Dense mullite zirconia composites obtained from the reaction sintering of milled stoichiometric alumina zircon mixtures by SPS

Autores
Rendtorff Birrer, Nicolás Maximiliano; Suarez, Gustavo; Sakka, Yoshio; Aglietti, Esteban Fausto
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The main objective of this article is to obtain dense (porosity under 0.5%) polyphasic ceramics belonging to the Al2O3–SiO2–ZrO2 system by SPS sintering of high energy powders milled drily; the stoichiometric (54.45:45.54 zircon–alumina, weight basis) mixture was explored in this work. Particularly the principal sintering variables: sintering temperature and dwell time were investigated. The textural, structural and microstructural changes were evaluated together with the hardness and toughness of the obtained ceramics and their microstructure. The effect of the mechanical pre-treatment was carried out by X-ray diffraction and particle distribution evaluation. Due to the rapid heating process an incomplete reaction was achieved in several cases, as a consequence multiphasic ceramics with different alumina, mullite, zircon and zirconia contents were obtained. The mechanical pretreatment used resulted in a homogeneous dry mixture with a partial (≈20%) zircon dissociation, apparently enhanced by the alumina presence. This together with the posterior SPS processing permitted to obtain fully dense ceramic composites at a very low temperature (1300 °C) without the requirement of any additive. The reactions from alumina zircon mixtures to mullite zirconia occur 200 °C below conventional processing routes and at least 50 °C below the reported SPS based materials processed from un-milled mixtures. The microstructure and mechanical properties obtained were comparable to the ones obtained by other processing routes. Finally some interesting group correlations were found for the developed materials while the hardness is directly correlated with the density and the fracture toughness is correlated with the zirconia (m+t) content.
Fil: Rendtorff Birrer, Nicolás Maximiliano. Provincia de Buenos Aires. Gobernación. Comision de Invest.científicas. Centro de Tecnología de Recursos Minerales y Ceramica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - la Plata. Centro de Tecnología de Recursos Minerales y Ceramica; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química; Argentina
Fil: Suarez, Gustavo. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química; Argentina. Tsukuba University. National Institute For Materials Science; Japón. Provincia de Buenos Aires. Gobernación. Comision de Invest.científicas. Centro de Tecnología de Recursos Minerales y Ceramica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - la Plata. Centro de Tecnología de Recursos Minerales y Ceramica; Argentina
Fil: Sakka, Yoshio. Tsukuba University. National Institute For Materials Science; Japón
Fil: Aglietti, Esteban Fausto. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química; Argentina. Provincia de Buenos Aires. Gobernación. Comision de Invest.científicas. Centro de Tecnología de Recursos Minerales y Ceramica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - la Plata. Centro de Tecnología de Recursos Minerales y Ceramica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Materia
B. Composites
D. Mullite
Zirconia
Reaction Sintering
Sps
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/32389
Acceder
id CONICETDig_d6be9ad33ef5aed9c998c98123100683
oai_identifier_str oai:ri.conicet.gov.ar:11336/32389
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Dense mullite zirconia composites obtained from the reaction sintering of milled stoichiometric alumina zircon mixtures by SPSRendtorff Birrer, Nicolás MaximilianoSuarez, GustavoSakka, YoshioAglietti, Esteban FaustoB. CompositesD. MulliteZirconiaReaction SinteringSpshttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2The main objective of this article is to obtain dense (porosity under 0.5%) polyphasic ceramics belonging to the Al2O3–SiO2–ZrO2 system by SPS sintering of high energy powders milled drily; the stoichiometric (54.45:45.54 zircon–alumina, weight basis) mixture was explored in this work. Particularly the principal sintering variables: sintering temperature and dwell time were investigated. The textural, structural and microstructural changes were evaluated together with the hardness and toughness of the obtained ceramics and their microstructure. The effect of the mechanical pre-treatment was carried out by X-ray diffraction and particle distribution evaluation. Due to the rapid heating process an incomplete reaction was achieved in several cases, as a consequence multiphasic ceramics with different alumina, mullite, zircon and zirconia contents were obtained. The mechanical pretreatment used resulted in a homogeneous dry mixture with a partial (≈20%) zircon dissociation, apparently enhanced by the alumina presence. This together with the posterior SPS processing permitted to obtain fully dense ceramic composites at a very low temperature (1300 °C) without the requirement of any additive. The reactions from alumina zircon mixtures to mullite zirconia occur 200 °C below conventional processing routes and at least 50 °C below the reported SPS based materials processed from un-milled mixtures. The microstructure and mechanical properties obtained were comparable to the ones obtained by other processing routes. Finally some interesting group correlations were found for the developed materials while the hardness is directly correlated with the density and the fracture toughness is correlated with the zirconia (m+t) content.Fil: Rendtorff Birrer, Nicolás Maximiliano. Provincia de Buenos Aires. Gobernación. Comision de Invest.científicas. Centro de Tecnología de Recursos Minerales y Ceramica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - la Plata. Centro de Tecnología de Recursos Minerales y Ceramica; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química; ArgentinaFil: Suarez, Gustavo. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química; Argentina. Tsukuba University. National Institute For Materials Science; Japón. Provincia de Buenos Aires. Gobernación. Comision de Invest.científicas. Centro de Tecnología de Recursos Minerales y Ceramica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - la Plata. Centro de Tecnología de Recursos Minerales y Ceramica; ArgentinaFil: Sakka, Yoshio. Tsukuba University. National Institute For Materials Science; JapónFil: Aglietti, Esteban Fausto. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química; Argentina. Provincia de Buenos Aires. Gobernación. Comision de Invest.científicas. Centro de Tecnología de Recursos Minerales y Ceramica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - la Plata. Centro de Tecnología de Recursos Minerales y Ceramica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaElsevier2014-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/32389Aglietti, Esteban Fausto; Sakka, Yoshio; Suarez, Gustavo; Rendtorff Birrer, Nicolás Maximiliano; Dense mullite zirconia composites obtained from the reaction sintering of milled stoichiometric alumina zircon mixtures by SPS; Elsevier; Ceramics International; 40; 3; 1-2014; 4461-44700272-8842CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.ceramint.2013.08.119info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S027288421301078Xinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:12:00Zoai:ri.conicet.gov.ar:11336/32389instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:12:00.31CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Dense mullite zirconia composites obtained from the reaction sintering of milled stoichiometric alumina zircon mixtures by SPS
title Dense mullite zirconia composites obtained from the reaction sintering of milled stoichiometric alumina zircon mixtures by SPS
spellingShingle Dense mullite zirconia composites obtained from the reaction sintering of milled stoichiometric alumina zircon mixtures by SPS
Rendtorff Birrer, Nicolás Maximiliano
B. Composites
D. Mullite
Zirconia
Reaction Sintering
Sps
title_short Dense mullite zirconia composites obtained from the reaction sintering of milled stoichiometric alumina zircon mixtures by SPS
title_full Dense mullite zirconia composites obtained from the reaction sintering of milled stoichiometric alumina zircon mixtures by SPS
title_fullStr Dense mullite zirconia composites obtained from the reaction sintering of milled stoichiometric alumina zircon mixtures by SPS
title_full_unstemmed Dense mullite zirconia composites obtained from the reaction sintering of milled stoichiometric alumina zircon mixtures by SPS
title_sort Dense mullite zirconia composites obtained from the reaction sintering of milled stoichiometric alumina zircon mixtures by SPS
dc.creator.none.fl_str_mv Rendtorff Birrer, Nicolás Maximiliano
Suarez, Gustavo
Sakka, Yoshio
Aglietti, Esteban Fausto
author Rendtorff Birrer, Nicolás Maximiliano
author_facet Rendtorff Birrer, Nicolás Maximiliano
Suarez, Gustavo
Sakka, Yoshio
Aglietti, Esteban Fausto
author_role author
author2 Suarez, Gustavo
Sakka, Yoshio
Aglietti, Esteban Fausto
author2_role author
author
author
dc.subject.none.fl_str_mv B. Composites
D. Mullite
Zirconia
Reaction Sintering
Sps
topic B. Composites
D. Mullite
Zirconia
Reaction Sintering
Sps
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The main objective of this article is to obtain dense (porosity under 0.5%) polyphasic ceramics belonging to the Al2O3–SiO2–ZrO2 system by SPS sintering of high energy powders milled drily; the stoichiometric (54.45:45.54 zircon–alumina, weight basis) mixture was explored in this work. Particularly the principal sintering variables: sintering temperature and dwell time were investigated. The textural, structural and microstructural changes were evaluated together with the hardness and toughness of the obtained ceramics and their microstructure. The effect of the mechanical pre-treatment was carried out by X-ray diffraction and particle distribution evaluation. Due to the rapid heating process an incomplete reaction was achieved in several cases, as a consequence multiphasic ceramics with different alumina, mullite, zircon and zirconia contents were obtained. The mechanical pretreatment used resulted in a homogeneous dry mixture with a partial (≈20%) zircon dissociation, apparently enhanced by the alumina presence. This together with the posterior SPS processing permitted to obtain fully dense ceramic composites at a very low temperature (1300 °C) without the requirement of any additive. The reactions from alumina zircon mixtures to mullite zirconia occur 200 °C below conventional processing routes and at least 50 °C below the reported SPS based materials processed from un-milled mixtures. The microstructure and mechanical properties obtained were comparable to the ones obtained by other processing routes. Finally some interesting group correlations were found for the developed materials while the hardness is directly correlated with the density and the fracture toughness is correlated with the zirconia (m+t) content.
Fil: Rendtorff Birrer, Nicolás Maximiliano. Provincia de Buenos Aires. Gobernación. Comision de Invest.científicas. Centro de Tecnología de Recursos Minerales y Ceramica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - la Plata. Centro de Tecnología de Recursos Minerales y Ceramica; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química; Argentina
Fil: Suarez, Gustavo. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química; Argentina. Tsukuba University. National Institute For Materials Science; Japón. Provincia de Buenos Aires. Gobernación. Comision de Invest.científicas. Centro de Tecnología de Recursos Minerales y Ceramica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - la Plata. Centro de Tecnología de Recursos Minerales y Ceramica; Argentina
Fil: Sakka, Yoshio. Tsukuba University. National Institute For Materials Science; Japón
Fil: Aglietti, Esteban Fausto. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química; Argentina. Provincia de Buenos Aires. Gobernación. Comision de Invest.científicas. Centro de Tecnología de Recursos Minerales y Ceramica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - la Plata. Centro de Tecnología de Recursos Minerales y Ceramica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
description The main objective of this article is to obtain dense (porosity under 0.5%) polyphasic ceramics belonging to the Al2O3–SiO2–ZrO2 system by SPS sintering of high energy powders milled drily; the stoichiometric (54.45:45.54 zircon–alumina, weight basis) mixture was explored in this work. Particularly the principal sintering variables: sintering temperature and dwell time were investigated. The textural, structural and microstructural changes were evaluated together with the hardness and toughness of the obtained ceramics and their microstructure. The effect of the mechanical pre-treatment was carried out by X-ray diffraction and particle distribution evaluation. Due to the rapid heating process an incomplete reaction was achieved in several cases, as a consequence multiphasic ceramics with different alumina, mullite, zircon and zirconia contents were obtained. The mechanical pretreatment used resulted in a homogeneous dry mixture with a partial (≈20%) zircon dissociation, apparently enhanced by the alumina presence. This together with the posterior SPS processing permitted to obtain fully dense ceramic composites at a very low temperature (1300 °C) without the requirement of any additive. The reactions from alumina zircon mixtures to mullite zirconia occur 200 °C below conventional processing routes and at least 50 °C below the reported SPS based materials processed from un-milled mixtures. The microstructure and mechanical properties obtained were comparable to the ones obtained by other processing routes. Finally some interesting group correlations were found for the developed materials while the hardness is directly correlated with the density and the fracture toughness is correlated with the zirconia (m+t) content.
publishDate 2014
dc.date.none.fl_str_mv 2014-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/32389
Aglietti, Esteban Fausto; Sakka, Yoshio; Suarez, Gustavo; Rendtorff Birrer, Nicolás Maximiliano; Dense mullite zirconia composites obtained from the reaction sintering of milled stoichiometric alumina zircon mixtures by SPS; Elsevier; Ceramics International; 40; 3; 1-2014; 4461-4470
0272-8842
CONICET Digital
CONICET
url http://hdl.handle.net/11336/32389
identifier_str_mv Aglietti, Esteban Fausto; Sakka, Yoshio; Suarez, Gustavo; Rendtorff Birrer, Nicolás Maximiliano; Dense mullite zirconia composites obtained from the reaction sintering of milled stoichiometric alumina zircon mixtures by SPS; Elsevier; Ceramics International; 40; 3; 1-2014; 4461-4470
0272-8842
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ceramint.2013.08.119
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S027288421301078X
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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