Conversion of biogas to synthesis gas over NiO/CeO2–Sm2O3 catalysts

Autores
Zimicz, Maria Genoveva; Reznik, Brian A.; Larrondo, Susana Adelina
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The main objective of this work has been to study the catalytic activity in the conversion of biogas to Syngas of a Ni/Ce0.82Sm0.18O1.91 oxide system, which could be used as a component in the anode material of a SOFC directly fed with biogas. The solids were active without need of pretreatment with a stable behaviour during a time on stream of six hours for a carbon dioxide to methane molar ratio of 2.3. This feed composition maximize the production of synthesis gas, with stable catalytic behaviour without formation of carbonaceous compounds and involving CO2 capturing, contributing to the reduction of greenhouse gases. It can be concluded that NiO/CeO2-Sm2O3 catalysts exhibited promising catalytic performance for their use in the composition of anode material of solid oxide fuel cells fed with biogas.
Fil: Zimicz, Maria Genoveva. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Física del Sur. Universidad Nacional del Sur. Departamento de Física. Instituto de Física del Sur; Argentina
Fil: Reznik, Brian A.. Universidad de Buenos Aires. Facultad de Ingeniería. Departamento de Ingeniería Química; Argentina
Fil: Larrondo, Susana Adelina. Consejo Nacional de Investigaciones Científicas y Técnicas. Unidad de Investigación y Desarrollo Estratégico para la Defensa. Ministerio de Defensa. Unidad de Investigación y Desarrollo Estratégico para la Defensa; Argentina. Universidad Nacional de San Martín; Argentina
Materia
Biogas
Sofcs
Ceria-Based Materials
Syngas
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/47638
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Conversion of biogas to synthesis gas over NiO/CeO2–Sm2O3 catalystsZimicz, Maria GenovevaReznik, Brian A.Larrondo, Susana AdelinaBiogasSofcsCeria-Based MaterialsSyngashttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The main objective of this work has been to study the catalytic activity in the conversion of biogas to Syngas of a Ni/Ce0.82Sm0.18O1.91 oxide system, which could be used as a component in the anode material of a SOFC directly fed with biogas. The solids were active without need of pretreatment with a stable behaviour during a time on stream of six hours for a carbon dioxide to methane molar ratio of 2.3. This feed composition maximize the production of synthesis gas, with stable catalytic behaviour without formation of carbonaceous compounds and involving CO2 capturing, contributing to the reduction of greenhouse gases. It can be concluded that NiO/CeO2-Sm2O3 catalysts exhibited promising catalytic performance for their use in the composition of anode material of solid oxide fuel cells fed with biogas.Fil: Zimicz, Maria Genoveva. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Física del Sur. Universidad Nacional del Sur. Departamento de Física. Instituto de Física del Sur; ArgentinaFil: Reznik, Brian A.. Universidad de Buenos Aires. Facultad de Ingeniería. Departamento de Ingeniería Química; ArgentinaFil: Larrondo, Susana Adelina. Consejo Nacional de Investigaciones Científicas y Técnicas. Unidad de Investigación y Desarrollo Estratégico para la Defensa. Ministerio de Defensa. Unidad de Investigación y Desarrollo Estratégico para la Defensa; Argentina. Universidad Nacional de San Martín; ArgentinaElsevier2015-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/47638Zimicz, Maria Genoveva; Reznik, Brian A.; Larrondo, Susana Adelina; Conversion of biogas to synthesis gas over NiO/CeO2–Sm2O3 catalysts; Elsevier; Fuel; 149; 6-2015; 95-990016-2361CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.fuel.2014.09.024info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0016236114008849info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T14:24:37Zoai:ri.conicet.gov.ar:11336/47638instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 14:24:37.646CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Conversion of biogas to synthesis gas over NiO/CeO2–Sm2O3 catalysts
title Conversion of biogas to synthesis gas over NiO/CeO2–Sm2O3 catalysts
spellingShingle Conversion of biogas to synthesis gas over NiO/CeO2–Sm2O3 catalysts
Zimicz, Maria Genoveva
Biogas
Sofcs
Ceria-Based Materials
Syngas
title_short Conversion of biogas to synthesis gas over NiO/CeO2–Sm2O3 catalysts
title_full Conversion of biogas to synthesis gas over NiO/CeO2–Sm2O3 catalysts
title_fullStr Conversion of biogas to synthesis gas over NiO/CeO2–Sm2O3 catalysts
title_full_unstemmed Conversion of biogas to synthesis gas over NiO/CeO2–Sm2O3 catalysts
title_sort Conversion of biogas to synthesis gas over NiO/CeO2–Sm2O3 catalysts
dc.creator.none.fl_str_mv Zimicz, Maria Genoveva
Reznik, Brian A.
Larrondo, Susana Adelina
author Zimicz, Maria Genoveva
author_facet Zimicz, Maria Genoveva
Reznik, Brian A.
Larrondo, Susana Adelina
author_role author
author2 Reznik, Brian A.
Larrondo, Susana Adelina
author2_role author
author
dc.subject.none.fl_str_mv Biogas
Sofcs
Ceria-Based Materials
Syngas
topic Biogas
Sofcs
Ceria-Based Materials
Syngas
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The main objective of this work has been to study the catalytic activity in the conversion of biogas to Syngas of a Ni/Ce0.82Sm0.18O1.91 oxide system, which could be used as a component in the anode material of a SOFC directly fed with biogas. The solids were active without need of pretreatment with a stable behaviour during a time on stream of six hours for a carbon dioxide to methane molar ratio of 2.3. This feed composition maximize the production of synthesis gas, with stable catalytic behaviour without formation of carbonaceous compounds and involving CO2 capturing, contributing to the reduction of greenhouse gases. It can be concluded that NiO/CeO2-Sm2O3 catalysts exhibited promising catalytic performance for their use in the composition of anode material of solid oxide fuel cells fed with biogas.
Fil: Zimicz, Maria Genoveva. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Física del Sur. Universidad Nacional del Sur. Departamento de Física. Instituto de Física del Sur; Argentina
Fil: Reznik, Brian A.. Universidad de Buenos Aires. Facultad de Ingeniería. Departamento de Ingeniería Química; Argentina
Fil: Larrondo, Susana Adelina. Consejo Nacional de Investigaciones Científicas y Técnicas. Unidad de Investigación y Desarrollo Estratégico para la Defensa. Ministerio de Defensa. Unidad de Investigación y Desarrollo Estratégico para la Defensa; Argentina. Universidad Nacional de San Martín; Argentina
description The main objective of this work has been to study the catalytic activity in the conversion of biogas to Syngas of a Ni/Ce0.82Sm0.18O1.91 oxide system, which could be used as a component in the anode material of a SOFC directly fed with biogas. The solids were active without need of pretreatment with a stable behaviour during a time on stream of six hours for a carbon dioxide to methane molar ratio of 2.3. This feed composition maximize the production of synthesis gas, with stable catalytic behaviour without formation of carbonaceous compounds and involving CO2 capturing, contributing to the reduction of greenhouse gases. It can be concluded that NiO/CeO2-Sm2O3 catalysts exhibited promising catalytic performance for their use in the composition of anode material of solid oxide fuel cells fed with biogas.
publishDate 2015
dc.date.none.fl_str_mv 2015-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/47638
Zimicz, Maria Genoveva; Reznik, Brian A.; Larrondo, Susana Adelina; Conversion of biogas to synthesis gas over NiO/CeO2–Sm2O3 catalysts; Elsevier; Fuel; 149; 6-2015; 95-99
0016-2361
CONICET Digital
CONICET
url http://hdl.handle.net/11336/47638
identifier_str_mv Zimicz, Maria Genoveva; Reznik, Brian A.; Larrondo, Susana Adelina; Conversion of biogas to synthesis gas over NiO/CeO2–Sm2O3 catalysts; Elsevier; Fuel; 149; 6-2015; 95-99
0016-2361
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.fuel.2014.09.024
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0016236114008849
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.22299

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