MIL-100(Fe) MOF as an emerging sulfur-host cathode for ultra long-cycle Metal-Sulfur batteries

Autores
Bonilla, Álvaro; Ortega Moreno, Gabriela Andreines; Bernini, Maria Celeste; Gómez Cámer Juan Luis; Barbosa, Lucía Isabel; Caballero, Alvaro
Año de publicación
2024
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Metal–Sulfur (Li/Na–S) battery technology is considered one of the most promising energy storage systems because of its high specific capacity of 1675 mA h/g, attributed to sulfur. However, the rapid capacity degradation, mainly caused by metallic polysulfide dissolution, remains a significant challenge prior to practical applications. This work demonstrates for the first time that a Fe-based metal organic framework (MIL-100(Fe)) can remarkably stabilize the electrochemical behavior of sulfur-cathodes in Metal-S cells during prolonged cycling. The chemical and morphological properties of MIL-100(Fe) and, especially conjugated with their textural characteristics, can help immobilize lithium/sodium polysulfides within the highly microporous cathode structure. Capacity loss per cycle is 0.044 mA h after 3000 cycles at 2C in Li–S cells. This behavior is confirmed when the MOF-based cathode is studied in RT Na–S batteries, managing to stabilize the capacity with a loss of less than 0.08 % during 2000 cycles at 0.1 C-rate. The excellent performance can be attributed to the synergistic effects of the highly microporous structure of MOF-100(Fe), which provide an ideal matrix to confine polysulfides, and the presence of Fe(III) active centers that provide chemical affinities to sulfur and polysulfides. These factors contribute to the excellent cycling performance of the S@MIL-100(Fe) composite in Metal-Sulfur batteries.
Fil: Bonilla, Álvaro. Universidad de Cordoba. Instituto Universitario de Investigación En Química Fina y Nanoquímica.; España
Fil: Ortega Moreno, Gabriela Andreines. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Bernini, Maria Celeste. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Gómez Cámer Juan Luis. Universidad de Cordoba. Instituto Universitario de Investigación En Química Fina y Nanoquímica.; España
Fil: Barbosa, Lucía Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Caballero, Alvaro. Universidad de Cordoba. Instituto Universitario de Investigación En Química Fina y Nanoquímica.; España
Materia
METAL-ORGANIC FRAMEWORK
LITHIUM-SULFUR CELLS
SODIUM-SULFUR BATTERIES
ULTRA-STABLE CATHODE
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/257478
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/257478
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling MIL-100(Fe) MOF as an emerging sulfur-host cathode for ultra long-cycle Metal-Sulfur batteriesBonilla, ÁlvaroOrtega Moreno, Gabriela AndreinesBernini, Maria CelesteGómez Cámer Juan LuisBarbosa, Lucía IsabelCaballero, AlvaroMETAL-ORGANIC FRAMEWORKLITHIUM-SULFUR CELLSSODIUM-SULFUR BATTERIESULTRA-STABLE CATHODEhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Metal–Sulfur (Li/Na–S) battery technology is considered one of the most promising energy storage systems because of its high specific capacity of 1675 mA h/g, attributed to sulfur. However, the rapid capacity degradation, mainly caused by metallic polysulfide dissolution, remains a significant challenge prior to practical applications. This work demonstrates for the first time that a Fe-based metal organic framework (MIL-100(Fe)) can remarkably stabilize the electrochemical behavior of sulfur-cathodes in Metal-S cells during prolonged cycling. The chemical and morphological properties of MIL-100(Fe) and, especially conjugated with their textural characteristics, can help immobilize lithium/sodium polysulfides within the highly microporous cathode structure. Capacity loss per cycle is 0.044 mA h after 3000 cycles at 2C in Li–S cells. This behavior is confirmed when the MOF-based cathode is studied in RT Na–S batteries, managing to stabilize the capacity with a loss of less than 0.08 % during 2000 cycles at 0.1 C-rate. The excellent performance can be attributed to the synergistic effects of the highly microporous structure of MOF-100(Fe), which provide an ideal matrix to confine polysulfides, and the presence of Fe(III) active centers that provide chemical affinities to sulfur and polysulfides. These factors contribute to the excellent cycling performance of the S@MIL-100(Fe) composite in Metal-Sulfur batteries.Fil: Bonilla, Álvaro. Universidad de Cordoba. Instituto Universitario de Investigación En Química Fina y Nanoquímica.; EspañaFil: Ortega Moreno, Gabriela Andreines. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; ArgentinaFil: Bernini, Maria Celeste. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; ArgentinaFil: Gómez Cámer Juan Luis. Universidad de Cordoba. Instituto Universitario de Investigación En Química Fina y Nanoquímica.; EspañaFil: Barbosa, Lucía Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; ArgentinaFil: Caballero, Alvaro. Universidad de Cordoba. Instituto Universitario de Investigación En Química Fina y Nanoquímica.; EspañaElsevier Science2024-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/257478Bonilla, Álvaro; Ortega Moreno, Gabriela Andreines; Bernini, Maria Celeste; Gómez Cámer Juan Luis; Barbosa, Lucía Isabel; et al.; MIL-100(Fe) MOF as an emerging sulfur-host cathode for ultra long-cycle Metal-Sulfur batteries; Elsevier Science; Journal of Power Sources; 608; 7-2024; 234613-2346260378-7753CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S0378775324005652info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jpowsour.2024.234613info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:18:59Zoai:ri.conicet.gov.ar:11336/257478instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:18:59.543CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv MIL-100(Fe) MOF as an emerging sulfur-host cathode for ultra long-cycle Metal-Sulfur batteries
title MIL-100(Fe) MOF as an emerging sulfur-host cathode for ultra long-cycle Metal-Sulfur batteries
spellingShingle MIL-100(Fe) MOF as an emerging sulfur-host cathode for ultra long-cycle Metal-Sulfur batteries
Bonilla, Álvaro
METAL-ORGANIC FRAMEWORK
LITHIUM-SULFUR CELLS
SODIUM-SULFUR BATTERIES
ULTRA-STABLE CATHODE
title_short MIL-100(Fe) MOF as an emerging sulfur-host cathode for ultra long-cycle Metal-Sulfur batteries
title_full MIL-100(Fe) MOF as an emerging sulfur-host cathode for ultra long-cycle Metal-Sulfur batteries
title_fullStr MIL-100(Fe) MOF as an emerging sulfur-host cathode for ultra long-cycle Metal-Sulfur batteries
title_full_unstemmed MIL-100(Fe) MOF as an emerging sulfur-host cathode for ultra long-cycle Metal-Sulfur batteries
title_sort MIL-100(Fe) MOF as an emerging sulfur-host cathode for ultra long-cycle Metal-Sulfur batteries
dc.creator.none.fl_str_mv Bonilla, Álvaro
Ortega Moreno, Gabriela Andreines
Bernini, Maria Celeste
Gómez Cámer Juan Luis
Barbosa, Lucía Isabel
Caballero, Alvaro
author Bonilla, Álvaro
author_facet Bonilla, Álvaro
Ortega Moreno, Gabriela Andreines
Bernini, Maria Celeste
Gómez Cámer Juan Luis
Barbosa, Lucía Isabel
Caballero, Alvaro
author_role author
author2 Ortega Moreno, Gabriela Andreines
Bernini, Maria Celeste
Gómez Cámer Juan Luis
Barbosa, Lucía Isabel
Caballero, Alvaro
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv METAL-ORGANIC FRAMEWORK
LITHIUM-SULFUR CELLS
SODIUM-SULFUR BATTERIES
ULTRA-STABLE CATHODE
topic METAL-ORGANIC FRAMEWORK
LITHIUM-SULFUR CELLS
SODIUM-SULFUR BATTERIES
ULTRA-STABLE CATHODE
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Metal–Sulfur (Li/Na–S) battery technology is considered one of the most promising energy storage systems because of its high specific capacity of 1675 mA h/g, attributed to sulfur. However, the rapid capacity degradation, mainly caused by metallic polysulfide dissolution, remains a significant challenge prior to practical applications. This work demonstrates for the first time that a Fe-based metal organic framework (MIL-100(Fe)) can remarkably stabilize the electrochemical behavior of sulfur-cathodes in Metal-S cells during prolonged cycling. The chemical and morphological properties of MIL-100(Fe) and, especially conjugated with their textural characteristics, can help immobilize lithium/sodium polysulfides within the highly microporous cathode structure. Capacity loss per cycle is 0.044 mA h after 3000 cycles at 2C in Li–S cells. This behavior is confirmed when the MOF-based cathode is studied in RT Na–S batteries, managing to stabilize the capacity with a loss of less than 0.08 % during 2000 cycles at 0.1 C-rate. The excellent performance can be attributed to the synergistic effects of the highly microporous structure of MOF-100(Fe), which provide an ideal matrix to confine polysulfides, and the presence of Fe(III) active centers that provide chemical affinities to sulfur and polysulfides. These factors contribute to the excellent cycling performance of the S@MIL-100(Fe) composite in Metal-Sulfur batteries.
Fil: Bonilla, Álvaro. Universidad de Cordoba. Instituto Universitario de Investigación En Química Fina y Nanoquímica.; España
Fil: Ortega Moreno, Gabriela Andreines. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Bernini, Maria Celeste. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Gómez Cámer Juan Luis. Universidad de Cordoba. Instituto Universitario de Investigación En Química Fina y Nanoquímica.; España
Fil: Barbosa, Lucía Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Caballero, Alvaro. Universidad de Cordoba. Instituto Universitario de Investigación En Química Fina y Nanoquímica.; España
description Metal–Sulfur (Li/Na–S) battery technology is considered one of the most promising energy storage systems because of its high specific capacity of 1675 mA h/g, attributed to sulfur. However, the rapid capacity degradation, mainly caused by metallic polysulfide dissolution, remains a significant challenge prior to practical applications. This work demonstrates for the first time that a Fe-based metal organic framework (MIL-100(Fe)) can remarkably stabilize the electrochemical behavior of sulfur-cathodes in Metal-S cells during prolonged cycling. The chemical and morphological properties of MIL-100(Fe) and, especially conjugated with their textural characteristics, can help immobilize lithium/sodium polysulfides within the highly microporous cathode structure. Capacity loss per cycle is 0.044 mA h after 3000 cycles at 2C in Li–S cells. This behavior is confirmed when the MOF-based cathode is studied in RT Na–S batteries, managing to stabilize the capacity with a loss of less than 0.08 % during 2000 cycles at 0.1 C-rate. The excellent performance can be attributed to the synergistic effects of the highly microporous structure of MOF-100(Fe), which provide an ideal matrix to confine polysulfides, and the presence of Fe(III) active centers that provide chemical affinities to sulfur and polysulfides. These factors contribute to the excellent cycling performance of the S@MIL-100(Fe) composite in Metal-Sulfur batteries.
publishDate 2024
dc.date.none.fl_str_mv 2024-07
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/257478
Bonilla, Álvaro; Ortega Moreno, Gabriela Andreines; Bernini, Maria Celeste; Gómez Cámer Juan Luis; Barbosa, Lucía Isabel; et al.; MIL-100(Fe) MOF as an emerging sulfur-host cathode for ultra long-cycle Metal-Sulfur batteries; Elsevier Science; Journal of Power Sources; 608; 7-2024; 234613-234626
0378-7753
CONICET Digital
CONICET
url http://hdl.handle.net/11336/257478
identifier_str_mv Bonilla, Álvaro; Ortega Moreno, Gabriela Andreines; Bernini, Maria Celeste; Gómez Cámer Juan Luis; Barbosa, Lucía Isabel; et al.; MIL-100(Fe) MOF as an emerging sulfur-host cathode for ultra long-cycle Metal-Sulfur batteries; Elsevier Science; Journal of Power Sources; 608; 7-2024; 234613-234626
0378-7753
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S0378775324005652
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jpowsour.2024.234613
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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