Influence of concentration and order of aggregation of the active phases in V-Mo-O catalysts in the oxidative dehydrogenation of propane

Autores
Murgia, Viviana; Farfan Torres, Elsa Monica; Gottifredi, Juan Carlos Agustin; Sham, Edgardo Ling
Año de publicación
2008
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The activation of alkanes by oxidative route is an alternative way to obtain products with greater added value. The mixed catalysts obtained by impregnation of Mo and V on different supports conform a potentially attractive system to achieve dehydrogenation of propane. The activity and selectivity depend on the Mo/V ratio used. In this work, we have studied the effect of the concentration and the order of incorporation of the active phases on the catalytic behavior and the nature of the acid sites on the catalyst surface for this reaction. Catalysts with weight contents of 1.4 and 2.8% of vanadium and/or 4 and 8% of molybdenum were prepared. The results show that for solids with low vanadium load the order of aggregation of the active phases does not modify the catalytic behavior. When vanadium load increases, greater conversion is observed when molybdenum is incorporated in the first place. This behavior can be related to the formation of Mo-V-O species. The catalytic properties are also influenced by the nature and strength of the acid sites on the surface. © 2008.
Fil: Murgia, Viviana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; Argentina. Universidad Nacional de Salta. Facultad de Ingenieria; Argentina
Fil: Farfan Torres, Elsa Monica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; Argentina. Universidad Nacional de Salta. Facultad de Ciencias Exactas; Argentina
Fil: Gottifredi, Juan Carlos Agustin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; Argentina. Universidad Nacional de Salta. Facultad de Ingenieria; Argentina
Fil: Sham, Edgardo Ling. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; Argentina. Universidad Nacional de Salta. Facultad de Ingenieria; Argentina
Materia
Oxidative Dehydrogenation
Propane
Vanadium-Molybdenum Catalyst
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/66936
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/66936
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Influence of concentration and order of aggregation of the active phases in V-Mo-O catalysts in the oxidative dehydrogenation of propaneMurgia, VivianaFarfan Torres, Elsa MonicaGottifredi, Juan Carlos AgustinSham, Edgardo LingOxidative DehydrogenationPropaneVanadium-Molybdenum Catalysthttps://purl.org/becyt/ford/1.5https://purl.org/becyt/ford/1The activation of alkanes by oxidative route is an alternative way to obtain products with greater added value. The mixed catalysts obtained by impregnation of Mo and V on different supports conform a potentially attractive system to achieve dehydrogenation of propane. The activity and selectivity depend on the Mo/V ratio used. In this work, we have studied the effect of the concentration and the order of incorporation of the active phases on the catalytic behavior and the nature of the acid sites on the catalyst surface for this reaction. Catalysts with weight contents of 1.4 and 2.8% of vanadium and/or 4 and 8% of molybdenum were prepared. The results show that for solids with low vanadium load the order of aggregation of the active phases does not modify the catalytic behavior. When vanadium load increases, greater conversion is observed when molybdenum is incorporated in the first place. This behavior can be related to the formation of Mo-V-O species. The catalytic properties are also influenced by the nature and strength of the acid sites on the surface. © 2008.Fil: Murgia, Viviana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; Argentina. Universidad Nacional de Salta. Facultad de Ingenieria; ArgentinaFil: Farfan Torres, Elsa Monica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; Argentina. Universidad Nacional de Salta. Facultad de Ciencias Exactas; ArgentinaFil: Gottifredi, Juan Carlos Agustin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; Argentina. Universidad Nacional de Salta. Facultad de Ingenieria; ArgentinaFil: Sham, Edgardo Ling. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; Argentina. Universidad Nacional de Salta. Facultad de Ingenieria; ArgentinaElsevier Science2008-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/66936Murgia, Viviana; Farfan Torres, Elsa Monica; Gottifredi, Juan Carlos Agustin; Sham, Edgardo Ling; Influence of concentration and order of aggregation of the active phases in V-Mo-O catalysts in the oxidative dehydrogenation of propane; Elsevier Science; Catalysis Today; 133-135; 1-4; 4-2008; 87-910920-5861CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.cattod.2007.12.038info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0920586107008589info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:33:41Zoai:ri.conicet.gov.ar:11336/66936instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:33:42.183CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Influence of concentration and order of aggregation of the active phases in V-Mo-O catalysts in the oxidative dehydrogenation of propane
title Influence of concentration and order of aggregation of the active phases in V-Mo-O catalysts in the oxidative dehydrogenation of propane
spellingShingle Influence of concentration and order of aggregation of the active phases in V-Mo-O catalysts in the oxidative dehydrogenation of propane
Murgia, Viviana
Oxidative Dehydrogenation
Propane
Vanadium-Molybdenum Catalyst
title_short Influence of concentration and order of aggregation of the active phases in V-Mo-O catalysts in the oxidative dehydrogenation of propane
title_full Influence of concentration and order of aggregation of the active phases in V-Mo-O catalysts in the oxidative dehydrogenation of propane
title_fullStr Influence of concentration and order of aggregation of the active phases in V-Mo-O catalysts in the oxidative dehydrogenation of propane
title_full_unstemmed Influence of concentration and order of aggregation of the active phases in V-Mo-O catalysts in the oxidative dehydrogenation of propane
title_sort Influence of concentration and order of aggregation of the active phases in V-Mo-O catalysts in the oxidative dehydrogenation of propane
dc.creator.none.fl_str_mv Murgia, Viviana
Farfan Torres, Elsa Monica
Gottifredi, Juan Carlos Agustin
Sham, Edgardo Ling
author Murgia, Viviana
author_facet Murgia, Viviana
Farfan Torres, Elsa Monica
Gottifredi, Juan Carlos Agustin
Sham, Edgardo Ling
author_role author
author2 Farfan Torres, Elsa Monica
Gottifredi, Juan Carlos Agustin
Sham, Edgardo Ling
author2_role author
author
author
dc.subject.none.fl_str_mv Oxidative Dehydrogenation
Propane
Vanadium-Molybdenum Catalyst
topic Oxidative Dehydrogenation
Propane
Vanadium-Molybdenum Catalyst
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.5
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The activation of alkanes by oxidative route is an alternative way to obtain products with greater added value. The mixed catalysts obtained by impregnation of Mo and V on different supports conform a potentially attractive system to achieve dehydrogenation of propane. The activity and selectivity depend on the Mo/V ratio used. In this work, we have studied the effect of the concentration and the order of incorporation of the active phases on the catalytic behavior and the nature of the acid sites on the catalyst surface for this reaction. Catalysts with weight contents of 1.4 and 2.8% of vanadium and/or 4 and 8% of molybdenum were prepared. The results show that for solids with low vanadium load the order of aggregation of the active phases does not modify the catalytic behavior. When vanadium load increases, greater conversion is observed when molybdenum is incorporated in the first place. This behavior can be related to the formation of Mo-V-O species. The catalytic properties are also influenced by the nature and strength of the acid sites on the surface. © 2008.
Fil: Murgia, Viviana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; Argentina. Universidad Nacional de Salta. Facultad de Ingenieria; Argentina
Fil: Farfan Torres, Elsa Monica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; Argentina. Universidad Nacional de Salta. Facultad de Ciencias Exactas; Argentina
Fil: Gottifredi, Juan Carlos Agustin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; Argentina. Universidad Nacional de Salta. Facultad de Ingenieria; Argentina
Fil: Sham, Edgardo Ling. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; Argentina. Universidad Nacional de Salta. Facultad de Ingenieria; Argentina
description The activation of alkanes by oxidative route is an alternative way to obtain products with greater added value. The mixed catalysts obtained by impregnation of Mo and V on different supports conform a potentially attractive system to achieve dehydrogenation of propane. The activity and selectivity depend on the Mo/V ratio used. In this work, we have studied the effect of the concentration and the order of incorporation of the active phases on the catalytic behavior and the nature of the acid sites on the catalyst surface for this reaction. Catalysts with weight contents of 1.4 and 2.8% of vanadium and/or 4 and 8% of molybdenum were prepared. The results show that for solids with low vanadium load the order of aggregation of the active phases does not modify the catalytic behavior. When vanadium load increases, greater conversion is observed when molybdenum is incorporated in the first place. This behavior can be related to the formation of Mo-V-O species. The catalytic properties are also influenced by the nature and strength of the acid sites on the surface. © 2008.
publishDate 2008
dc.date.none.fl_str_mv 2008-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/66936
Murgia, Viviana; Farfan Torres, Elsa Monica; Gottifredi, Juan Carlos Agustin; Sham, Edgardo Ling; Influence of concentration and order of aggregation of the active phases in V-Mo-O catalysts in the oxidative dehydrogenation of propane; Elsevier Science; Catalysis Today; 133-135; 1-4; 4-2008; 87-91
0920-5861
CONICET Digital
CONICET
url http://hdl.handle.net/11336/66936
identifier_str_mv Murgia, Viviana; Farfan Torres, Elsa Monica; Gottifredi, Juan Carlos Agustin; Sham, Edgardo Ling; Influence of concentration and order of aggregation of the active phases in V-Mo-O catalysts in the oxidative dehydrogenation of propane; Elsevier Science; Catalysis Today; 133-135; 1-4; 4-2008; 87-91
0920-5861
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.cattod.2007.12.038
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0920586107008589
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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