The carbon budget of a large catchment in the Argentine Pampa plain through hydrochemical modeling

Autores
Glok Galli, Melisa; Martinez, Daniel Emilio; Kruse, Eduardo Emilio
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Mar Chiquita is a coastal lagoon located in the Argentine Buenos Aires province in South America. The aim of this study is to estimate the annual contribution of inland waters to the carbon cycle in this lagoon?s catchment by estimating the corresponding local carbon budget. Fifteen pairs of water samples were chosen to carry out hydrogeochemical modeling using PHREEQC software. Groundwater samples were considered as recharge water (initial solutions), while streamwater samples were taken as groundwater discharge (final solutions for inverse modeling/reference solutions for direct modeling). Fifteen direct models were performed, where each groundwater sample was constrained to calcite equilibrium under two different carbon dioxide partial pressure (PCO2) conditions: atmospheric conditions (log PCO2 (atm) = -3.5) and a PCO2 value of log PCO2 (atm) = -3. Groundwater samples are close to calcite equilibrium conditions. The calcite precipitation process is kinetically slower than gas diffusion, causing oversaturation of this reactant phase in streamwater samples. This was accompanied by a pH increase of approximately two units due to a PCO2 decrease. From the fifteen inverse models it was estimated that, of the total carbon that enters per year in the hydrological cycle of the study area, about 11.9 % is delivered to the atmosphere as CO2 and around 6.7 % is buried in sediments. This would indicate that 81.4 % of the remaining carbon is retained in equilibrium within the system or discharged into the Mar Chiquita lagoon and/or directly to the ocean through regional flows.
Fil: Glok Galli, Melisa. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales. Instituto de Geología de Costas y del Cuaternario. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Instituto de Geología de Costas y del Cuaternario; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones Marinas y Costeras. Universidad Nacional de Mar del Plata. Facultad de Ciencia Exactas y Naturales. Instituto de Investigaciones Marinas y Costeras; Argentina
Fil: Martinez, Daniel Emilio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones Marinas y Costeras. Universidad Nacional de Mar del Plata. Facultad de Ciencia Exactas y Naturales. Instituto de Investigaciones Marinas y Costeras; Argentina. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales. Instituto de Geología de Costas y del Cuaternario. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Instituto de Geología de Costas y del Cuaternario; Argentina
Fil: Kruse, Eduardo Emilio. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Naturales y Museo; Argentina
Materia
Carbon Budget
Mar Chiquita Lagoon'S Catchment
Hydrogeochemical Modeling
Ph
Co2 Partial Pressure
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/34766
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/34766
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling The carbon budget of a large catchment in the Argentine Pampa plain through hydrochemical modelingGlok Galli, MelisaMartinez, Daniel EmilioKruse, Eduardo EmilioCarbon BudgetMar Chiquita Lagoon'S CatchmentHydrogeochemical ModelingPhCo2 Partial Pressurehttps://purl.org/becyt/ford/1.5https://purl.org/becyt/ford/1Mar Chiquita is a coastal lagoon located in the Argentine Buenos Aires province in South America. The aim of this study is to estimate the annual contribution of inland waters to the carbon cycle in this lagoon?s catchment by estimating the corresponding local carbon budget. Fifteen pairs of water samples were chosen to carry out hydrogeochemical modeling using PHREEQC software. Groundwater samples were considered as recharge water (initial solutions), while streamwater samples were taken as groundwater discharge (final solutions for inverse modeling/reference solutions for direct modeling). Fifteen direct models were performed, where each groundwater sample was constrained to calcite equilibrium under two different carbon dioxide partial pressure (PCO2) conditions: atmospheric conditions (log PCO2 (atm) = -3.5) and a PCO2 value of log PCO2 (atm) = -3. Groundwater samples are close to calcite equilibrium conditions. The calcite precipitation process is kinetically slower than gas diffusion, causing oversaturation of this reactant phase in streamwater samples. This was accompanied by a pH increase of approximately two units due to a PCO2 decrease. From the fifteen inverse models it was estimated that, of the total carbon that enters per year in the hydrological cycle of the study area, about 11.9 % is delivered to the atmosphere as CO2 and around 6.7 % is buried in sediments. This would indicate that 81.4 % of the remaining carbon is retained in equilibrium within the system or discharged into the Mar Chiquita lagoon and/or directly to the ocean through regional flows.Fil: Glok Galli, Melisa. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales. Instituto de Geología de Costas y del Cuaternario. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Instituto de Geología de Costas y del Cuaternario; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones Marinas y Costeras. Universidad Nacional de Mar del Plata. Facultad de Ciencia Exactas y Naturales. Instituto de Investigaciones Marinas y Costeras; ArgentinaFil: Martinez, Daniel Emilio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones Marinas y Costeras. Universidad Nacional de Mar del Plata. Facultad de Ciencia Exactas y Naturales. Instituto de Investigaciones Marinas y Costeras; Argentina. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales. Instituto de Geología de Costas y del Cuaternario. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Instituto de Geología de Costas y del Cuaternario; ArgentinaFil: Kruse, Eduardo Emilio. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Naturales y Museo; ArgentinaElsevier2014-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/34766Glok Galli, Melisa; Martinez, Daniel Emilio; Kruse, Eduardo Emilio; The carbon budget of a large catchment in the Argentine Pampa plain through hydrochemical modeling; Elsevier; Science of the Total Environment; 493; 6-2014; 649-6550048-9697CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.scitotenv.2014.06.032info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0048969714008870info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:32:05Zoai:ri.conicet.gov.ar:11336/34766instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:32:06.173CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv The carbon budget of a large catchment in the Argentine Pampa plain through hydrochemical modeling
title The carbon budget of a large catchment in the Argentine Pampa plain through hydrochemical modeling
spellingShingle The carbon budget of a large catchment in the Argentine Pampa plain through hydrochemical modeling
Glok Galli, Melisa
Carbon Budget
Mar Chiquita Lagoon'S Catchment
Hydrogeochemical Modeling
Ph
Co2 Partial Pressure
title_short The carbon budget of a large catchment in the Argentine Pampa plain through hydrochemical modeling
title_full The carbon budget of a large catchment in the Argentine Pampa plain through hydrochemical modeling
title_fullStr The carbon budget of a large catchment in the Argentine Pampa plain through hydrochemical modeling
title_full_unstemmed The carbon budget of a large catchment in the Argentine Pampa plain through hydrochemical modeling
title_sort The carbon budget of a large catchment in the Argentine Pampa plain through hydrochemical modeling
dc.creator.none.fl_str_mv Glok Galli, Melisa
Martinez, Daniel Emilio
Kruse, Eduardo Emilio
author Glok Galli, Melisa
author_facet Glok Galli, Melisa
Martinez, Daniel Emilio
Kruse, Eduardo Emilio
author_role author
author2 Martinez, Daniel Emilio
Kruse, Eduardo Emilio
author2_role author
author
dc.subject.none.fl_str_mv Carbon Budget
Mar Chiquita Lagoon'S Catchment
Hydrogeochemical Modeling
Ph
Co2 Partial Pressure
topic Carbon Budget
Mar Chiquita Lagoon'S Catchment
Hydrogeochemical Modeling
Ph
Co2 Partial Pressure
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.5
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Mar Chiquita is a coastal lagoon located in the Argentine Buenos Aires province in South America. The aim of this study is to estimate the annual contribution of inland waters to the carbon cycle in this lagoon?s catchment by estimating the corresponding local carbon budget. Fifteen pairs of water samples were chosen to carry out hydrogeochemical modeling using PHREEQC software. Groundwater samples were considered as recharge water (initial solutions), while streamwater samples were taken as groundwater discharge (final solutions for inverse modeling/reference solutions for direct modeling). Fifteen direct models were performed, where each groundwater sample was constrained to calcite equilibrium under two different carbon dioxide partial pressure (PCO2) conditions: atmospheric conditions (log PCO2 (atm) = -3.5) and a PCO2 value of log PCO2 (atm) = -3. Groundwater samples are close to calcite equilibrium conditions. The calcite precipitation process is kinetically slower than gas diffusion, causing oversaturation of this reactant phase in streamwater samples. This was accompanied by a pH increase of approximately two units due to a PCO2 decrease. From the fifteen inverse models it was estimated that, of the total carbon that enters per year in the hydrological cycle of the study area, about 11.9 % is delivered to the atmosphere as CO2 and around 6.7 % is buried in sediments. This would indicate that 81.4 % of the remaining carbon is retained in equilibrium within the system or discharged into the Mar Chiquita lagoon and/or directly to the ocean through regional flows.
Fil: Glok Galli, Melisa. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales. Instituto de Geología de Costas y del Cuaternario. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Instituto de Geología de Costas y del Cuaternario; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones Marinas y Costeras. Universidad Nacional de Mar del Plata. Facultad de Ciencia Exactas y Naturales. Instituto de Investigaciones Marinas y Costeras; Argentina
Fil: Martinez, Daniel Emilio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones Marinas y Costeras. Universidad Nacional de Mar del Plata. Facultad de Ciencia Exactas y Naturales. Instituto de Investigaciones Marinas y Costeras; Argentina. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales. Instituto de Geología de Costas y del Cuaternario. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Instituto de Geología de Costas y del Cuaternario; Argentina
Fil: Kruse, Eduardo Emilio. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Naturales y Museo; Argentina
description Mar Chiquita is a coastal lagoon located in the Argentine Buenos Aires province in South America. The aim of this study is to estimate the annual contribution of inland waters to the carbon cycle in this lagoon?s catchment by estimating the corresponding local carbon budget. Fifteen pairs of water samples were chosen to carry out hydrogeochemical modeling using PHREEQC software. Groundwater samples were considered as recharge water (initial solutions), while streamwater samples were taken as groundwater discharge (final solutions for inverse modeling/reference solutions for direct modeling). Fifteen direct models were performed, where each groundwater sample was constrained to calcite equilibrium under two different carbon dioxide partial pressure (PCO2) conditions: atmospheric conditions (log PCO2 (atm) = -3.5) and a PCO2 value of log PCO2 (atm) = -3. Groundwater samples are close to calcite equilibrium conditions. The calcite precipitation process is kinetically slower than gas diffusion, causing oversaturation of this reactant phase in streamwater samples. This was accompanied by a pH increase of approximately two units due to a PCO2 decrease. From the fifteen inverse models it was estimated that, of the total carbon that enters per year in the hydrological cycle of the study area, about 11.9 % is delivered to the atmosphere as CO2 and around 6.7 % is buried in sediments. This would indicate that 81.4 % of the remaining carbon is retained in equilibrium within the system or discharged into the Mar Chiquita lagoon and/or directly to the ocean through regional flows.
publishDate 2014
dc.date.none.fl_str_mv 2014-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/34766
Glok Galli, Melisa; Martinez, Daniel Emilio; Kruse, Eduardo Emilio; The carbon budget of a large catchment in the Argentine Pampa plain through hydrochemical modeling; Elsevier; Science of the Total Environment; 493; 6-2014; 649-655
0048-9697
CONICET Digital
CONICET
url http://hdl.handle.net/11336/34766
identifier_str_mv Glok Galli, Melisa; Martinez, Daniel Emilio; Kruse, Eduardo Emilio; The carbon budget of a large catchment in the Argentine Pampa plain through hydrochemical modeling; Elsevier; Science of the Total Environment; 493; 6-2014; 649-655
0048-9697
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.scitotenv.2014.06.032
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0048969714008870
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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