Quantification of hydrogen peroxide using poly Fe (III)-5-Amino 1,10 phenantroline

Autores
Lozano, María Luisa C.; Galicia, Laura; Rodriguez, Marcela Cecilia; Rivas, Gustavo Adolfo
Año de publicación
2009
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
This work reports the results obtained with a composite prepared by dispersing multiple-wall carbon nanotubes in mineral oil (CNTPE) modified with a polymeric matrix of poly Fe(III)-5- Amino 1,10 phenanthroline (MCNTPE). The MCNTPE was used as electrochemical sensor for hydrogen peroxide quantification based on the polymer electrocatalytic effects. The amperometric response to H2O2 on MCNTPE was evaluated at -0,100 and 0,700 V vs Ag/AgCl. At -0,100 V, the sensitivity of the MCNTPE was increased by a factor of 2 orders of magnitude in comparison with the one obtained at CNTPE. At 700 mV, the sensitivity of the modified electrode was increased by a factor of 268 with respect to the non-modified electrode. The sensor also demonstrated to be very stable after continuous use. These results show that a new composite with remarkable electrocatalytic properties can be proposed for the future development of electrochemical (bio)sensors for the quantification of hydrogen peroxide.
Fil: Lozano, María Luisa C.. Universidad Autónoma Metropolitana; México
Fil: Galicia, Laura. Universidad Autónoma Metropolitana; México
Fil: Rodriguez, Marcela Cecilia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Rivas, Gustavo Adolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Materia
Carbon Nanotubes
Poly Fe(Iii)-5- Amino 1,10 Phenanthroline
Electrochemical Sensor
Hydrogen Peroxide
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/113769
Acceder
id CONICETDig_dacdc0aca61fda4ed4766f7bc57ff37a
oai_identifier_str oai:ri.conicet.gov.ar:11336/113769
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Quantification of hydrogen peroxide using poly Fe (III)-5-Amino 1,10 phenantrolineLozano, María Luisa C.Galicia, LauraRodriguez, Marcela CeciliaRivas, Gustavo AdolfoCarbon NanotubesPoly Fe(Iii)-5- Amino 1,10 PhenanthrolineElectrochemical SensorHydrogen Peroxidehttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1This work reports the results obtained with a composite prepared by dispersing multiple-wall carbon nanotubes in mineral oil (CNTPE) modified with a polymeric matrix of poly Fe(III)-5- Amino 1,10 phenanthroline (MCNTPE). The MCNTPE was used as electrochemical sensor for hydrogen peroxide quantification based on the polymer electrocatalytic effects. The amperometric response to H2O2 on MCNTPE was evaluated at -0,100 and 0,700 V vs Ag/AgCl. At -0,100 V, the sensitivity of the MCNTPE was increased by a factor of 2 orders of magnitude in comparison with the one obtained at CNTPE. At 700 mV, the sensitivity of the modified electrode was increased by a factor of 268 with respect to the non-modified electrode. The sensor also demonstrated to be very stable after continuous use. These results show that a new composite with remarkable electrocatalytic properties can be proposed for the future development of electrochemical (bio)sensors for the quantification of hydrogen peroxide.Fil: Lozano, María Luisa C.. Universidad Autónoma Metropolitana; MéxicoFil: Galicia, Laura. Universidad Autónoma Metropolitana; MéxicoFil: Rodriguez, Marcela Cecilia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Rivas, Gustavo Adolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaThe Electrochemical Society2009-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/113769Lozano, María Luisa C.; Galicia, Laura; Rodriguez, Marcela Cecilia; Rivas, Gustavo Adolfo; Quantification of hydrogen peroxide using poly Fe (III)-5-Amino 1,10 phenantroline; The Electrochemical Society; ECS Transactions; 20; 1; 6-2009; 41-481938-58621938-6737CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1149/1.3268371info:eu-repo/semantics/altIdentifier/url/https://iopscience.iop.org/article/10.1149/1.3268371info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:14:54Zoai:ri.conicet.gov.ar:11336/113769instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:14:54.416CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Quantification of hydrogen peroxide using poly Fe (III)-5-Amino 1,10 phenantroline
title Quantification of hydrogen peroxide using poly Fe (III)-5-Amino 1,10 phenantroline
spellingShingle Quantification of hydrogen peroxide using poly Fe (III)-5-Amino 1,10 phenantroline
Lozano, María Luisa C.
Carbon Nanotubes
Poly Fe(Iii)-5- Amino 1,10 Phenanthroline
Electrochemical Sensor
Hydrogen Peroxide
title_short Quantification of hydrogen peroxide using poly Fe (III)-5-Amino 1,10 phenantroline
title_full Quantification of hydrogen peroxide using poly Fe (III)-5-Amino 1,10 phenantroline
title_fullStr Quantification of hydrogen peroxide using poly Fe (III)-5-Amino 1,10 phenantroline
title_full_unstemmed Quantification of hydrogen peroxide using poly Fe (III)-5-Amino 1,10 phenantroline
title_sort Quantification of hydrogen peroxide using poly Fe (III)-5-Amino 1,10 phenantroline
dc.creator.none.fl_str_mv Lozano, María Luisa C.
Galicia, Laura
Rodriguez, Marcela Cecilia
Rivas, Gustavo Adolfo
author Lozano, María Luisa C.
author_facet Lozano, María Luisa C.
Galicia, Laura
Rodriguez, Marcela Cecilia
Rivas, Gustavo Adolfo
author_role author
author2 Galicia, Laura
Rodriguez, Marcela Cecilia
Rivas, Gustavo Adolfo
author2_role author
author
author
dc.subject.none.fl_str_mv Carbon Nanotubes
Poly Fe(Iii)-5- Amino 1,10 Phenanthroline
Electrochemical Sensor
Hydrogen Peroxide
topic Carbon Nanotubes
Poly Fe(Iii)-5- Amino 1,10 Phenanthroline
Electrochemical Sensor
Hydrogen Peroxide
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv This work reports the results obtained with a composite prepared by dispersing multiple-wall carbon nanotubes in mineral oil (CNTPE) modified with a polymeric matrix of poly Fe(III)-5- Amino 1,10 phenanthroline (MCNTPE). The MCNTPE was used as electrochemical sensor for hydrogen peroxide quantification based on the polymer electrocatalytic effects. The amperometric response to H2O2 on MCNTPE was evaluated at -0,100 and 0,700 V vs Ag/AgCl. At -0,100 V, the sensitivity of the MCNTPE was increased by a factor of 2 orders of magnitude in comparison with the one obtained at CNTPE. At 700 mV, the sensitivity of the modified electrode was increased by a factor of 268 with respect to the non-modified electrode. The sensor also demonstrated to be very stable after continuous use. These results show that a new composite with remarkable electrocatalytic properties can be proposed for the future development of electrochemical (bio)sensors for the quantification of hydrogen peroxide.
Fil: Lozano, María Luisa C.. Universidad Autónoma Metropolitana; México
Fil: Galicia, Laura. Universidad Autónoma Metropolitana; México
Fil: Rodriguez, Marcela Cecilia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Rivas, Gustavo Adolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
description This work reports the results obtained with a composite prepared by dispersing multiple-wall carbon nanotubes in mineral oil (CNTPE) modified with a polymeric matrix of poly Fe(III)-5- Amino 1,10 phenanthroline (MCNTPE). The MCNTPE was used as electrochemical sensor for hydrogen peroxide quantification based on the polymer electrocatalytic effects. The amperometric response to H2O2 on MCNTPE was evaluated at -0,100 and 0,700 V vs Ag/AgCl. At -0,100 V, the sensitivity of the MCNTPE was increased by a factor of 2 orders of magnitude in comparison with the one obtained at CNTPE. At 700 mV, the sensitivity of the modified electrode was increased by a factor of 268 with respect to the non-modified electrode. The sensor also demonstrated to be very stable after continuous use. These results show that a new composite with remarkable electrocatalytic properties can be proposed for the future development of electrochemical (bio)sensors for the quantification of hydrogen peroxide.
publishDate 2009
dc.date.none.fl_str_mv 2009-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/113769
Lozano, María Luisa C.; Galicia, Laura; Rodriguez, Marcela Cecilia; Rivas, Gustavo Adolfo; Quantification of hydrogen peroxide using poly Fe (III)-5-Amino 1,10 phenantroline; The Electrochemical Society; ECS Transactions; 20; 1; 6-2009; 41-48
1938-5862
1938-6737
CONICET Digital
CONICET
url http://hdl.handle.net/11336/113769
identifier_str_mv Lozano, María Luisa C.; Galicia, Laura; Rodriguez, Marcela Cecilia; Rivas, Gustavo Adolfo; Quantification of hydrogen peroxide using poly Fe (III)-5-Amino 1,10 phenantroline; The Electrochemical Society; ECS Transactions; 20; 1; 6-2009; 41-48
1938-5862
1938-6737
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1149/1.3268371
info:eu-repo/semantics/altIdentifier/url/https://iopscience.iop.org/article/10.1149/1.3268371
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv The Electrochemical Society
publisher.none.fl_str_mv The Electrochemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844614080616202240
score 13.070432

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