Generalized statistical description of adsorption of polyatomics

Autores
Riccardo, Jose Luis; Romá, Federico José; Ramirez Pastor, Antonio Jose
Año de publicación
2005
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Multisite-occupancy adsorption is described as a fractional statistic problem, based on Haldane’s statistics. Site exclusion is characterized by a statistical exclusion parameter, g, which relates to the molecular size and lattice geometry. A general adsorption isotherm is obtained and comparisons with experiments indicate that the spatial configuration of adsorbed molecules and lateral interactions may accurately be assessed from this theory. In addition, the theoretical framework developed in this paper allows to describe orientational transitions occurring in adlayers of polyatomics.
Fil: Riccardo, Jose Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis; Argentina. Universidad Nacional de San Luis. Facultad de Cs.fisico Matemáticas y Naturales. Laboratorio de Cs.de Superficies y Medios Porosos; Argentina
Fil: Romá, Federico José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis; Argentina. Universidad Nacional de San Luis. Facultad de Cs.fisico Matemáticas y Naturales. Laboratorio de Cs.de Superficies y Medios Porosos; Argentina
Fil: Ramirez Pastor, Antonio Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis; Argentina. Universidad Nacional de San Luis. Facultad de Cs.fisico Matemáticas y Naturales. Laboratorio de Cs.de Superficies y Medios Porosos; Argentina
Materia
ADSORPTION ISOTHERMS
MULTISITE OCCUPANCY
QUANTUM FRACTIONAL STATISTICS
MONTE CARLO SIMULATIONS
EQUILIBRIUM THERMODYNAMICS AND STATISTICAL MECHANICS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/158338
Acceder
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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Generalized statistical description of adsorption of polyatomicsRiccardo, Jose LuisRomá, Federico JoséRamirez Pastor, Antonio JoseADSORPTION ISOTHERMSMULTISITE OCCUPANCYQUANTUM FRACTIONAL STATISTICSMONTE CARLO SIMULATIONSEQUILIBRIUM THERMODYNAMICS AND STATISTICAL MECHANICShttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1Multisite-occupancy adsorption is described as a fractional statistic problem, based on Haldane’s statistics. Site exclusion is characterized by a statistical exclusion parameter, g, which relates to the molecular size and lattice geometry. A general adsorption isotherm is obtained and comparisons with experiments indicate that the spatial configuration of adsorbed molecules and lateral interactions may accurately be assessed from this theory. In addition, the theoretical framework developed in this paper allows to describe orientational transitions occurring in adlayers of polyatomics.Fil: Riccardo, Jose Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis; Argentina. Universidad Nacional de San Luis. Facultad de Cs.fisico Matemáticas y Naturales. Laboratorio de Cs.de Superficies y Medios Porosos; ArgentinaFil: Romá, Federico José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis; Argentina. Universidad Nacional de San Luis. Facultad de Cs.fisico Matemáticas y Naturales. Laboratorio de Cs.de Superficies y Medios Porosos; ArgentinaFil: Ramirez Pastor, Antonio Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis; Argentina. Universidad Nacional de San Luis. Facultad de Cs.fisico Matemáticas y Naturales. Laboratorio de Cs.de Superficies y Medios Porosos; ArgentinaElsevier Science2005-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/158338Riccardo, Jose Luis; Romá, Federico José; Ramirez Pastor, Antonio Jose; Generalized statistical description of adsorption of polyatomics; Elsevier Science; Applied Surface Science; 252; 3; 12-2005; 505-5110169-4332CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.apsusc.2005.02.067info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0169433205003028info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:06:47Zoai:ri.conicet.gov.ar:11336/158338instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:06:47.743CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Generalized statistical description of adsorption of polyatomics
title Generalized statistical description of adsorption of polyatomics
spellingShingle Generalized statistical description of adsorption of polyatomics
Riccardo, Jose Luis
ADSORPTION ISOTHERMS
MULTISITE OCCUPANCY
QUANTUM FRACTIONAL STATISTICS
MONTE CARLO SIMULATIONS
EQUILIBRIUM THERMODYNAMICS AND STATISTICAL MECHANICS
title_short Generalized statistical description of adsorption of polyatomics
title_full Generalized statistical description of adsorption of polyatomics
title_fullStr Generalized statistical description of adsorption of polyatomics
title_full_unstemmed Generalized statistical description of adsorption of polyatomics
title_sort Generalized statistical description of adsorption of polyatomics
dc.creator.none.fl_str_mv Riccardo, Jose Luis
Romá, Federico José
Ramirez Pastor, Antonio Jose
author Riccardo, Jose Luis
author_facet Riccardo, Jose Luis
Romá, Federico José
Ramirez Pastor, Antonio Jose
author_role author
author2 Romá, Federico José
Ramirez Pastor, Antonio Jose
author2_role author
author
dc.subject.none.fl_str_mv ADSORPTION ISOTHERMS
MULTISITE OCCUPANCY
QUANTUM FRACTIONAL STATISTICS
MONTE CARLO SIMULATIONS
EQUILIBRIUM THERMODYNAMICS AND STATISTICAL MECHANICS
topic ADSORPTION ISOTHERMS
MULTISITE OCCUPANCY
QUANTUM FRACTIONAL STATISTICS
MONTE CARLO SIMULATIONS
EQUILIBRIUM THERMODYNAMICS AND STATISTICAL MECHANICS
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Multisite-occupancy adsorption is described as a fractional statistic problem, based on Haldane’s statistics. Site exclusion is characterized by a statistical exclusion parameter, g, which relates to the molecular size and lattice geometry. A general adsorption isotherm is obtained and comparisons with experiments indicate that the spatial configuration of adsorbed molecules and lateral interactions may accurately be assessed from this theory. In addition, the theoretical framework developed in this paper allows to describe orientational transitions occurring in adlayers of polyatomics.
Fil: Riccardo, Jose Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis; Argentina. Universidad Nacional de San Luis. Facultad de Cs.fisico Matemáticas y Naturales. Laboratorio de Cs.de Superficies y Medios Porosos; Argentina
Fil: Romá, Federico José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis; Argentina. Universidad Nacional de San Luis. Facultad de Cs.fisico Matemáticas y Naturales. Laboratorio de Cs.de Superficies y Medios Porosos; Argentina
Fil: Ramirez Pastor, Antonio Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis; Argentina. Universidad Nacional de San Luis. Facultad de Cs.fisico Matemáticas y Naturales. Laboratorio de Cs.de Superficies y Medios Porosos; Argentina
description Multisite-occupancy adsorption is described as a fractional statistic problem, based on Haldane’s statistics. Site exclusion is characterized by a statistical exclusion parameter, g, which relates to the molecular size and lattice geometry. A general adsorption isotherm is obtained and comparisons with experiments indicate that the spatial configuration of adsorbed molecules and lateral interactions may accurately be assessed from this theory. In addition, the theoretical framework developed in this paper allows to describe orientational transitions occurring in adlayers of polyatomics.
publishDate 2005
dc.date.none.fl_str_mv 2005-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/158338
Riccardo, Jose Luis; Romá, Federico José; Ramirez Pastor, Antonio Jose; Generalized statistical description of adsorption of polyatomics; Elsevier Science; Applied Surface Science; 252; 3; 12-2005; 505-511
0169-4332
CONICET Digital
CONICET
url http://hdl.handle.net/11336/158338
identifier_str_mv Riccardo, Jose Luis; Romá, Federico José; Ramirez Pastor, Antonio Jose; Generalized statistical description of adsorption of polyatomics; Elsevier Science; Applied Surface Science; 252; 3; 12-2005; 505-511
0169-4332
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apsusc.2005.02.067
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0169433205003028
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1842269974570205184
score 13.13397

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