Thinfilms of polymerized acetylene by RF discharge and its benzene absorption ability

Autores
Arias Durán, Andrés; Giuliani, Leandro Estanislao; D´ Accorso, N.B.; Grondona, Diana Elena; Goyanes, Silvia Nair
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Thin films of polymerized acetylene have been deposited by Plasma Enhanced Chemical Vapor Deposition with a capacitively coupled RF discharge of acetylene. From the results of elemental analysis, FTIR, 1H-NMR and electrical conductivity, a highly branched chemical structure for the polymeric film is proposed. The morphology of the film surface, as well as its thickness was determined by scanning electron microscopy. The optical constants of thefilm, refractive index and optical band gap energy were obtained by the UV?vis transmittance spectrum using different models from the literature. Thefilms presented a moderate degree of hydrophobicity and showed a high capacity to absorb and retain benzene after drying at room temperature during 24 h. This result shows the potential of the obtained polymer to be used infiller of filters employed for the treatment of industrial effluent.
Fil: Arias Durán, Andrés. Consejo Nacional de Invest.cientif.y Tecnicas. Oficina de Coordinacion Administrativa Ciudad Universitaria. Instituto de Fisica del Plasma; Argentina;
Fil: Giuliani, Leandro Estanislao. Consejo Nacional de Invest.cientif.y Tecnicas. Oficina de Coordinacion Administrativa Ciudad Universitaria. Instituto de Fisica del Plasma; Argentina;
Fil: D´ Accorso, N.B.. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina;
Fil: Grondona, Diana Elena. Consejo Nacional de Invest.cientif.y Tecnicas. Oficina de Coordinacion Administrativa Ciudad Universitaria. Instituto de Fisica del Plasma; Argentina;
Fil: Goyanes, Silvia Nair. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física de Buenos Aires; Argentina;
Materia
Rf Plasma
Polymerization Acetylene
Benzene Absorption
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/789
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/789
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Thinfilms of polymerized acetylene by RF discharge and its benzene absorption abilityArias Durán, AndrésGiuliani, Leandro EstanislaoD´ Accorso, N.B.Grondona, Diana ElenaGoyanes, Silvia NairRf PlasmaPolymerization AcetyleneBenzene Absorptionhttps://purl.org/becyt/ford/1https://purl.org/becyt/ford/1.3Thin films of polymerized acetylene have been deposited by Plasma Enhanced Chemical Vapor Deposition with a capacitively coupled RF discharge of acetylene. From the results of elemental analysis, FTIR, 1H-NMR and electrical conductivity, a highly branched chemical structure for the polymeric film is proposed. The morphology of the film surface, as well as its thickness was determined by scanning electron microscopy. The optical constants of thefilm, refractive index and optical band gap energy were obtained by the UV?vis transmittance spectrum using different models from the literature. Thefilms presented a moderate degree of hydrophobicity and showed a high capacity to absorb and retain benzene after drying at room temperature during 24 h. This result shows the potential of the obtained polymer to be used infiller of filters employed for the treatment of industrial effluent.Fil: Arias Durán, Andrés. Consejo Nacional de Invest.cientif.y Tecnicas. Oficina de Coordinacion Administrativa Ciudad Universitaria. Instituto de Fisica del Plasma; Argentina;Fil: Giuliani, Leandro Estanislao. Consejo Nacional de Invest.cientif.y Tecnicas. Oficina de Coordinacion Administrativa Ciudad Universitaria. Instituto de Fisica del Plasma; Argentina;Fil: D´ Accorso, N.B.. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina;Fil: Grondona, Diana Elena. Consejo Nacional de Invest.cientif.y Tecnicas. Oficina de Coordinacion Administrativa Ciudad Universitaria. Instituto de Fisica del Plasma; Argentina;Fil: Goyanes, Silvia Nair. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física de Buenos Aires; Argentina;Elsevier Science Sa2013-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/789Arias Durán, Andrés; Giuliani, Leandro Estanislao; D´ Accorso, N.B.; Grondona, Diana Elena; Goyanes, Silvia Nair; Thinfilms of polymerized acetylene by RF discharge and its benzene absorption ability; Elsevier Science Sa; Surface And Coatings Technology; 216; 15; 9-2013; 185-1900257-8972enginfo:eu-repo/semantics/altIdentifier/url/http://ac.els-cdn.com/S0257897212012169/1-s2.0-S0257897212012169-main.pdf?_tid=bcbe5036-146c-11e5-ba15-00000aacb360&acdnat=1434489476_5c52eb302c7947dde0782b86919ba3c4info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0257897212012169#?np=yinfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.surfcoat.2012.11.063info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:59:57Zoai:ri.conicet.gov.ar:11336/789instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:59:57.947CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Thinfilms of polymerized acetylene by RF discharge and its benzene absorption ability
title Thinfilms of polymerized acetylene by RF discharge and its benzene absorption ability
spellingShingle Thinfilms of polymerized acetylene by RF discharge and its benzene absorption ability
Arias Durán, Andrés
Rf Plasma
Polymerization Acetylene
Benzene Absorption
title_short Thinfilms of polymerized acetylene by RF discharge and its benzene absorption ability
title_full Thinfilms of polymerized acetylene by RF discharge and its benzene absorption ability
title_fullStr Thinfilms of polymerized acetylene by RF discharge and its benzene absorption ability
title_full_unstemmed Thinfilms of polymerized acetylene by RF discharge and its benzene absorption ability
title_sort Thinfilms of polymerized acetylene by RF discharge and its benzene absorption ability
dc.creator.none.fl_str_mv Arias Durán, Andrés
Giuliani, Leandro Estanislao
D´ Accorso, N.B.
Grondona, Diana Elena
Goyanes, Silvia Nair
author Arias Durán, Andrés
author_facet Arias Durán, Andrés
Giuliani, Leandro Estanislao
D´ Accorso, N.B.
Grondona, Diana Elena
Goyanes, Silvia Nair
author_role author
author2 Giuliani, Leandro Estanislao
D´ Accorso, N.B.
Grondona, Diana Elena
Goyanes, Silvia Nair
author2_role author
author
author
author
dc.subject.none.fl_str_mv Rf Plasma
Polymerization Acetylene
Benzene Absorption
topic Rf Plasma
Polymerization Acetylene
Benzene Absorption
purl_subject.fl_str_mv https://purl.org/becyt/ford/1
https://purl.org/becyt/ford/1.3
dc.description.none.fl_txt_mv Thin films of polymerized acetylene have been deposited by Plasma Enhanced Chemical Vapor Deposition with a capacitively coupled RF discharge of acetylene. From the results of elemental analysis, FTIR, 1H-NMR and electrical conductivity, a highly branched chemical structure for the polymeric film is proposed. The morphology of the film surface, as well as its thickness was determined by scanning electron microscopy. The optical constants of thefilm, refractive index and optical band gap energy were obtained by the UV?vis transmittance spectrum using different models from the literature. Thefilms presented a moderate degree of hydrophobicity and showed a high capacity to absorb and retain benzene after drying at room temperature during 24 h. This result shows the potential of the obtained polymer to be used infiller of filters employed for the treatment of industrial effluent.
Fil: Arias Durán, Andrés. Consejo Nacional de Invest.cientif.y Tecnicas. Oficina de Coordinacion Administrativa Ciudad Universitaria. Instituto de Fisica del Plasma; Argentina;
Fil: Giuliani, Leandro Estanislao. Consejo Nacional de Invest.cientif.y Tecnicas. Oficina de Coordinacion Administrativa Ciudad Universitaria. Instituto de Fisica del Plasma; Argentina;
Fil: D´ Accorso, N.B.. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Industrias; Argentina;
Fil: Grondona, Diana Elena. Consejo Nacional de Invest.cientif.y Tecnicas. Oficina de Coordinacion Administrativa Ciudad Universitaria. Instituto de Fisica del Plasma; Argentina;
Fil: Goyanes, Silvia Nair. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física de Buenos Aires; Argentina;
description Thin films of polymerized acetylene have been deposited by Plasma Enhanced Chemical Vapor Deposition with a capacitively coupled RF discharge of acetylene. From the results of elemental analysis, FTIR, 1H-NMR and electrical conductivity, a highly branched chemical structure for the polymeric film is proposed. The morphology of the film surface, as well as its thickness was determined by scanning electron microscopy. The optical constants of thefilm, refractive index and optical band gap energy were obtained by the UV?vis transmittance spectrum using different models from the literature. Thefilms presented a moderate degree of hydrophobicity and showed a high capacity to absorb and retain benzene after drying at room temperature during 24 h. This result shows the potential of the obtained polymer to be used infiller of filters employed for the treatment of industrial effluent.
publishDate 2013
dc.date.none.fl_str_mv 2013-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/789
Arias Durán, Andrés; Giuliani, Leandro Estanislao; D´ Accorso, N.B.; Grondona, Diana Elena; Goyanes, Silvia Nair; Thinfilms of polymerized acetylene by RF discharge and its benzene absorption ability; Elsevier Science Sa; Surface And Coatings Technology; 216; 15; 9-2013; 185-190
0257-8972
url http://hdl.handle.net/11336/789
identifier_str_mv Arias Durán, Andrés; Giuliani, Leandro Estanislao; D´ Accorso, N.B.; Grondona, Diana Elena; Goyanes, Silvia Nair; Thinfilms of polymerized acetylene by RF discharge and its benzene absorption ability; Elsevier Science Sa; Surface And Coatings Technology; 216; 15; 9-2013; 185-190
0257-8972
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://ac.els-cdn.com/S0257897212012169/1-s2.0-S0257897212012169-main.pdf?_tid=bcbe5036-146c-11e5-ba15-00000aacb360&acdnat=1434489476_5c52eb302c7947dde0782b86919ba3c4
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0257897212012169#?np=y
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.surfcoat.2012.11.063
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science Sa
publisher.none.fl_str_mv Elsevier Science Sa
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846782323023937536
score 12.982451

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