High catalytic activity at low temperature in oxidative dehydrogenation of propane with Cr–Al pillared clay

Autores
de León, María Andrea; De los Santos, Carolina; Latronica, Luis; Cesio, Ana Maria; Volzone, Cristina; Castiglioni, Jorge; Sergio, Marta
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A montmorillonite was pillared separately with chromium and aluminum polyoxocations (Cr–C and Al–C respectively) and also with an equimolar mixture of both polioxocations (Al–Cr–C). The resulting solids were characterized by scanning electron microscopy, energy dispersive spectrometry, thermal analysis, Fourier transform infrared spectroscopy, X-ray diffraction and nitrogen adsorption at −196 °C. The inclusion of polycations in the interlamellar space led to modifications in the properties of the clay. An eleven fold increase in specific surface area with respect to the calcined starting clay was found for the Al–C, whereas a twofold increase was observed for the Cr–C; the value for the Al–Cr–C was only slightly higher than that for the latter. Diffractograms of the Cr–C showed the occurrence of a Cr2O3 phase. Catalytic activity in oxidative dehydrogenation of propane was assayed in the temperature range from 350 °C to 450 °C using Ar/C3H8/O2 (80/10/10) as reactant gas mixture. Propylene selectivity was found to be temperature-dependent, showing a maximum in the studied temperature range for the catalyst containing only aluminum, whereas remaining practically constant for the Cr-containing catalysts. Highly promising propylene yields at low temperature were obtained with the catalyst containing Al and Cr (Al–Cr–C): 9.3% at 350 °C and 10.3% at 450 °C.
Fil: de León, María Andrea. Universidad de la República; Uruguay
Fil: De los Santos, Carolina. Universidad de la República; Uruguay
Fil: Latronica, Luis. Universidad de la República; Uruguay
Fil: Cesio, Ana Maria. Provincia de Buenos Aires. Gobernación. Comision de Invest.científicas. Centro de Tecnología de Recursos Minerales y Ceramica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - la Plata. Centro de Tecnología de Recursos Minerales y Ceramica; Argentina
Fil: Volzone, Cristina. Provincia de Buenos Aires. Gobernación. Comision de Invest.científicas. Centro de Tecnología de Recursos Minerales y Ceramica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - la Plata. Centro de Tecnología de Recursos Minerales y Ceramica; Argentina
Fil: Castiglioni, Jorge. Universidad de la República; Uruguay
Fil: Sergio, Marta. Universidad de la República; Uruguay
Materia
Oxidative Dehydrogenation
Propane
Propene
Al–Cr-Pilc
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/24499
Acceder
id CONICETDig_ca5bfb28de8fd254fdd0b8316ee0a3bd
oai_identifier_str oai:ri.conicet.gov.ar:11336/24499
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling High catalytic activity at low temperature in oxidative dehydrogenation of propane with Cr–Al pillared clayde León, María AndreaDe los Santos, CarolinaLatronica, LuisCesio, Ana MariaVolzone, CristinaCastiglioni, JorgeSergio, MartaOxidative DehydrogenationPropanePropeneAl–Cr-Pilchttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2A montmorillonite was pillared separately with chromium and aluminum polyoxocations (Cr–C and Al–C respectively) and also with an equimolar mixture of both polioxocations (Al–Cr–C). The resulting solids were characterized by scanning electron microscopy, energy dispersive spectrometry, thermal analysis, Fourier transform infrared spectroscopy, X-ray diffraction and nitrogen adsorption at −196 °C. The inclusion of polycations in the interlamellar space led to modifications in the properties of the clay. An eleven fold increase in specific surface area with respect to the calcined starting clay was found for the Al–C, whereas a twofold increase was observed for the Cr–C; the value for the Al–Cr–C was only slightly higher than that for the latter. Diffractograms of the Cr–C showed the occurrence of a Cr2O3 phase. Catalytic activity in oxidative dehydrogenation of propane was assayed in the temperature range from 350 °C to 450 °C using Ar/C3H8/O2 (80/10/10) as reactant gas mixture. Propylene selectivity was found to be temperature-dependent, showing a maximum in the studied temperature range for the catalyst containing only aluminum, whereas remaining practically constant for the Cr-containing catalysts. Highly promising propylene yields at low temperature were obtained with the catalyst containing Al and Cr (Al–Cr–C): 9.3% at 350 °C and 10.3% at 450 °C.Fil: de León, María Andrea. Universidad de la República; UruguayFil: De los Santos, Carolina. Universidad de la República; UruguayFil: Latronica, Luis. Universidad de la República; UruguayFil: Cesio, Ana Maria. Provincia de Buenos Aires. Gobernación. Comision de Invest.científicas. Centro de Tecnología de Recursos Minerales y Ceramica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - la Plata. Centro de Tecnología de Recursos Minerales y Ceramica; ArgentinaFil: Volzone, Cristina. Provincia de Buenos Aires. Gobernación. Comision de Invest.científicas. Centro de Tecnología de Recursos Minerales y Ceramica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - la Plata. Centro de Tecnología de Recursos Minerales y Ceramica; ArgentinaFil: Castiglioni, Jorge. Universidad de la República; UruguayFil: Sergio, Marta. Universidad de la República; UruguayElsevier Science Sa2013-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/24499de León, María Andrea; De los Santos, Carolina; Latronica, Luis; Cesio, Ana Maria; Volzone, Cristina; et al.; High catalytic activity at low temperature in oxidative dehydrogenation of propane with Cr–Al pillared clay; Elsevier Science Sa; Chemical Engineering Journal; 241; 10-2013; 336-3431385-8947CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.cej.2013.10.086info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S1385894713014150info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:51:52Zoai:ri.conicet.gov.ar:11336/24499instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:51:52.931CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv High catalytic activity at low temperature in oxidative dehydrogenation of propane with Cr–Al pillared clay
title High catalytic activity at low temperature in oxidative dehydrogenation of propane with Cr–Al pillared clay
spellingShingle High catalytic activity at low temperature in oxidative dehydrogenation of propane with Cr–Al pillared clay
de León, María Andrea
Oxidative Dehydrogenation
Propane
Propene
Al–Cr-Pilc
title_short High catalytic activity at low temperature in oxidative dehydrogenation of propane with Cr–Al pillared clay
title_full High catalytic activity at low temperature in oxidative dehydrogenation of propane with Cr–Al pillared clay
title_fullStr High catalytic activity at low temperature in oxidative dehydrogenation of propane with Cr–Al pillared clay
title_full_unstemmed High catalytic activity at low temperature in oxidative dehydrogenation of propane with Cr–Al pillared clay
title_sort High catalytic activity at low temperature in oxidative dehydrogenation of propane with Cr–Al pillared clay
dc.creator.none.fl_str_mv de León, María Andrea
De los Santos, Carolina
Latronica, Luis
Cesio, Ana Maria
Volzone, Cristina
Castiglioni, Jorge
Sergio, Marta
author de León, María Andrea
author_facet de León, María Andrea
De los Santos, Carolina
Latronica, Luis
Cesio, Ana Maria
Volzone, Cristina
Castiglioni, Jorge
Sergio, Marta
author_role author
author2 De los Santos, Carolina
Latronica, Luis
Cesio, Ana Maria
Volzone, Cristina
Castiglioni, Jorge
Sergio, Marta
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv Oxidative Dehydrogenation
Propane
Propene
Al–Cr-Pilc
topic Oxidative Dehydrogenation
Propane
Propene
Al–Cr-Pilc
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv A montmorillonite was pillared separately with chromium and aluminum polyoxocations (Cr–C and Al–C respectively) and also with an equimolar mixture of both polioxocations (Al–Cr–C). The resulting solids were characterized by scanning electron microscopy, energy dispersive spectrometry, thermal analysis, Fourier transform infrared spectroscopy, X-ray diffraction and nitrogen adsorption at −196 °C. The inclusion of polycations in the interlamellar space led to modifications in the properties of the clay. An eleven fold increase in specific surface area with respect to the calcined starting clay was found for the Al–C, whereas a twofold increase was observed for the Cr–C; the value for the Al–Cr–C was only slightly higher than that for the latter. Diffractograms of the Cr–C showed the occurrence of a Cr2O3 phase. Catalytic activity in oxidative dehydrogenation of propane was assayed in the temperature range from 350 °C to 450 °C using Ar/C3H8/O2 (80/10/10) as reactant gas mixture. Propylene selectivity was found to be temperature-dependent, showing a maximum in the studied temperature range for the catalyst containing only aluminum, whereas remaining practically constant for the Cr-containing catalysts. Highly promising propylene yields at low temperature were obtained with the catalyst containing Al and Cr (Al–Cr–C): 9.3% at 350 °C and 10.3% at 450 °C.
Fil: de León, María Andrea. Universidad de la República; Uruguay
Fil: De los Santos, Carolina. Universidad de la República; Uruguay
Fil: Latronica, Luis. Universidad de la República; Uruguay
Fil: Cesio, Ana Maria. Provincia de Buenos Aires. Gobernación. Comision de Invest.científicas. Centro de Tecnología de Recursos Minerales y Ceramica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - la Plata. Centro de Tecnología de Recursos Minerales y Ceramica; Argentina
Fil: Volzone, Cristina. Provincia de Buenos Aires. Gobernación. Comision de Invest.científicas. Centro de Tecnología de Recursos Minerales y Ceramica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - la Plata. Centro de Tecnología de Recursos Minerales y Ceramica; Argentina
Fil: Castiglioni, Jorge. Universidad de la República; Uruguay
Fil: Sergio, Marta. Universidad de la República; Uruguay
description A montmorillonite was pillared separately with chromium and aluminum polyoxocations (Cr–C and Al–C respectively) and also with an equimolar mixture of both polioxocations (Al–Cr–C). The resulting solids were characterized by scanning electron microscopy, energy dispersive spectrometry, thermal analysis, Fourier transform infrared spectroscopy, X-ray diffraction and nitrogen adsorption at −196 °C. The inclusion of polycations in the interlamellar space led to modifications in the properties of the clay. An eleven fold increase in specific surface area with respect to the calcined starting clay was found for the Al–C, whereas a twofold increase was observed for the Cr–C; the value for the Al–Cr–C was only slightly higher than that for the latter. Diffractograms of the Cr–C showed the occurrence of a Cr2O3 phase. Catalytic activity in oxidative dehydrogenation of propane was assayed in the temperature range from 350 °C to 450 °C using Ar/C3H8/O2 (80/10/10) as reactant gas mixture. Propylene selectivity was found to be temperature-dependent, showing a maximum in the studied temperature range for the catalyst containing only aluminum, whereas remaining practically constant for the Cr-containing catalysts. Highly promising propylene yields at low temperature were obtained with the catalyst containing Al and Cr (Al–Cr–C): 9.3% at 350 °C and 10.3% at 450 °C.
publishDate 2013
dc.date.none.fl_str_mv 2013-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/24499
de León, María Andrea; De los Santos, Carolina; Latronica, Luis; Cesio, Ana Maria; Volzone, Cristina; et al.; High catalytic activity at low temperature in oxidative dehydrogenation of propane with Cr–Al pillared clay; Elsevier Science Sa; Chemical Engineering Journal; 241; 10-2013; 336-343
1385-8947
CONICET Digital
CONICET
url http://hdl.handle.net/11336/24499
identifier_str_mv de León, María Andrea; De los Santos, Carolina; Latronica, Luis; Cesio, Ana Maria; Volzone, Cristina; et al.; High catalytic activity at low temperature in oxidative dehydrogenation of propane with Cr–Al pillared clay; Elsevier Science Sa; Chemical Engineering Journal; 241; 10-2013; 336-343
1385-8947
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.cej.2013.10.086
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S1385894713014150
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science Sa
publisher.none.fl_str_mv Elsevier Science Sa
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1842269122488958976
score 13.13397

Publicaciones similares