Microstructural study of air-drying kinetics of Ca(II)-alginate beads to preserve cowpea extracts
- Autores
- Traffano Schiffo, Maria Victoria; Zazzali, Ignacio; Aguirre Calvo, Tatiana Rocio; Avanza, María Victoria; Perullini, Ana Mercedes; Santagapita, Patricio Roman
- Año de publicación
- 2021
- Idioma
- inglés
- Tipo de recurso
- documento de conferencia
- Estado
- versión publicada
- Descripción
- The great potential of Ca(II)-alginate beads in preserving biomolecules and their use as a carrier of bioactive compounds has been demonstrated. However, several food applications require long-term storage and thus, numerous preservation techniques such as drying have been applied. Still, research of stability of bioactive compounds in these treatments focus on the morphology of the beads and the microstructure of the network but do not consider the microstructural changes that occur during the drying process.Ca(II)-alginate beads were prepared to preserve phenolic compounds extracted from cowpea (Vigna unguiculata) by-products by using high-intensity ultrasound (VCX500, Sonics, US). Also, the influence of the addition of cowpea isolated proteins as an excipient of the beads has been analysed. The microstructural changes of the network during air-drying treatment have been studied by SAXS at the LNLS SAXS1 beamline in Campinas, Brazil at λ = 0.1488 nm. The wave vector (q) was selected in the range 0.142 nm−1 < q < 5.035 nm−1. All the Ca(II)-alginate beads analysed showed isotropic scattering and were modelled as a fractal system composed of rod-like structures.Significant differences were observed between the alginate beads containing the whole extract with respect to those containing cowpea isolate protein, revealing that cowpea protein is embedded within the rods, obtaining thicker but less dense rods disposed in a more disordered structure. These differences remained constant until 60 min of the air-drying treatment at 25 °C (even with moisture losses up to 30%). From this time, the microstructure of the dried beads at the final stage if drying (xw = 0.5 kgw/kgT) showed the loss of the typical scattering of rod-like structures and even displayed new signals at high q in the presence of cowpea proteins.
Fil: Traffano Schiffo, Maria Victoria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Química Básica y Aplicada del Nordeste Argentino. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas Naturales y Agrimensura. Instituto de Química Básica y Aplicada del Nordeste Argentino; Argentina
Fil: Zazzali, Ignacio. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones en Hidratos de Carbono. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Centro de Investigaciones en Hidratos de Carbono; Argentina
Fil: Aguirre Calvo, Tatiana Rocio. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones en Hidratos de Carbono. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Centro de Investigaciones en Hidratos de Carbono; Argentina
Fil: Avanza, María Victoria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Química Básica y Aplicada del Nordeste Argentino. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas Naturales y Agrimensura. Instituto de Química Básica y Aplicada del Nordeste Argentino; Argentina
Fil: Perullini, Ana Mercedes. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Santagapita, Patricio Roman. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones en Hidratos de Carbono. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Centro de Investigaciones en Hidratos de Carbono; Argentina
31st RAU Annual Users Meeting
Campinhas
Brasil
Brazilian Center for Research in Energy and Materials
Ministry for Science, Technology and Innovations - Materia
-
MICROSTRUCTURE
Ca(ii)-ALGINATE
COWPEA BYPRODUCTS - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/172209
Ver los metadatos del registro completo
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Microstructural study of air-drying kinetics of Ca(II)-alginate beads to preserve cowpea extractsTraffano Schiffo, Maria VictoriaZazzali, IgnacioAguirre Calvo, Tatiana RocioAvanza, María VictoriaPerullini, Ana MercedesSantagapita, Patricio RomanMICROSTRUCTURECa(ii)-ALGINATECOWPEA BYPRODUCTShttps://purl.org/becyt/ford/2.11https://purl.org/becyt/ford/2The great potential of Ca(II)-alginate beads in preserving biomolecules and their use as a carrier of bioactive compounds has been demonstrated. However, several food applications require long-term storage and thus, numerous preservation techniques such as drying have been applied. Still, research of stability of bioactive compounds in these treatments focus on the morphology of the beads and the microstructure of the network but do not consider the microstructural changes that occur during the drying process.Ca(II)-alginate beads were prepared to preserve phenolic compounds extracted from cowpea (Vigna unguiculata) by-products by using high-intensity ultrasound (VCX500, Sonics, US). Also, the influence of the addition of cowpea isolated proteins as an excipient of the beads has been analysed. The microstructural changes of the network during air-drying treatment have been studied by SAXS at the LNLS SAXS1 beamline in Campinas, Brazil at λ = 0.1488 nm. The wave vector (q) was selected in the range 0.142 nm−1 < q < 5.035 nm−1. All the Ca(II)-alginate beads analysed showed isotropic scattering and were modelled as a fractal system composed of rod-like structures.Significant differences were observed between the alginate beads containing the whole extract with respect to those containing cowpea isolate protein, revealing that cowpea protein is embedded within the rods, obtaining thicker but less dense rods disposed in a more disordered structure. These differences remained constant until 60 min of the air-drying treatment at 25 °C (even with moisture losses up to 30%). From this time, the microstructure of the dried beads at the final stage if drying (xw = 0.5 kgw/kgT) showed the loss of the typical scattering of rod-like structures and even displayed new signals at high q in the presence of cowpea proteins.Fil: Traffano Schiffo, Maria Victoria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Química Básica y Aplicada del Nordeste Argentino. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas Naturales y Agrimensura. Instituto de Química Básica y Aplicada del Nordeste Argentino; ArgentinaFil: Zazzali, Ignacio. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones en Hidratos de Carbono. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Centro de Investigaciones en Hidratos de Carbono; ArgentinaFil: Aguirre Calvo, Tatiana Rocio. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones en Hidratos de Carbono. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Centro de Investigaciones en Hidratos de Carbono; ArgentinaFil: Avanza, María Victoria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Química Básica y Aplicada del Nordeste Argentino. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas Naturales y Agrimensura. Instituto de Química Básica y Aplicada del Nordeste Argentino; ArgentinaFil: Perullini, Ana Mercedes. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaFil: Santagapita, Patricio Roman. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones en Hidratos de Carbono. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Centro de Investigaciones en Hidratos de Carbono; Argentina31st RAU Annual Users MeetingCampinhasBrasilBrazilian Center for Research in Energy and MaterialsMinistry for Science, Technology and InnovationsMinistry for Science, Technology and Innovations2021info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/conferenceObjectReuniónBookhttp://purl.org/coar/resource_type/c_5794info:ar-repo/semantics/documentoDeConferenciatext/plainapplication/pdfhttp://hdl.handle.net/11336/172209Microstructural study of air-drying kinetics of Ca(II)-alginate beads to preserve cowpea extracts; 31st RAU Annual Users Meeting; Campinhas; Brasil; 2021; 52-52CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://pages.cnpem.br/rau/wp-content/uploads/sites/8/2021/11/31RAU_book_of_abstracts_4.pdfInternacionalinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:41:53Zoai:ri.conicet.gov.ar:11336/172209instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:41:53.692CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Microstructural study of air-drying kinetics of Ca(II)-alginate beads to preserve cowpea extracts |
title |
Microstructural study of air-drying kinetics of Ca(II)-alginate beads to preserve cowpea extracts |
spellingShingle |
Microstructural study of air-drying kinetics of Ca(II)-alginate beads to preserve cowpea extracts Traffano Schiffo, Maria Victoria MICROSTRUCTURE Ca(ii)-ALGINATE COWPEA BYPRODUCTS |
title_short |
Microstructural study of air-drying kinetics of Ca(II)-alginate beads to preserve cowpea extracts |
title_full |
Microstructural study of air-drying kinetics of Ca(II)-alginate beads to preserve cowpea extracts |
title_fullStr |
Microstructural study of air-drying kinetics of Ca(II)-alginate beads to preserve cowpea extracts |
title_full_unstemmed |
Microstructural study of air-drying kinetics of Ca(II)-alginate beads to preserve cowpea extracts |
title_sort |
Microstructural study of air-drying kinetics of Ca(II)-alginate beads to preserve cowpea extracts |
dc.creator.none.fl_str_mv |
Traffano Schiffo, Maria Victoria Zazzali, Ignacio Aguirre Calvo, Tatiana Rocio Avanza, María Victoria Perullini, Ana Mercedes Santagapita, Patricio Roman |
author |
Traffano Schiffo, Maria Victoria |
author_facet |
Traffano Schiffo, Maria Victoria Zazzali, Ignacio Aguirre Calvo, Tatiana Rocio Avanza, María Victoria Perullini, Ana Mercedes Santagapita, Patricio Roman |
author_role |
author |
author2 |
Zazzali, Ignacio Aguirre Calvo, Tatiana Rocio Avanza, María Victoria Perullini, Ana Mercedes Santagapita, Patricio Roman |
author2_role |
author author author author author |
dc.subject.none.fl_str_mv |
MICROSTRUCTURE Ca(ii)-ALGINATE COWPEA BYPRODUCTS |
topic |
MICROSTRUCTURE Ca(ii)-ALGINATE COWPEA BYPRODUCTS |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.11 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
The great potential of Ca(II)-alginate beads in preserving biomolecules and their use as a carrier of bioactive compounds has been demonstrated. However, several food applications require long-term storage and thus, numerous preservation techniques such as drying have been applied. Still, research of stability of bioactive compounds in these treatments focus on the morphology of the beads and the microstructure of the network but do not consider the microstructural changes that occur during the drying process.Ca(II)-alginate beads were prepared to preserve phenolic compounds extracted from cowpea (Vigna unguiculata) by-products by using high-intensity ultrasound (VCX500, Sonics, US). Also, the influence of the addition of cowpea isolated proteins as an excipient of the beads has been analysed. The microstructural changes of the network during air-drying treatment have been studied by SAXS at the LNLS SAXS1 beamline in Campinas, Brazil at λ = 0.1488 nm. The wave vector (q) was selected in the range 0.142 nm−1 < q < 5.035 nm−1. All the Ca(II)-alginate beads analysed showed isotropic scattering and were modelled as a fractal system composed of rod-like structures.Significant differences were observed between the alginate beads containing the whole extract with respect to those containing cowpea isolate protein, revealing that cowpea protein is embedded within the rods, obtaining thicker but less dense rods disposed in a more disordered structure. These differences remained constant until 60 min of the air-drying treatment at 25 °C (even with moisture losses up to 30%). From this time, the microstructure of the dried beads at the final stage if drying (xw = 0.5 kgw/kgT) showed the loss of the typical scattering of rod-like structures and even displayed new signals at high q in the presence of cowpea proteins. Fil: Traffano Schiffo, Maria Victoria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Química Básica y Aplicada del Nordeste Argentino. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas Naturales y Agrimensura. Instituto de Química Básica y Aplicada del Nordeste Argentino; Argentina Fil: Zazzali, Ignacio. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones en Hidratos de Carbono. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Centro de Investigaciones en Hidratos de Carbono; Argentina Fil: Aguirre Calvo, Tatiana Rocio. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones en Hidratos de Carbono. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Centro de Investigaciones en Hidratos de Carbono; Argentina Fil: Avanza, María Victoria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Química Básica y Aplicada del Nordeste Argentino. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas Naturales y Agrimensura. Instituto de Química Básica y Aplicada del Nordeste Argentino; Argentina Fil: Perullini, Ana Mercedes. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina Fil: Santagapita, Patricio Roman. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones en Hidratos de Carbono. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Centro de Investigaciones en Hidratos de Carbono; Argentina 31st RAU Annual Users Meeting Campinhas Brasil Brazilian Center for Research in Energy and Materials Ministry for Science, Technology and Innovations |
description |
The great potential of Ca(II)-alginate beads in preserving biomolecules and their use as a carrier of bioactive compounds has been demonstrated. However, several food applications require long-term storage and thus, numerous preservation techniques such as drying have been applied. Still, research of stability of bioactive compounds in these treatments focus on the morphology of the beads and the microstructure of the network but do not consider the microstructural changes that occur during the drying process.Ca(II)-alginate beads were prepared to preserve phenolic compounds extracted from cowpea (Vigna unguiculata) by-products by using high-intensity ultrasound (VCX500, Sonics, US). Also, the influence of the addition of cowpea isolated proteins as an excipient of the beads has been analysed. The microstructural changes of the network during air-drying treatment have been studied by SAXS at the LNLS SAXS1 beamline in Campinas, Brazil at λ = 0.1488 nm. The wave vector (q) was selected in the range 0.142 nm−1 < q < 5.035 nm−1. All the Ca(II)-alginate beads analysed showed isotropic scattering and were modelled as a fractal system composed of rod-like structures.Significant differences were observed between the alginate beads containing the whole extract with respect to those containing cowpea isolate protein, revealing that cowpea protein is embedded within the rods, obtaining thicker but less dense rods disposed in a more disordered structure. These differences remained constant until 60 min of the air-drying treatment at 25 °C (even with moisture losses up to 30%). From this time, the microstructure of the dried beads at the final stage if drying (xw = 0.5 kgw/kgT) showed the loss of the typical scattering of rod-like structures and even displayed new signals at high q in the presence of cowpea proteins. |
publishDate |
2021 |
dc.date.none.fl_str_mv |
2021 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/publishedVersion info:eu-repo/semantics/conferenceObject Reunión Book http://purl.org/coar/resource_type/c_5794 info:ar-repo/semantics/documentoDeConferencia |
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publishedVersion |
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http://hdl.handle.net/11336/172209 Microstructural study of air-drying kinetics of Ca(II)-alginate beads to preserve cowpea extracts; 31st RAU Annual Users Meeting; Campinhas; Brasil; 2021; 52-52 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/172209 |
identifier_str_mv |
Microstructural study of air-drying kinetics of Ca(II)-alginate beads to preserve cowpea extracts; 31st RAU Annual Users Meeting; Campinhas; Brasil; 2021; 52-52 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
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info:eu-repo/semantics/altIdentifier/url/http://pages.cnpem.br/rau/wp-content/uploads/sites/8/2021/11/31RAU_book_of_abstracts_4.pdf |
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openAccess |
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https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
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Internacional |
dc.publisher.none.fl_str_mv |
Ministry for Science, Technology and Innovations |
publisher.none.fl_str_mv |
Ministry for Science, Technology and Innovations |
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reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
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Consejo Nacional de Investigaciones Científicas y Técnicas |
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CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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