Influence of the synthesis method of layered double hydroxides on the textural properties and nitrate removal

Autores
Cano, Leonardo Andres; Barrera Diaz, Deicy Amparo; Villarroel Rocha, Jhonny; Sapag, Manuel Karim
Año de publicación
2023
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Layered double hydroxides were prepared by co-precipitating Mg2+ and Al3+ ions at constant pH. Three different methods of solution additions and two temperatures for synthesis and aging were tested in each method. Through X-ray diffraction, it was confirmed that all the synthesized solids have a hydrotalcite-type structure, obtaining more crystalline compounds when one solution of Mg/Al is added to another whit CO3-/OH- and compounds with greater interlaminar spacing when three different solutions are added (Mg/Al, CO3- and OH-). In addition, the solids obtained by this last method have a higher specific surface area and total pore volume, as confirmed by the N2 adsorption-desorption. A similar trend occurs with synthesis and aging temperatures where better textural properties are obtained at a higher temperature, reaching surface area values of 242 m2/g and pore volume of 0,93 cm3/g. All the synthesized solids were active for removing nitrates in water, obtaining the best results with the samples prepared by dripping three different solutions at 60 °C (26 mgNO3-/g.) This fact demonstrates the correlation between the synthesis method and the textural properties of the material with its potential application in removing contaminants.
Fil: Cano, Leonardo Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Barrera Diaz, Deicy Amparo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina
Fil: Villarroel Rocha, Jhonny. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina
Fil: Sapag, Manuel Karim. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina
Materia
ADSORPTION
LAYERED DOUBLE HYDROXIDES
NITRATE REMOVAL
SYNTHESIS
TEXTURAL PROPERTIES
WATER
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/227974
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/227974
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Influence of the synthesis method of layered double hydroxides on the textural properties and nitrate removalCano, Leonardo AndresBarrera Diaz, Deicy AmparoVillarroel Rocha, JhonnySapag, Manuel KarimADSORPTIONLAYERED DOUBLE HYDROXIDESNITRATE REMOVALSYNTHESISTEXTURAL PROPERTIESWATERhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1https://purl.org/becyt/ford/2.10https://purl.org/becyt/ford/2https://purl.org/becyt/ford/2.7https://purl.org/becyt/ford/2Layered double hydroxides were prepared by co-precipitating Mg2+ and Al3+ ions at constant pH. Three different methods of solution additions and two temperatures for synthesis and aging were tested in each method. Through X-ray diffraction, it was confirmed that all the synthesized solids have a hydrotalcite-type structure, obtaining more crystalline compounds when one solution of Mg/Al is added to another whit CO3-/OH- and compounds with greater interlaminar spacing when three different solutions are added (Mg/Al, CO3- and OH-). In addition, the solids obtained by this last method have a higher specific surface area and total pore volume, as confirmed by the N2 adsorption-desorption. A similar trend occurs with synthesis and aging temperatures where better textural properties are obtained at a higher temperature, reaching surface area values of 242 m2/g and pore volume of 0,93 cm3/g. All the synthesized solids were active for removing nitrates in water, obtaining the best results with the samples prepared by dripping three different solutions at 60 °C (26 mgNO3-/g.) This fact demonstrates the correlation between the synthesis method and the textural properties of the material with its potential application in removing contaminants.Fil: Cano, Leonardo Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Barrera Diaz, Deicy Amparo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; ArgentinaFil: Villarroel Rocha, Jhonny. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; ArgentinaFil: Sapag, Manuel Karim. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; ArgentinaElsevier Science2023-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/227974Cano, Leonardo Andres; Barrera Diaz, Deicy Amparo; Villarroel Rocha, Jhonny; Sapag, Manuel Karim; Influence of the synthesis method of layered double hydroxides on the textural properties and nitrate removal; Elsevier Science; Catalysis Today; 422; 5-2023; 1-220920-5861CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S0920586123002468info:eu-repo/semantics/altIdentifier/doi/10.1016/j.cattod.2023.114222info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:54:46Zoai:ri.conicet.gov.ar:11336/227974instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:54:46.872CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Influence of the synthesis method of layered double hydroxides on the textural properties and nitrate removal
title Influence of the synthesis method of layered double hydroxides on the textural properties and nitrate removal
spellingShingle Influence of the synthesis method of layered double hydroxides on the textural properties and nitrate removal
Cano, Leonardo Andres
ADSORPTION
LAYERED DOUBLE HYDROXIDES
NITRATE REMOVAL
SYNTHESIS
TEXTURAL PROPERTIES
WATER
title_short Influence of the synthesis method of layered double hydroxides on the textural properties and nitrate removal
title_full Influence of the synthesis method of layered double hydroxides on the textural properties and nitrate removal
title_fullStr Influence of the synthesis method of layered double hydroxides on the textural properties and nitrate removal
title_full_unstemmed Influence of the synthesis method of layered double hydroxides on the textural properties and nitrate removal
title_sort Influence of the synthesis method of layered double hydroxides on the textural properties and nitrate removal
dc.creator.none.fl_str_mv Cano, Leonardo Andres
Barrera Diaz, Deicy Amparo
Villarroel Rocha, Jhonny
Sapag, Manuel Karim
author Cano, Leonardo Andres
author_facet Cano, Leonardo Andres
Barrera Diaz, Deicy Amparo
Villarroel Rocha, Jhonny
Sapag, Manuel Karim
author_role author
author2 Barrera Diaz, Deicy Amparo
Villarroel Rocha, Jhonny
Sapag, Manuel Karim
author2_role author
author
author
dc.subject.none.fl_str_mv ADSORPTION
LAYERED DOUBLE HYDROXIDES
NITRATE REMOVAL
SYNTHESIS
TEXTURAL PROPERTIES
WATER
topic ADSORPTION
LAYERED DOUBLE HYDROXIDES
NITRATE REMOVAL
SYNTHESIS
TEXTURAL PROPERTIES
WATER
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
https://purl.org/becyt/ford/2.10
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/2.7
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Layered double hydroxides were prepared by co-precipitating Mg2+ and Al3+ ions at constant pH. Three different methods of solution additions and two temperatures for synthesis and aging were tested in each method. Through X-ray diffraction, it was confirmed that all the synthesized solids have a hydrotalcite-type structure, obtaining more crystalline compounds when one solution of Mg/Al is added to another whit CO3-/OH- and compounds with greater interlaminar spacing when three different solutions are added (Mg/Al, CO3- and OH-). In addition, the solids obtained by this last method have a higher specific surface area and total pore volume, as confirmed by the N2 adsorption-desorption. A similar trend occurs with synthesis and aging temperatures where better textural properties are obtained at a higher temperature, reaching surface area values of 242 m2/g and pore volume of 0,93 cm3/g. All the synthesized solids were active for removing nitrates in water, obtaining the best results with the samples prepared by dripping three different solutions at 60 °C (26 mgNO3-/g.) This fact demonstrates the correlation between the synthesis method and the textural properties of the material with its potential application in removing contaminants.
Fil: Cano, Leonardo Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Barrera Diaz, Deicy Amparo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina
Fil: Villarroel Rocha, Jhonny. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina
Fil: Sapag, Manuel Karim. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina
description Layered double hydroxides were prepared by co-precipitating Mg2+ and Al3+ ions at constant pH. Three different methods of solution additions and two temperatures for synthesis and aging were tested in each method. Through X-ray diffraction, it was confirmed that all the synthesized solids have a hydrotalcite-type structure, obtaining more crystalline compounds when one solution of Mg/Al is added to another whit CO3-/OH- and compounds with greater interlaminar spacing when three different solutions are added (Mg/Al, CO3- and OH-). In addition, the solids obtained by this last method have a higher specific surface area and total pore volume, as confirmed by the N2 adsorption-desorption. A similar trend occurs with synthesis and aging temperatures where better textural properties are obtained at a higher temperature, reaching surface area values of 242 m2/g and pore volume of 0,93 cm3/g. All the synthesized solids were active for removing nitrates in water, obtaining the best results with the samples prepared by dripping three different solutions at 60 °C (26 mgNO3-/g.) This fact demonstrates the correlation between the synthesis method and the textural properties of the material with its potential application in removing contaminants.
publishDate 2023
dc.date.none.fl_str_mv 2023-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/227974
Cano, Leonardo Andres; Barrera Diaz, Deicy Amparo; Villarroel Rocha, Jhonny; Sapag, Manuel Karim; Influence of the synthesis method of layered double hydroxides on the textural properties and nitrate removal; Elsevier Science; Catalysis Today; 422; 5-2023; 1-22
0920-5861
CONICET Digital
CONICET
url http://hdl.handle.net/11336/227974
identifier_str_mv Cano, Leonardo Andres; Barrera Diaz, Deicy Amparo; Villarroel Rocha, Jhonny; Sapag, Manuel Karim; Influence of the synthesis method of layered double hydroxides on the textural properties and nitrate removal; Elsevier Science; Catalysis Today; 422; 5-2023; 1-22
0920-5861
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S0920586123002468
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.cattod.2023.114222
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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