Electrogenerated Conductive Polymers from Triphenylamine End-Capped Dendrimers

Autores
Mangione, Maria Ines; Spanevello, Rolando Angel; Rumbero, Angel; Heredia, Daniel Alejandro; Marzari, Gabriela Lorena; Fernandez, Luciana Andrea; Otero, Luis Alberto; Fungo, Fernando Gabriel
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Electroactive end-capped dendritic macromolecules were designed and synthesized. Their structures contain triphenylamine moieties as part of the core or dendrons. The electrogenerated films produced with these monomers behaved as conductive dendritic polymers that can be reversible charged, both in the core and in the peripheral units. The design of dendrimer structures with the introduction of systematic changes allows to establish relationships between their electro-optical properties with molecular structural parameters. The films of polymeric material hold good electrical conductivity, reversible electrochemical processes and chemical stability. The results indicate that the use of conjugated and rigid structures in dendritic macromolecules is an important factor in order to obtain electropolymeric films. This work provides a model to design starburst dendrimers capable to form electrochemically active polymers with potential applications in electronic and optoelectronic devices.
Fil: Mangione, Maria Ines. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Rosario. Instituto de Química Rosario; Argentina
Fil: Spanevello, Rolando Angel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Rosario. Instituto de Química Rosario; Argentina
Fil: Rumbero, Angel. Universidad Autónoma de Madrid; España
Fil: Heredia, Daniel Alejandro. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina
Fil: Marzari, Gabriela Lorena. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina
Fil: Fernandez, Luciana Andrea. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina
Fil: Otero, Luis Alberto. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina
Fil: Fungo, Fernando Gabriel. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina
Materia
Conductive Polymers
Triphenylamine
Dendrimer
Macromolecules
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/6086
Acceder
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spelling Electrogenerated Conductive Polymers from Triphenylamine End-Capped DendrimersMangione, Maria InesSpanevello, Rolando AngelRumbero, AngelHeredia, Daniel AlejandroMarzari, Gabriela LorenaFernandez, Luciana AndreaOtero, Luis AlbertoFungo, Fernando GabrielConductive PolymersTriphenylamineDendrimerMacromoleculeshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Electroactive end-capped dendritic macromolecules were designed and synthesized. Their structures contain triphenylamine moieties as part of the core or dendrons. The electrogenerated films produced with these monomers behaved as conductive dendritic polymers that can be reversible charged, both in the core and in the peripheral units. The design of dendrimer structures with the introduction of systematic changes allows to establish relationships between their electro-optical properties with molecular structural parameters. The films of polymeric material hold good electrical conductivity, reversible electrochemical processes and chemical stability. The results indicate that the use of conjugated and rigid structures in dendritic macromolecules is an important factor in order to obtain electropolymeric films. This work provides a model to design starburst dendrimers capable to form electrochemically active polymers with potential applications in electronic and optoelectronic devices.Fil: Mangione, Maria Ines. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Rosario. Instituto de Química Rosario; ArgentinaFil: Spanevello, Rolando Angel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Rosario. Instituto de Química Rosario; ArgentinaFil: Rumbero, Angel. Universidad Autónoma de Madrid; EspañaFil: Heredia, Daniel Alejandro. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; ArgentinaFil: Marzari, Gabriela Lorena. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; ArgentinaFil: Fernandez, Luciana Andrea. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; ArgentinaFil: Otero, Luis Alberto. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; ArgentinaFil: Fungo, Fernando Gabriel. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; ArgentinaAmerican Chemical Society2013-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/6086Mangione, Maria Ines; Spanevello, Rolando Angel; Rumbero, Angel; Heredia, Daniel Alejandro; Marzari, Gabriela Lorena; et al.; Electrogenerated Conductive Polymers from Triphenylamine End-Capped Dendrimers; American Chemical Society; Macromolecules; 46; 12; 5-2013; 4754-47630024-9297enginfo:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/ipdf/10.1021/ma401085qinfo:eu-repo/semantics/altIdentifier/doi/10.1021/ma401085qinfo:eu-repo/semantics/altIdentifier/doi/info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T15:29:17Zoai:ri.conicet.gov.ar:11336/6086instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 15:29:17.99CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Electrogenerated Conductive Polymers from Triphenylamine End-Capped Dendrimers
title Electrogenerated Conductive Polymers from Triphenylamine End-Capped Dendrimers
spellingShingle Electrogenerated Conductive Polymers from Triphenylamine End-Capped Dendrimers
Mangione, Maria Ines
Conductive Polymers
Triphenylamine
Dendrimer
Macromolecules
title_short Electrogenerated Conductive Polymers from Triphenylamine End-Capped Dendrimers
title_full Electrogenerated Conductive Polymers from Triphenylamine End-Capped Dendrimers
title_fullStr Electrogenerated Conductive Polymers from Triphenylamine End-Capped Dendrimers
title_full_unstemmed Electrogenerated Conductive Polymers from Triphenylamine End-Capped Dendrimers
title_sort Electrogenerated Conductive Polymers from Triphenylamine End-Capped Dendrimers
dc.creator.none.fl_str_mv Mangione, Maria Ines
Spanevello, Rolando Angel
Rumbero, Angel
Heredia, Daniel Alejandro
Marzari, Gabriela Lorena
Fernandez, Luciana Andrea
Otero, Luis Alberto
Fungo, Fernando Gabriel
author Mangione, Maria Ines
author_facet Mangione, Maria Ines
Spanevello, Rolando Angel
Rumbero, Angel
Heredia, Daniel Alejandro
Marzari, Gabriela Lorena
Fernandez, Luciana Andrea
Otero, Luis Alberto
Fungo, Fernando Gabriel
author_role author
author2 Spanevello, Rolando Angel
Rumbero, Angel
Heredia, Daniel Alejandro
Marzari, Gabriela Lorena
Fernandez, Luciana Andrea
Otero, Luis Alberto
Fungo, Fernando Gabriel
author2_role author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Conductive Polymers
Triphenylamine
Dendrimer
Macromolecules
topic Conductive Polymers
Triphenylamine
Dendrimer
Macromolecules
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Electroactive end-capped dendritic macromolecules were designed and synthesized. Their structures contain triphenylamine moieties as part of the core or dendrons. The electrogenerated films produced with these monomers behaved as conductive dendritic polymers that can be reversible charged, both in the core and in the peripheral units. The design of dendrimer structures with the introduction of systematic changes allows to establish relationships between their electro-optical properties with molecular structural parameters. The films of polymeric material hold good electrical conductivity, reversible electrochemical processes and chemical stability. The results indicate that the use of conjugated and rigid structures in dendritic macromolecules is an important factor in order to obtain electropolymeric films. This work provides a model to design starburst dendrimers capable to form electrochemically active polymers with potential applications in electronic and optoelectronic devices.
Fil: Mangione, Maria Ines. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Rosario. Instituto de Química Rosario; Argentina
Fil: Spanevello, Rolando Angel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Rosario. Instituto de Química Rosario; Argentina
Fil: Rumbero, Angel. Universidad Autónoma de Madrid; España
Fil: Heredia, Daniel Alejandro. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina
Fil: Marzari, Gabriela Lorena. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina
Fil: Fernandez, Luciana Andrea. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina
Fil: Otero, Luis Alberto. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina
Fil: Fungo, Fernando Gabriel. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina
description Electroactive end-capped dendritic macromolecules were designed and synthesized. Their structures contain triphenylamine moieties as part of the core or dendrons. The electrogenerated films produced with these monomers behaved as conductive dendritic polymers that can be reversible charged, both in the core and in the peripheral units. The design of dendrimer structures with the introduction of systematic changes allows to establish relationships between their electro-optical properties with molecular structural parameters. The films of polymeric material hold good electrical conductivity, reversible electrochemical processes and chemical stability. The results indicate that the use of conjugated and rigid structures in dendritic macromolecules is an important factor in order to obtain electropolymeric films. This work provides a model to design starburst dendrimers capable to form electrochemically active polymers with potential applications in electronic and optoelectronic devices.
publishDate 2013
dc.date.none.fl_str_mv 2013-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/6086
Mangione, Maria Ines; Spanevello, Rolando Angel; Rumbero, Angel; Heredia, Daniel Alejandro; Marzari, Gabriela Lorena; et al.; Electrogenerated Conductive Polymers from Triphenylamine End-Capped Dendrimers; American Chemical Society; Macromolecules; 46; 12; 5-2013; 4754-4763
0024-9297
url http://hdl.handle.net/11336/6086
identifier_str_mv Mangione, Maria Ines; Spanevello, Rolando Angel; Rumbero, Angel; Heredia, Daniel Alejandro; Marzari, Gabriela Lorena; et al.; Electrogenerated Conductive Polymers from Triphenylamine End-Capped Dendrimers; American Chemical Society; Macromolecules; 46; 12; 5-2013; 4754-4763
0024-9297
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/ipdf/10.1021/ma401085q
info:eu-repo/semantics/altIdentifier/doi/10.1021/ma401085q
info:eu-repo/semantics/altIdentifier/doi/
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
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application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.22299

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