallographic planes (1̅11)/(002) and (111)/(200). NLs obtained by this method agglomerateforming flower-like nanostructures, exhibiting indirect band gap energy of 1.21 eV. NLs grown by alkali addition in a one-stepmanner are on average significantly bigger, being 602, 219, and 26 nm long, wide, and thick, respectively, composed of crystallites of19 and 16 nm corresponding to the crystallographic planes (1̅11)/(002) and (111)/(200), respectively. These NLs agglomeraterandomly with no predominant form observed, exhibiting indirect band gap energy of 1.39 eV. The addition method of alkali doesnot influence the average crystallite size of NLs, whereas the microstrain distribution is sensitive to the initial concentration of OH−ions. Our results suggest that an indirect electronic transition between the valence and conduction bands might be more feasiblethan a direct one. NLs grown by the one-step method present the highest efficiency as catalyst toward catalytic oxidative degradationof the methyl orange dye with no heating and without the influence of light. Finally, this catalyst is easily recycled several timespreserving its high catalytic activity.Fil: Londoño Calderon, Cesar Leandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; ArgentinaFil: Menchaca Nal, Sandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; ArgentinaFil: Francois, Nora J.. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; ArgentinaFil: Pampillo, Laura Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long". Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long"; ArgentinaFil: Froimowicz, Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; ArgentinaAmerican Chemical Society2020-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/129631Londoño Calderon, Cesar Leandro; Menchaca Nal, Sandra; Francois, Nora J.; Pampillo, Laura Gabriela; Froimowicz, Pablo; Cupric Oxide Nanoleaves for the Oxidative Degradation of Methyl Orange without Heating or Light; American Chemical Society; ACS Applied Nano Materials; 3; 3; 2-2020; 2987-29962574-0970CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acsanm.0c00283info:eu-repo/semantics/altIdentifier/doi/10.1021/acsanm.0c00283info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:57:58Zoai:ri.conicet.gov.ar:11336/129631instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:57:58.735CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Cupric Oxide Nanoleaves for the Oxidative Degradation of Methyl Orange without Heating or Light
title Cupric Oxide Nanoleaves for the Oxidative Degradation of Methyl Orange without Heating or Light
spellingShingle Cupric Oxide Nanoleaves for the Oxidative Degradation of Methyl Orange without Heating or Light
Londoño Calderon, Cesar Leandro
CHEMICAL DESIGN
NANOPARTICLES
NANOLEAVES
CUPRIC OXIDE
CATALYTIC DEGRADATION
title_short Cupric Oxide Nanoleaves for the Oxidative Degradation of Methyl Orange without Heating or Light
title_full Cupric Oxide Nanoleaves for the Oxidative Degradation of Methyl Orange without Heating or Light
title_fullStr Cupric Oxide Nanoleaves for the Oxidative Degradation of Methyl Orange without Heating or Light
title_full_unstemmed Cupric Oxide Nanoleaves for the Oxidative Degradation of Methyl Orange without Heating or Light
title_sort Cupric Oxide Nanoleaves for the Oxidative Degradation of Methyl Orange without Heating or Light
dc.creator.none.fl_str_mv Londoño Calderon, Cesar Leandro
Menchaca Nal, Sandra
Francois, Nora J.
Pampillo, Laura Gabriela
Froimowicz, Pablo
author Londoño Calderon, Cesar Leandro
author_facet Londoño Calderon, Cesar Leandro
Menchaca Nal, Sandra
Francois, Nora J.
Pampillo, Laura Gabriela
Froimowicz, Pablo
author_role author
author2 Menchaca Nal, Sandra
Francois, Nora J.
Pampillo, Laura Gabriela
Froimowicz, Pablo
author2_role author
author
author
author
dc.subject.none.fl_str_mv CHEMICAL DESIGN
NANOPARTICLES
NANOLEAVES
CUPRIC OXIDE
CATALYTIC DEGRADATION
topic CHEMICAL DESIGN
NANOPARTICLES
NANOLEAVES
CUPRIC OXIDE
CATALYTIC DEGRADATION
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Low-cost 2D cupric oxide nanoleaves (CuO NLs) arestraightforwardly synthesized at room temperature by precipitationvarying the addition method of the alkali. No further treatments arenecessary to obtain high purity NLs. The effect of the different additionmethods of alkali on the morphological, structural, vibrational, andoptical properties is studied by field emission scanning electronmicroscopy (FESEM), X-ray diffraction (XRD), and Fourier transforminfrared (FT-IR) and ultraviolet−visible (UV−vis) spectroscopies. NLsgrown by alkali addition in a dropwise manner are on average 281, 178,and 17 nm long, wide, and thick, respectively, and composed ofcrystallites of 14 nm corresponding to the crystallographic planes (1̅11)/(002) and (111)/(200). NLs obtained by this method agglomerateforming flower-like nanostructures, exhibiting indirect band gap energy of 1.21 eV. NLs grown by alkali addition in a one-stepmanner are on average significantly bigger, being 602, 219, and 26 nm long, wide, and thick, respectively, composed of crystallites of19 and 16 nm corresponding to the crystallographic planes (1̅11)/(002) and (111)/(200), respectively. These NLs agglomeraterandomly with no predominant form observed, exhibiting indirect band gap energy of 1.39 eV. The addition method of alkali doesnot influence the average crystallite size of NLs, whereas the microstrain distribution is sensitive to the initial concentration of OH−ions. Our results suggest that an indirect electronic transition between the valence and conduction bands might be more feasiblethan a direct one. NLs grown by the one-step method present the highest efficiency as catalyst toward catalytic oxidative degradationof the methyl orange dye with no heating and without the influence of light. Finally, this catalyst is easily recycled several timespreserving its high catalytic activity.
Fil: Londoño Calderon, Cesar Leandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; Argentina
Fil: Menchaca Nal, Sandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; Argentina
Fil: Francois, Nora J.. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; Argentina
Fil: Pampillo, Laura Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long". Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long"; Argentina
Fil: Froimowicz, Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; Argentina
description Low-cost 2D cupric oxide nanoleaves (CuO NLs) arestraightforwardly synthesized at room temperature by precipitationvarying the addition method of the alkali. No further treatments arenecessary to obtain high purity NLs. The effect of the different additionmethods of alkali on the morphological, structural, vibrational, andoptical properties is studied by field emission scanning electronmicroscopy (FESEM), X-ray diffraction (XRD), and Fourier transforminfrared (FT-IR) and ultraviolet−visible (UV−vis) spectroscopies. NLsgrown by alkali addition in a dropwise manner are on average 281, 178,and 17 nm long, wide, and thick, respectively, and composed ofcrystallites of 14 nm corresponding to the crystallographic planes (1̅11)/(002) and (111)/(200). NLs obtained by this method agglomerateforming flower-like nanostructures, exhibiting indirect band gap energy of 1.21 eV. NLs grown by alkali addition in a one-stepmanner are on average significantly bigger, being 602, 219, and 26 nm long, wide, and thick, respectively, composed of crystallites of19 and 16 nm corresponding to the crystallographic planes (1̅11)/(002) and (111)/(200), respectively. These NLs agglomeraterandomly with no predominant form observed, exhibiting indirect band gap energy of 1.39 eV. The addition method of alkali doesnot influence the average crystallite size of NLs, whereas the microstrain distribution is sensitive to the initial concentration of OH−ions. Our results suggest that an indirect electronic transition between the valence and conduction bands might be more feasiblethan a direct one. NLs grown by the one-step method present the highest efficiency as catalyst toward catalytic oxidative degradationof the methyl orange dye with no heating and without the influence of light. Finally, this catalyst is easily recycled several timespreserving its high catalytic activity.
publishDate 2020
dc.date.none.fl_str_mv 2020-02
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/129631
Londoño Calderon, Cesar Leandro; Menchaca Nal, Sandra; Francois, Nora J.; Pampillo, Laura Gabriela; Froimowicz, Pablo; Cupric Oxide Nanoleaves for the Oxidative Degradation of Methyl Orange without Heating or Light; American Chemical Society; ACS Applied Nano Materials; 3; 3; 2-2020; 2987-2996
2574-0970
CONICET Digital
CONICET
url http://hdl.handle.net/11336/129631
identifier_str_mv Londoño Calderon, Cesar Leandro; Menchaca Nal, Sandra; Francois, Nora J.; Pampillo, Laura Gabriela; Froimowicz, Pablo; Cupric Oxide Nanoleaves for the Oxidative Degradation of Methyl Orange without Heating or Light; American Chemical Society; ACS Applied Nano Materials; 3; 3; 2-2020; 2987-2996
2574-0970
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acsanm.0c00283
info:eu-repo/semantics/altIdentifier/doi/10.1021/acsanm.0c00283
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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