The carbon budget of a large catchment in the Argentine Pampa plain through hydrochemical modeling
- Autores
- Glok Galli, M.; Martínez, D. E.; Kruse, Eduardo
- Año de publicación
- 2014
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión enviada
- Descripción
- Mar Chiquita is a coastal lagoon located in the Argentine Buenos Aires province in South America. The aim of this study is to estimate the annual contribution of inland waters to the carbon cycle in this lagoon's catchment by estimating the corresponding local carbon budget. Fifteen pairs of water samples were chosen to carry out hydrogeochemical modeling using PHREEQC software. Groundwater samples were considered as recharge water (initial solutions), while streamwater samples were taken as groundwater discharge (final solutions for inverse modeling/reference solutions for direct modeling). Fifteen direct models were performed, where each groundwater sample was constrained to calcite equilibrium under two different carbon dioxide partial pressure (PCO2) conditions: atmospheric conditions (log PCO2 (atm) = -3.5) and a PCO2 value of log PCO2 (atm) = -3. Groundwater samples are close to calcite equilibrium conditions. The calcite precipitation process is kinetically slower than gas diffusion, causing oversaturation of this reactant phase in streamwater samples. This was accompanied by a pH increase of approximately two units due to a PCO2 decrease. From the fifteen inverse models it was estimated that, of the total carbon that enters per year in the hydrological cycle of the study area, about 11.9% is delivered to the atmosphere as CO2 and around 6.7% is buried in sediments. This would indicate that 81.4% of the remaining carbon is retained in equilibrium within the system or discharged into the Mar Chiquita lagoon and/or directly to the ocean through regional flows.
- Materia
-
Ciencias de la Tierra y relacionadas con el Medio Ambiente
Carbon budget
Mar Chiquita lagoon's catchment
Hydrogeochemical modeling
pH
CO2 partial pressure - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- http://creativecommons.org/licenses/by/4.0/
- Repositorio
- Institución
- Comisión de Investigaciones Científicas de la Provincia de Buenos Aires
- OAI Identificador
- oai:digital.cic.gba.gob.ar:11746/5787
Ver los metadatos del registro completo
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spelling |
The carbon budget of a large catchment in the Argentine Pampa plain through hydrochemical modelingGlok Galli, M.Martínez, D. E.Kruse, EduardoCiencias de la Tierra y relacionadas con el Medio AmbienteCarbon budgetMar Chiquita lagoon's catchmentHydrogeochemical modelingpHCO2 partial pressureMar Chiquita is a coastal lagoon located in the Argentine Buenos Aires province in South America. The aim of this study is to estimate the annual contribution of inland waters to the carbon cycle in this lagoon's catchment by estimating the corresponding local carbon budget. Fifteen pairs of water samples were chosen to carry out hydrogeochemical modeling using PHREEQC software. Groundwater samples were considered as recharge water (initial solutions), while streamwater samples were taken as groundwater discharge (final solutions for inverse modeling/reference solutions for direct modeling). Fifteen direct models were performed, where each groundwater sample was constrained to calcite equilibrium under two different carbon dioxide partial pressure (PCO2) conditions: atmospheric conditions (log PCO2 (atm) = -3.5) and a PCO2 value of log PCO2 (atm) = -3. Groundwater samples are close to calcite equilibrium conditions. The calcite precipitation process is kinetically slower than gas diffusion, causing oversaturation of this reactant phase in streamwater samples. This was accompanied by a pH increase of approximately two units due to a PCO2 decrease. From the fifteen inverse models it was estimated that, of the total carbon that enters per year in the hydrological cycle of the study area, about 11.9% is delivered to the atmosphere as CO2 and around 6.7% is buried in sediments. This would indicate that 81.4% of the remaining carbon is retained in equilibrium within the system or discharged into the Mar Chiquita lagoon and/or directly to the ocean through regional flows.2014info:eu-repo/semantics/articleinfo:eu-repo/semantics/submittedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfhttps://digital.cic.gba.gob.ar/handle/11746/5787enginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.scitotenv.2014.06.032info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/4.0/reponame:CIC Digital (CICBA)instname:Comisión de Investigaciones Científicas de la Provincia de Buenos Airesinstacron:CICBA2025-09-29T13:39:47Zoai:digital.cic.gba.gob.ar:11746/5787Institucionalhttp://digital.cic.gba.gob.arOrganismo científico-tecnológicoNo correspondehttp://digital.cic.gba.gob.ar/oai/snrdmarisa.degiusti@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:94412025-09-29 13:39:47.886CIC Digital (CICBA) - Comisión de Investigaciones Científicas de la Provincia de Buenos Airesfalse |
dc.title.none.fl_str_mv |
The carbon budget of a large catchment in the Argentine Pampa plain through hydrochemical modeling |
title |
The carbon budget of a large catchment in the Argentine Pampa plain through hydrochemical modeling |
spellingShingle |
The carbon budget of a large catchment in the Argentine Pampa plain through hydrochemical modeling Glok Galli, M. Ciencias de la Tierra y relacionadas con el Medio Ambiente Carbon budget Mar Chiquita lagoon's catchment Hydrogeochemical modeling pH CO2 partial pressure |
title_short |
The carbon budget of a large catchment in the Argentine Pampa plain through hydrochemical modeling |
title_full |
The carbon budget of a large catchment in the Argentine Pampa plain through hydrochemical modeling |
title_fullStr |
The carbon budget of a large catchment in the Argentine Pampa plain through hydrochemical modeling |
title_full_unstemmed |
The carbon budget of a large catchment in the Argentine Pampa plain through hydrochemical modeling |
title_sort |
The carbon budget of a large catchment in the Argentine Pampa plain through hydrochemical modeling |
dc.creator.none.fl_str_mv |
Glok Galli, M. Martínez, D. E. Kruse, Eduardo |
author |
Glok Galli, M. |
author_facet |
Glok Galli, M. Martínez, D. E. Kruse, Eduardo |
author_role |
author |
author2 |
Martínez, D. E. Kruse, Eduardo |
author2_role |
author author |
dc.subject.none.fl_str_mv |
Ciencias de la Tierra y relacionadas con el Medio Ambiente Carbon budget Mar Chiquita lagoon's catchment Hydrogeochemical modeling pH CO2 partial pressure |
topic |
Ciencias de la Tierra y relacionadas con el Medio Ambiente Carbon budget Mar Chiquita lagoon's catchment Hydrogeochemical modeling pH CO2 partial pressure |
dc.description.none.fl_txt_mv |
Mar Chiquita is a coastal lagoon located in the Argentine Buenos Aires province in South America. The aim of this study is to estimate the annual contribution of inland waters to the carbon cycle in this lagoon's catchment by estimating the corresponding local carbon budget. Fifteen pairs of water samples were chosen to carry out hydrogeochemical modeling using PHREEQC software. Groundwater samples were considered as recharge water (initial solutions), while streamwater samples were taken as groundwater discharge (final solutions for inverse modeling/reference solutions for direct modeling). Fifteen direct models were performed, where each groundwater sample was constrained to calcite equilibrium under two different carbon dioxide partial pressure (PCO2) conditions: atmospheric conditions (log PCO2 (atm) = -3.5) and a PCO2 value of log PCO2 (atm) = -3. Groundwater samples are close to calcite equilibrium conditions. The calcite precipitation process is kinetically slower than gas diffusion, causing oversaturation of this reactant phase in streamwater samples. This was accompanied by a pH increase of approximately two units due to a PCO2 decrease. From the fifteen inverse models it was estimated that, of the total carbon that enters per year in the hydrological cycle of the study area, about 11.9% is delivered to the atmosphere as CO2 and around 6.7% is buried in sediments. This would indicate that 81.4% of the remaining carbon is retained in equilibrium within the system or discharged into the Mar Chiquita lagoon and/or directly to the ocean through regional flows. |
description |
Mar Chiquita is a coastal lagoon located in the Argentine Buenos Aires province in South America. The aim of this study is to estimate the annual contribution of inland waters to the carbon cycle in this lagoon's catchment by estimating the corresponding local carbon budget. Fifteen pairs of water samples were chosen to carry out hydrogeochemical modeling using PHREEQC software. Groundwater samples were considered as recharge water (initial solutions), while streamwater samples were taken as groundwater discharge (final solutions for inverse modeling/reference solutions for direct modeling). Fifteen direct models were performed, where each groundwater sample was constrained to calcite equilibrium under two different carbon dioxide partial pressure (PCO2) conditions: atmospheric conditions (log PCO2 (atm) = -3.5) and a PCO2 value of log PCO2 (atm) = -3. Groundwater samples are close to calcite equilibrium conditions. The calcite precipitation process is kinetically slower than gas diffusion, causing oversaturation of this reactant phase in streamwater samples. This was accompanied by a pH increase of approximately two units due to a PCO2 decrease. From the fifteen inverse models it was estimated that, of the total carbon that enters per year in the hydrological cycle of the study area, about 11.9% is delivered to the atmosphere as CO2 and around 6.7% is buried in sediments. This would indicate that 81.4% of the remaining carbon is retained in equilibrium within the system or discharged into the Mar Chiquita lagoon and/or directly to the ocean through regional flows. |
publishDate |
2014 |
dc.date.none.fl_str_mv |
2014 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/submittedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
submittedVersion |
dc.identifier.none.fl_str_mv |
https://digital.cic.gba.gob.ar/handle/11746/5787 |
url |
https://digital.cic.gba.gob.ar/handle/11746/5787 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.scitotenv.2014.06.032 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/4.0/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
http://creativecommons.org/licenses/by/4.0/ |
dc.format.none.fl_str_mv |
application/pdf |
dc.source.none.fl_str_mv |
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CIC Digital (CICBA) |
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CIC Digital (CICBA) |
instname_str |
Comisión de Investigaciones Científicas de la Provincia de Buenos Aires |
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repository.name.fl_str_mv |
CIC Digital (CICBA) - Comisión de Investigaciones Científicas de la Provincia de Buenos Aires |
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marisa.degiusti@sedici.unlp.edu.ar |
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