Biomass toward fine chemical products: Oxidation of -pinene over sieves nanostructured modified with vanadium
- Autores
- Cánepa, Analía Laura; Chanquia, Corina Mercedes; Vaschetti, Virginia María; Eimer, Griselda Alejandra; Casuscelli, Sandra Graciela
- Año de publicación
- 2015
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Vanadium-containing molecular sieves (V-M(x)) were synthetized and applied as heterogeneous catalysts for the liquid phase oxidation of -pinene with hydrogen peroxide at 70 ◦C. It has been found that the vanadium content in V-M(x) materials affected the conversion of -pinene and product distribution. The turnover numbers increased strongly with the decreasing of V content probably caused by a high V dispersion. The major products were verbenone,trans-sobrerol and campholenic aldehyde. The acid–base properties of V-M(x) affected the distribution of products formed via the isomerization of -pinene oxide over Lewis acid sites to campholenic aldehyde while Brønsted acid sites brought about the formation of 1,2 pinanediol and trans-sobrerol by hydrolysis and by the opening of oxirane ring. The increase in V content in V-M(x) led to the increase in campholenic aldehyde, 1,2 pinanediol, trans- sobrerol and over oxidation products. Moreover, the effect of several solvents on the reaction oxidation was studied. The results showed that the highest -pinene conversions are obtained in the following order: acetonitrile > ethanol > isoamyl alcohol > methyl ethyl ketone. Thus, using aprotic solvents, the catalytic activity was increased and the formation of alkyl glycol ethers as by-product was not observed.
Fil: Cánepa, Analía Laura. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnologico Cordoba. Centro de Investigacion y Tecnologia Quimica; Argentina. Universidad Tecnologica Nacional. Facultad Regional Cordoba; Argentina
Fil: Chanquia, Corina Mercedes. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina
Fil: Vaschetti, Virginia María. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnologico Cordoba. Centro de Investigacion y Tecnologia Quimica; Argentina. Universidad Tecnologica Nacional. Facultad Regional Cordoba; Argentina
Fil: Eimer, Griselda Alejandra. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnologico Cordoba. Centro de Investigacion y Tecnologia Quimica; Argentina. Universidad Tecnologica Nacional. Facultad Regional Cordoba; Argentina
Fil: Casuscelli, Sandra Graciela. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnologico Cordoba. Centro de Investigacion y Tecnologia Quimica; Argentina. Universidad Tecnologica Nacional. Facultad Regional Cordoba; Argentina - Materia
-
Oxidation
V-Mcm-41
Biomass - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/10990
Ver los metadatos del registro completo
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CONICET Digital (CONICET) |
spelling |
Biomass toward fine chemical products: Oxidation of -pinene over sieves nanostructured modified with vanadiumCánepa, Analía LauraChanquia, Corina MercedesVaschetti, Virginia MaríaEimer, Griselda AlejandraCasuscelli, Sandra GracielaOxidationV-Mcm-41Biomasshttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Vanadium-containing molecular sieves (V-M(x)) were synthetized and applied as heterogeneous catalysts for the liquid phase oxidation of -pinene with hydrogen peroxide at 70 ◦C. It has been found that the vanadium content in V-M(x) materials affected the conversion of -pinene and product distribution. The turnover numbers increased strongly with the decreasing of V content probably caused by a high V dispersion. The major products were verbenone,trans-sobrerol and campholenic aldehyde. The acid–base properties of V-M(x) affected the distribution of products formed via the isomerization of -pinene oxide over Lewis acid sites to campholenic aldehyde while Brønsted acid sites brought about the formation of 1,2 pinanediol and trans-sobrerol by hydrolysis and by the opening of oxirane ring. The increase in V content in V-M(x) led to the increase in campholenic aldehyde, 1,2 pinanediol, trans- sobrerol and over oxidation products. Moreover, the effect of several solvents on the reaction oxidation was studied. The results showed that the highest -pinene conversions are obtained in the following order: acetonitrile > ethanol > isoamyl alcohol > methyl ethyl ketone. Thus, using aprotic solvents, the catalytic activity was increased and the formation of alkyl glycol ethers as by-product was not observed.Fil: Cánepa, Analía Laura. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnologico Cordoba. Centro de Investigacion y Tecnologia Quimica; Argentina. Universidad Tecnologica Nacional. Facultad Regional Cordoba; ArgentinaFil: Chanquia, Corina Mercedes. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; ArgentinaFil: Vaschetti, Virginia María. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnologico Cordoba. Centro de Investigacion y Tecnologia Quimica; Argentina. Universidad Tecnologica Nacional. Facultad Regional Cordoba; ArgentinaFil: Eimer, Griselda Alejandra. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnologico Cordoba. Centro de Investigacion y Tecnologia Quimica; Argentina. Universidad Tecnologica Nacional. Facultad Regional Cordoba; ArgentinaFil: Casuscelli, Sandra Graciela. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnologico Cordoba. Centro de Investigacion y Tecnologia Quimica; Argentina. Universidad Tecnologica Nacional. Facultad Regional Cordoba; ArgentinaElsevier Science2015-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/10990Cánepa, Analía Laura; Chanquia, Corina Mercedes; Vaschetti, Virginia María; Eimer, Griselda Alejandra; Casuscelli, Sandra Graciela; Biomass toward fine chemical products: Oxidation of -pinene over sieves nanostructured modified with vanadium; Elsevier Science; Journal Of Molecular Catalysis A: Chemical; 404-405; 8-2015; 65-731381-1169enginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.molcata.2015.04.009info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S138111691500148Xinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:01:58Zoai:ri.conicet.gov.ar:11336/10990instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:01:58.446CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Biomass toward fine chemical products: Oxidation of -pinene over sieves nanostructured modified with vanadium |
title |
Biomass toward fine chemical products: Oxidation of -pinene over sieves nanostructured modified with vanadium |
spellingShingle |
Biomass toward fine chemical products: Oxidation of -pinene over sieves nanostructured modified with vanadium Cánepa, Analía Laura Oxidation V-Mcm-41 Biomass |
title_short |
Biomass toward fine chemical products: Oxidation of -pinene over sieves nanostructured modified with vanadium |
title_full |
Biomass toward fine chemical products: Oxidation of -pinene over sieves nanostructured modified with vanadium |
title_fullStr |
Biomass toward fine chemical products: Oxidation of -pinene over sieves nanostructured modified with vanadium |
title_full_unstemmed |
Biomass toward fine chemical products: Oxidation of -pinene over sieves nanostructured modified with vanadium |
title_sort |
Biomass toward fine chemical products: Oxidation of -pinene over sieves nanostructured modified with vanadium |
dc.creator.none.fl_str_mv |
Cánepa, Analía Laura Chanquia, Corina Mercedes Vaschetti, Virginia María Eimer, Griselda Alejandra Casuscelli, Sandra Graciela |
author |
Cánepa, Analía Laura |
author_facet |
Cánepa, Analía Laura Chanquia, Corina Mercedes Vaschetti, Virginia María Eimer, Griselda Alejandra Casuscelli, Sandra Graciela |
author_role |
author |
author2 |
Chanquia, Corina Mercedes Vaschetti, Virginia María Eimer, Griselda Alejandra Casuscelli, Sandra Graciela |
author2_role |
author author author author |
dc.subject.none.fl_str_mv |
Oxidation V-Mcm-41 Biomass |
topic |
Oxidation V-Mcm-41 Biomass |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
Vanadium-containing molecular sieves (V-M(x)) were synthetized and applied as heterogeneous catalysts for the liquid phase oxidation of -pinene with hydrogen peroxide at 70 ◦C. It has been found that the vanadium content in V-M(x) materials affected the conversion of -pinene and product distribution. The turnover numbers increased strongly with the decreasing of V content probably caused by a high V dispersion. The major products were verbenone,trans-sobrerol and campholenic aldehyde. The acid–base properties of V-M(x) affected the distribution of products formed via the isomerization of -pinene oxide over Lewis acid sites to campholenic aldehyde while Brønsted acid sites brought about the formation of 1,2 pinanediol and trans-sobrerol by hydrolysis and by the opening of oxirane ring. The increase in V content in V-M(x) led to the increase in campholenic aldehyde, 1,2 pinanediol, trans- sobrerol and over oxidation products. Moreover, the effect of several solvents on the reaction oxidation was studied. The results showed that the highest -pinene conversions are obtained in the following order: acetonitrile > ethanol > isoamyl alcohol > methyl ethyl ketone. Thus, using aprotic solvents, the catalytic activity was increased and the formation of alkyl glycol ethers as by-product was not observed. Fil: Cánepa, Analía Laura. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnologico Cordoba. Centro de Investigacion y Tecnologia Quimica; Argentina. Universidad Tecnologica Nacional. Facultad Regional Cordoba; Argentina Fil: Chanquia, Corina Mercedes. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina Fil: Vaschetti, Virginia María. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnologico Cordoba. Centro de Investigacion y Tecnologia Quimica; Argentina. Universidad Tecnologica Nacional. Facultad Regional Cordoba; Argentina Fil: Eimer, Griselda Alejandra. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnologico Cordoba. Centro de Investigacion y Tecnologia Quimica; Argentina. Universidad Tecnologica Nacional. Facultad Regional Cordoba; Argentina Fil: Casuscelli, Sandra Graciela. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnologico Cordoba. Centro de Investigacion y Tecnologia Quimica; Argentina. Universidad Tecnologica Nacional. Facultad Regional Cordoba; Argentina |
description |
Vanadium-containing molecular sieves (V-M(x)) were synthetized and applied as heterogeneous catalysts for the liquid phase oxidation of -pinene with hydrogen peroxide at 70 ◦C. It has been found that the vanadium content in V-M(x) materials affected the conversion of -pinene and product distribution. The turnover numbers increased strongly with the decreasing of V content probably caused by a high V dispersion. The major products were verbenone,trans-sobrerol and campholenic aldehyde. The acid–base properties of V-M(x) affected the distribution of products formed via the isomerization of -pinene oxide over Lewis acid sites to campholenic aldehyde while Brønsted acid sites brought about the formation of 1,2 pinanediol and trans-sobrerol by hydrolysis and by the opening of oxirane ring. The increase in V content in V-M(x) led to the increase in campholenic aldehyde, 1,2 pinanediol, trans- sobrerol and over oxidation products. Moreover, the effect of several solvents on the reaction oxidation was studied. The results showed that the highest -pinene conversions are obtained in the following order: acetonitrile > ethanol > isoamyl alcohol > methyl ethyl ketone. Thus, using aprotic solvents, the catalytic activity was increased and the formation of alkyl glycol ethers as by-product was not observed. |
publishDate |
2015 |
dc.date.none.fl_str_mv |
2015-08 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/10990 Cánepa, Analía Laura; Chanquia, Corina Mercedes; Vaschetti, Virginia María; Eimer, Griselda Alejandra; Casuscelli, Sandra Graciela; Biomass toward fine chemical products: Oxidation of -pinene over sieves nanostructured modified with vanadium; Elsevier Science; Journal Of Molecular Catalysis A: Chemical; 404-405; 8-2015; 65-73 1381-1169 |
url |
http://hdl.handle.net/11336/10990 |
identifier_str_mv |
Cánepa, Analía Laura; Chanquia, Corina Mercedes; Vaschetti, Virginia María; Eimer, Griselda Alejandra; Casuscelli, Sandra Graciela; Biomass toward fine chemical products: Oxidation of -pinene over sieves nanostructured modified with vanadium; Elsevier Science; Journal Of Molecular Catalysis A: Chemical; 404-405; 8-2015; 65-73 1381-1169 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.molcata.2015.04.009 info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S138111691500148X |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science |
publisher.none.fl_str_mv |
Elsevier Science |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1842269727799377920 |
score |
13.13397 |