Structure and reactivity of synthetic Co-substituted goethites
- Autores
- Alvarez, Mariana; Sileo, Elsa Ester; Rueda, Elsa Haydee
- Año de publicación
- 2008
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- A set of synthetic goethites were prepared from Fe3+- and Co2+-nitrate solutions in alkaline media with a Co/(Co + Fe) ratio (xCo) up to 10 mol%. The structural characterization of the resultant solid phases was carried out by X-ray diffraction (XRD). XRD analyses showed that in preparations with xCo <10 mol%, Co-substituted goethite was the only crystalline phase present. Atomic and cell parameters for the samples synthesized were obtained by the Rietveld refinement of the XRD data, and showed that the unit cell in the goethite-like phase is contracted as a function of xCo. Little deviation from the Vegard rule was observed for all unit-cell parameters. Cobalt substitution produces an increase in the surface area of the goethite, as well as an increment in the dehydroxylation temperature. The acid dissolution of all Co-goethites showed an increase in dissolution rate with the Co content, and a congruent behavior was observed. The activation energy for dissolution was obtained two samples. A modified first-order Kabai equation best describes the dissolution data.
Fil: Alvarez, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca; Argentina. Universidad Nacional del Sur. Departamento de Química; Argentina
Fil: Sileo, Elsa Ester. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Rueda, Elsa Haydee. Universidad Nacional del Sur. Departamento de Química; Argentina - Materia
-
Acid Dissolution
Co-Goethite
Isomorphous Substitution
Rietveld Refinement - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/75482
Ver los metadatos del registro completo
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Structure and reactivity of synthetic Co-substituted goethitesAlvarez, MarianaSileo, Elsa EsterRueda, Elsa HaydeeAcid DissolutionCo-GoethiteIsomorphous SubstitutionRietveld Refinementhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A set of synthetic goethites were prepared from Fe3+- and Co2+-nitrate solutions in alkaline media with a Co/(Co + Fe) ratio (xCo) up to 10 mol%. The structural characterization of the resultant solid phases was carried out by X-ray diffraction (XRD). XRD analyses showed that in preparations with xCo <10 mol%, Co-substituted goethite was the only crystalline phase present. Atomic and cell parameters for the samples synthesized were obtained by the Rietveld refinement of the XRD data, and showed that the unit cell in the goethite-like phase is contracted as a function of xCo. Little deviation from the Vegard rule was observed for all unit-cell parameters. Cobalt substitution produces an increase in the surface area of the goethite, as well as an increment in the dehydroxylation temperature. The acid dissolution of all Co-goethites showed an increase in dissolution rate with the Co content, and a congruent behavior was observed. The activation energy for dissolution was obtained two samples. A modified first-order Kabai equation best describes the dissolution data.Fil: Alvarez, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca; Argentina. Universidad Nacional del Sur. Departamento de Química; ArgentinaFil: Sileo, Elsa Ester. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaFil: Rueda, Elsa Haydee. Universidad Nacional del Sur. Departamento de Química; ArgentinaMineralogical Society of America2008-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/75482Alvarez, Mariana; Sileo, Elsa Ester; Rueda, Elsa Haydee; Structure and reactivity of synthetic Co-substituted goethites; Mineralogical Society of America; American Mineralogist; 93; 4; 4-2008; 584-5900003-004X1945-3027CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.2138/am.2008.2608info:eu-repo/semantics/altIdentifier/url/https://pubs.geoscienceworld.org/msa/ammin/article/93/4/584-590/44632info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:36:19Zoai:ri.conicet.gov.ar:11336/75482instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:36:19.756CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Structure and reactivity of synthetic Co-substituted goethites |
title |
Structure and reactivity of synthetic Co-substituted goethites |
spellingShingle |
Structure and reactivity of synthetic Co-substituted goethites Alvarez, Mariana Acid Dissolution Co-Goethite Isomorphous Substitution Rietveld Refinement |
title_short |
Structure and reactivity of synthetic Co-substituted goethites |
title_full |
Structure and reactivity of synthetic Co-substituted goethites |
title_fullStr |
Structure and reactivity of synthetic Co-substituted goethites |
title_full_unstemmed |
Structure and reactivity of synthetic Co-substituted goethites |
title_sort |
Structure and reactivity of synthetic Co-substituted goethites |
dc.creator.none.fl_str_mv |
Alvarez, Mariana Sileo, Elsa Ester Rueda, Elsa Haydee |
author |
Alvarez, Mariana |
author_facet |
Alvarez, Mariana Sileo, Elsa Ester Rueda, Elsa Haydee |
author_role |
author |
author2 |
Sileo, Elsa Ester Rueda, Elsa Haydee |
author2_role |
author author |
dc.subject.none.fl_str_mv |
Acid Dissolution Co-Goethite Isomorphous Substitution Rietveld Refinement |
topic |
Acid Dissolution Co-Goethite Isomorphous Substitution Rietveld Refinement |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
A set of synthetic goethites were prepared from Fe3+- and Co2+-nitrate solutions in alkaline media with a Co/(Co + Fe) ratio (xCo) up to 10 mol%. The structural characterization of the resultant solid phases was carried out by X-ray diffraction (XRD). XRD analyses showed that in preparations with xCo <10 mol%, Co-substituted goethite was the only crystalline phase present. Atomic and cell parameters for the samples synthesized were obtained by the Rietveld refinement of the XRD data, and showed that the unit cell in the goethite-like phase is contracted as a function of xCo. Little deviation from the Vegard rule was observed for all unit-cell parameters. Cobalt substitution produces an increase in the surface area of the goethite, as well as an increment in the dehydroxylation temperature. The acid dissolution of all Co-goethites showed an increase in dissolution rate with the Co content, and a congruent behavior was observed. The activation energy for dissolution was obtained two samples. A modified first-order Kabai equation best describes the dissolution data. Fil: Alvarez, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca; Argentina. Universidad Nacional del Sur. Departamento de Química; Argentina Fil: Sileo, Elsa Ester. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina Fil: Rueda, Elsa Haydee. Universidad Nacional del Sur. Departamento de Química; Argentina |
description |
A set of synthetic goethites were prepared from Fe3+- and Co2+-nitrate solutions in alkaline media with a Co/(Co + Fe) ratio (xCo) up to 10 mol%. The structural characterization of the resultant solid phases was carried out by X-ray diffraction (XRD). XRD analyses showed that in preparations with xCo <10 mol%, Co-substituted goethite was the only crystalline phase present. Atomic and cell parameters for the samples synthesized were obtained by the Rietveld refinement of the XRD data, and showed that the unit cell in the goethite-like phase is contracted as a function of xCo. Little deviation from the Vegard rule was observed for all unit-cell parameters. Cobalt substitution produces an increase in the surface area of the goethite, as well as an increment in the dehydroxylation temperature. The acid dissolution of all Co-goethites showed an increase in dissolution rate with the Co content, and a congruent behavior was observed. The activation energy for dissolution was obtained two samples. A modified first-order Kabai equation best describes the dissolution data. |
publishDate |
2008 |
dc.date.none.fl_str_mv |
2008-04 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/75482 Alvarez, Mariana; Sileo, Elsa Ester; Rueda, Elsa Haydee; Structure and reactivity of synthetic Co-substituted goethites; Mineralogical Society of America; American Mineralogist; 93; 4; 4-2008; 584-590 0003-004X 1945-3027 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/75482 |
identifier_str_mv |
Alvarez, Mariana; Sileo, Elsa Ester; Rueda, Elsa Haydee; Structure and reactivity of synthetic Co-substituted goethites; Mineralogical Society of America; American Mineralogist; 93; 4; 4-2008; 584-590 0003-004X 1945-3027 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.2138/am.2008.2608 info:eu-repo/semantics/altIdentifier/url/https://pubs.geoscienceworld.org/msa/ammin/article/93/4/584-590/44632 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Mineralogical Society of America |
publisher.none.fl_str_mv |
Mineralogical Society of America |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844614383426076672 |
score |
13.070432 |