Phase diagrams for the adsorption of monomers with non-additive interactions

Autores
Pinto, Oscar Alejandro; Ramirez Pastor, Antonio Jose; Nieto Quintas, Felix Daniel
Año de publicación
2016
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In several experimental systems phase diagrams coverage-temperature show a strong asymmetry. This behavior can be reproduced by including non-additive lateral interactions. In this work a Monte Carlo study on the canonical assembly of the criticality of monomer adsorption with non-additive interactions is presented. Traditional pairwise energies were replaced by other more general ones where the lateral interaction between two ad-atoms depends on the coverage at first sphere of coordination. This kind of energies includes multibody interactions like three-body interactions and four-body interactions, etc. These energies induce the formation of several non-additive ordered structures. Finite size scaling method was used to classify the order of phase transition of each non-additive phase. On the other hand, the corresponding phase diagrams are formed naturally, in which case the diagrams show strong asymmetries.
Fil: Pinto, Oscar Alejandro. Universidad Nacional de Santiago del Estero. Instituto de Bionanotecnología del Noa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Bionanotecnología del Noa; Argentina
Fil: Ramirez Pastor, Antonio Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina
Fil: Nieto Quintas, Felix Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada ; Argentina
Materia
Computer Simulations
Monte Carlo Simulations
Equilibrium Thermodynamics
Statistical Mechanics
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/44786
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Phase diagrams for the adsorption of monomers with non-additive interactionsPinto, Oscar AlejandroRamirez Pastor, Antonio JoseNieto Quintas, Felix DanielComputer SimulationsMonte Carlo SimulationsEquilibrium ThermodynamicsStatistical Mechanicshttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1In several experimental systems phase diagrams coverage-temperature show a strong asymmetry. This behavior can be reproduced by including non-additive lateral interactions. In this work a Monte Carlo study on the canonical assembly of the criticality of monomer adsorption with non-additive interactions is presented. Traditional pairwise energies were replaced by other more general ones where the lateral interaction between two ad-atoms depends on the coverage at first sphere of coordination. This kind of energies includes multibody interactions like three-body interactions and four-body interactions, etc. These energies induce the formation of several non-additive ordered structures. Finite size scaling method was used to classify the order of phase transition of each non-additive phase. On the other hand, the corresponding phase diagrams are formed naturally, in which case the diagrams show strong asymmetries.Fil: Pinto, Oscar Alejandro. Universidad Nacional de Santiago del Estero. Instituto de Bionanotecnología del Noa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Bionanotecnología del Noa; ArgentinaFil: Ramirez Pastor, Antonio Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; ArgentinaFil: Nieto Quintas, Felix Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada ; ArgentinaElsevier Science2016-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/44786Pinto, Oscar Alejandro; Ramirez Pastor, Antonio Jose; Nieto Quintas, Felix Daniel; Phase diagrams for the adsorption of monomers with non-additive interactions; Elsevier Science; Surface Science; 651; 9-2016; 62-690039-6028CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.susc.2016.03.023info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0039602816300322info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-11-05T09:51:21Zoai:ri.conicet.gov.ar:11336/44786instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-11-05 09:51:21.393CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Phase diagrams for the adsorption of monomers with non-additive interactions
title Phase diagrams for the adsorption of monomers with non-additive interactions
spellingShingle Phase diagrams for the adsorption of monomers with non-additive interactions
Pinto, Oscar Alejandro
Computer Simulations
Monte Carlo Simulations
Equilibrium Thermodynamics
Statistical Mechanics
title_short Phase diagrams for the adsorption of monomers with non-additive interactions
title_full Phase diagrams for the adsorption of monomers with non-additive interactions
title_fullStr Phase diagrams for the adsorption of monomers with non-additive interactions
title_full_unstemmed Phase diagrams for the adsorption of monomers with non-additive interactions
title_sort Phase diagrams for the adsorption of monomers with non-additive interactions
dc.creator.none.fl_str_mv Pinto, Oscar Alejandro
Ramirez Pastor, Antonio Jose
Nieto Quintas, Felix Daniel
author Pinto, Oscar Alejandro
author_facet Pinto, Oscar Alejandro
Ramirez Pastor, Antonio Jose
Nieto Quintas, Felix Daniel
author_role author
author2 Ramirez Pastor, Antonio Jose
Nieto Quintas, Felix Daniel
author2_role author
author
dc.subject.none.fl_str_mv Computer Simulations
Monte Carlo Simulations
Equilibrium Thermodynamics
Statistical Mechanics
topic Computer Simulations
Monte Carlo Simulations
Equilibrium Thermodynamics
Statistical Mechanics
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv In several experimental systems phase diagrams coverage-temperature show a strong asymmetry. This behavior can be reproduced by including non-additive lateral interactions. In this work a Monte Carlo study on the canonical assembly of the criticality of monomer adsorption with non-additive interactions is presented. Traditional pairwise energies were replaced by other more general ones where the lateral interaction between two ad-atoms depends on the coverage at first sphere of coordination. This kind of energies includes multibody interactions like three-body interactions and four-body interactions, etc. These energies induce the formation of several non-additive ordered structures. Finite size scaling method was used to classify the order of phase transition of each non-additive phase. On the other hand, the corresponding phase diagrams are formed naturally, in which case the diagrams show strong asymmetries.
Fil: Pinto, Oscar Alejandro. Universidad Nacional de Santiago del Estero. Instituto de Bionanotecnología del Noa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Bionanotecnología del Noa; Argentina
Fil: Ramirez Pastor, Antonio Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina
Fil: Nieto Quintas, Felix Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada ; Argentina
description In several experimental systems phase diagrams coverage-temperature show a strong asymmetry. This behavior can be reproduced by including non-additive lateral interactions. In this work a Monte Carlo study on the canonical assembly of the criticality of monomer adsorption with non-additive interactions is presented. Traditional pairwise energies were replaced by other more general ones where the lateral interaction between two ad-atoms depends on the coverage at first sphere of coordination. This kind of energies includes multibody interactions like three-body interactions and four-body interactions, etc. These energies induce the formation of several non-additive ordered structures. Finite size scaling method was used to classify the order of phase transition of each non-additive phase. On the other hand, the corresponding phase diagrams are formed naturally, in which case the diagrams show strong asymmetries.
publishDate 2016
dc.date.none.fl_str_mv 2016-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/44786
Pinto, Oscar Alejandro; Ramirez Pastor, Antonio Jose; Nieto Quintas, Felix Daniel; Phase diagrams for the adsorption of monomers with non-additive interactions; Elsevier Science; Surface Science; 651; 9-2016; 62-69
0039-6028
CONICET Digital
CONICET
url http://hdl.handle.net/11336/44786
identifier_str_mv Pinto, Oscar Alejandro; Ramirez Pastor, Antonio Jose; Nieto Quintas, Felix Daniel; Phase diagrams for the adsorption of monomers with non-additive interactions; Elsevier Science; Surface Science; 651; 9-2016; 62-69
0039-6028
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.susc.2016.03.023
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0039602816300322
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.084122

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