Synthesis and characterization of MEL and FAU zeolites doped with transition metals for their application to the fine chemistry under microwave irradiation

Autores
Azzolina Jury, Federico; Polaert, Isabelle; Estel, Lionel; Pierella, Liliana Beatriz
Año de publicación
2012
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Doped zeolites with transition metals were prepared for their application to the synthesis of chemical compounds under microwave irradiation. The zeolite crystalline structures were verified by XRD. Their surface areas were determined by the BET method. Lewis and Brönsted acid sites were quantified by FTIR of adsorbed pyridine in zeolites. The characterization of acidic properties revealed the generation of new Lewis acid sites after transition metal incorporation into zeolites. The dielectric properties of compacted zeolites were measured by using a reflection method. The temperature profiles of these compacted beds were measured during heating under microwave irradiation. Heating phenomena in zeolites were interpreted using a modified Debye model. Two main dielectric mechanisms were determined in zeolites: rotational polarization phenomenon and interfacial polarization. The selective catalytic oxidation of styrene with hydrogen peroxide was studied over zeolites doped with transition metals in a batch system, under conventional and microwave heating. Benzaldehyde was the main product in all the samples under study. Styrene conversion showed an important influence of the transition metal nature and content and so, the kind of zeolite structure used. With the present experimental conditions, no difference was proved between microwave and conventional heating neither on activity nor on selectivity.
Fil: Azzolina Jury, Federico. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina. Institut National des Sciences Appliquées; Francia. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Polaert, Isabelle. Institut National des Sciences Appliquées; Francia
Fil: Estel, Lionel. Institut National des Sciences Appliquées; Francia
Fil: Pierella, Liliana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Materia
Zeolites
Dielectric Properties
Microwave
Styrene Oxydation
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/23322
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/23322
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Synthesis and characterization of MEL and FAU zeolites doped with transition metals for their application to the fine chemistry under microwave irradiationAzzolina Jury, FedericoPolaert, IsabelleEstel, LionelPierella, Liliana BeatrizZeolitesDielectric PropertiesMicrowaveStyrene Oxydationhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Doped zeolites with transition metals were prepared for their application to the synthesis of chemical compounds under microwave irradiation. The zeolite crystalline structures were verified by XRD. Their surface areas were determined by the BET method. Lewis and Brönsted acid sites were quantified by FTIR of adsorbed pyridine in zeolites. The characterization of acidic properties revealed the generation of new Lewis acid sites after transition metal incorporation into zeolites. The dielectric properties of compacted zeolites were measured by using a reflection method. The temperature profiles of these compacted beds were measured during heating under microwave irradiation. Heating phenomena in zeolites were interpreted using a modified Debye model. Two main dielectric mechanisms were determined in zeolites: rotational polarization phenomenon and interfacial polarization. The selective catalytic oxidation of styrene with hydrogen peroxide was studied over zeolites doped with transition metals in a batch system, under conventional and microwave heating. Benzaldehyde was the main product in all the samples under study. Styrene conversion showed an important influence of the transition metal nature and content and so, the kind of zeolite structure used. With the present experimental conditions, no difference was proved between microwave and conventional heating neither on activity nor on selectivity.Fil: Azzolina Jury, Federico. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina. Institut National des Sciences Appliquées; Francia. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Polaert, Isabelle. Institut National des Sciences Appliquées; FranciaFil: Estel, Lionel. Institut National des Sciences Appliquées; FranciaFil: Pierella, Liliana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaElsevier Science2012-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/23322Azzolina Jury, Federico; Polaert, Isabelle; Estel, Lionel; Pierella, Liliana Beatriz; Synthesis and characterization of MEL and FAU zeolites doped with transition metals for their application to the fine chemistry under microwave irradiation; Elsevier Science; Applied Catalysis A: General; 453; 12-2012; 92-1010926-860XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2012.11.046info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0926860X1200765Xinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:16:55Zoai:ri.conicet.gov.ar:11336/23322instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:16:56.057CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Synthesis and characterization of MEL and FAU zeolites doped with transition metals for their application to the fine chemistry under microwave irradiation
title Synthesis and characterization of MEL and FAU zeolites doped with transition metals for their application to the fine chemistry under microwave irradiation
spellingShingle Synthesis and characterization of MEL and FAU zeolites doped with transition metals for their application to the fine chemistry under microwave irradiation
Azzolina Jury, Federico
Zeolites
Dielectric Properties
Microwave
Styrene Oxydation
title_short Synthesis and characterization of MEL and FAU zeolites doped with transition metals for their application to the fine chemistry under microwave irradiation
title_full Synthesis and characterization of MEL and FAU zeolites doped with transition metals for their application to the fine chemistry under microwave irradiation
title_fullStr Synthesis and characterization of MEL and FAU zeolites doped with transition metals for their application to the fine chemistry under microwave irradiation
title_full_unstemmed Synthesis and characterization of MEL and FAU zeolites doped with transition metals for their application to the fine chemistry under microwave irradiation
title_sort Synthesis and characterization of MEL and FAU zeolites doped with transition metals for their application to the fine chemistry under microwave irradiation
dc.creator.none.fl_str_mv Azzolina Jury, Federico
Polaert, Isabelle
Estel, Lionel
Pierella, Liliana Beatriz
author Azzolina Jury, Federico
author_facet Azzolina Jury, Federico
Polaert, Isabelle
Estel, Lionel
Pierella, Liliana Beatriz
author_role author
author2 Polaert, Isabelle
Estel, Lionel
Pierella, Liliana Beatriz
author2_role author
author
author
dc.subject.none.fl_str_mv Zeolites
Dielectric Properties
Microwave
Styrene Oxydation
topic Zeolites
Dielectric Properties
Microwave
Styrene Oxydation
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Doped zeolites with transition metals were prepared for their application to the synthesis of chemical compounds under microwave irradiation. The zeolite crystalline structures were verified by XRD. Their surface areas were determined by the BET method. Lewis and Brönsted acid sites were quantified by FTIR of adsorbed pyridine in zeolites. The characterization of acidic properties revealed the generation of new Lewis acid sites after transition metal incorporation into zeolites. The dielectric properties of compacted zeolites were measured by using a reflection method. The temperature profiles of these compacted beds were measured during heating under microwave irradiation. Heating phenomena in zeolites were interpreted using a modified Debye model. Two main dielectric mechanisms were determined in zeolites: rotational polarization phenomenon and interfacial polarization. The selective catalytic oxidation of styrene with hydrogen peroxide was studied over zeolites doped with transition metals in a batch system, under conventional and microwave heating. Benzaldehyde was the main product in all the samples under study. Styrene conversion showed an important influence of the transition metal nature and content and so, the kind of zeolite structure used. With the present experimental conditions, no difference was proved between microwave and conventional heating neither on activity nor on selectivity.
Fil: Azzolina Jury, Federico. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina. Institut National des Sciences Appliquées; Francia. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Polaert, Isabelle. Institut National des Sciences Appliquées; Francia
Fil: Estel, Lionel. Institut National des Sciences Appliquées; Francia
Fil: Pierella, Liliana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
description Doped zeolites with transition metals were prepared for their application to the synthesis of chemical compounds under microwave irradiation. The zeolite crystalline structures were verified by XRD. Their surface areas were determined by the BET method. Lewis and Brönsted acid sites were quantified by FTIR of adsorbed pyridine in zeolites. The characterization of acidic properties revealed the generation of new Lewis acid sites after transition metal incorporation into zeolites. The dielectric properties of compacted zeolites were measured by using a reflection method. The temperature profiles of these compacted beds were measured during heating under microwave irradiation. Heating phenomena in zeolites were interpreted using a modified Debye model. Two main dielectric mechanisms were determined in zeolites: rotational polarization phenomenon and interfacial polarization. The selective catalytic oxidation of styrene with hydrogen peroxide was studied over zeolites doped with transition metals in a batch system, under conventional and microwave heating. Benzaldehyde was the main product in all the samples under study. Styrene conversion showed an important influence of the transition metal nature and content and so, the kind of zeolite structure used. With the present experimental conditions, no difference was proved between microwave and conventional heating neither on activity nor on selectivity.
publishDate 2012
dc.date.none.fl_str_mv 2012-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/23322
Azzolina Jury, Federico; Polaert, Isabelle; Estel, Lionel; Pierella, Liliana Beatriz; Synthesis and characterization of MEL and FAU zeolites doped with transition metals for their application to the fine chemistry under microwave irradiation; Elsevier Science; Applied Catalysis A: General; 453; 12-2012; 92-101
0926-860X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/23322
identifier_str_mv Azzolina Jury, Federico; Polaert, Isabelle; Estel, Lionel; Pierella, Liliana Beatriz; Synthesis and characterization of MEL and FAU zeolites doped with transition metals for their application to the fine chemistry under microwave irradiation; Elsevier Science; Applied Catalysis A: General; 453; 12-2012; 92-101
0926-860X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2012.11.046
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0926860X1200765X
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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