Synthesis and crystal structure refinement by th Rietveld method of an antimony-bearing titanite Ca(Ti0.6Al0.2Sb0.2)OSiO4

Autores
Colombo, Fernando; Pannunzio Miner, Elisa Victoria
Año de publicación
2009
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A synthetic analogue, Ca(Ti0.6Al0.2Sb0.2)OSiO4, of antimony-bearing titanite of a composition similar to that found at St. Marcel-Praborna (Italy) was synthesized using ceramic methods and the crystal structure was refined using the Rietveld method. Unit-cell dimensions (in Å) are a=7.0184(1), b=8.7097(2), c=6.5586(1), and β=113.700(1)°. The substitution of 40% Ti by (Al+Sb) in octahedra causes a loss of long-range coherency of the off-centered Ti atoms. The space group of Sb-bearing titanite is A2/a, like other cases of M3+-M5+-doped titanites. This study confirms that titanite with up to 0.2 Sb atom per f.u. can exist and that the substitution scheme is 2Ti4+↔Al3++Sb5+.
Fil: Colombo, Fernando. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas, Físicas y Naturales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Pannunzio Miner, Elisa Victoria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Materia
Doped Titanite
Antimony
Rietveld Refinement
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/58131
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Synthesis and crystal structure refinement by th Rietveld method of an antimony-bearing titanite Ca(Ti0.6Al0.2Sb0.2)OSiO4Colombo, FernandoPannunzio Miner, Elisa VictoriaDoped TitaniteAntimonyRietveld Refinementhttps://purl.org/becyt/ford/1.5https://purl.org/becyt/ford/1A synthetic analogue, Ca(Ti0.6Al0.2Sb0.2)OSiO4, of antimony-bearing titanite of a composition similar to that found at St. Marcel-Praborna (Italy) was synthesized using ceramic methods and the crystal structure was refined using the Rietveld method. Unit-cell dimensions (in Å) are a=7.0184(1), b=8.7097(2), c=6.5586(1), and β=113.700(1)°. The substitution of 40% Ti by (Al+Sb) in octahedra causes a loss of long-range coherency of the off-centered Ti atoms. The space group of Sb-bearing titanite is A2/a, like other cases of M3+-M5+-doped titanites. This study confirms that titanite with up to 0.2 Sb atom per f.u. can exist and that the substitution scheme is 2Ti4+↔Al3++Sb5+.Fil: Colombo, Fernando. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas, Físicas y Naturales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Pannunzio Miner, Elisa Victoria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaCambridge University Press2009-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/58131Colombo, Fernando; Pannunzio Miner, Elisa Victoria; Synthesis and crystal structure refinement by th Rietveld method of an antimony-bearing titanite Ca(Ti0.6Al0.2Sb0.2)OSiO4; Cambridge University Press; Powder Diffraction; 24; 3; 9-2009; 221-2270885-71561945-7413CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.cambridge.org/core/journals/powder-diffraction/article/synthesis-and-crystal-structure-refinement-by-the-rietveld-method-of-antimony-bearing-titanite-cati06al02sb02osio4/2D0D74FF4C28B8F3F1446DF78F148283info:eu-repo/semantics/altIdentifier/doi/10.1154/1.3194249info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-11-05T10:07:41Zoai:ri.conicet.gov.ar:11336/58131instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-11-05 10:07:41.646CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Synthesis and crystal structure refinement by th Rietveld method of an antimony-bearing titanite Ca(Ti0.6Al0.2Sb0.2)OSiO4
title Synthesis and crystal structure refinement by th Rietveld method of an antimony-bearing titanite Ca(Ti0.6Al0.2Sb0.2)OSiO4
spellingShingle Synthesis and crystal structure refinement by th Rietveld method of an antimony-bearing titanite Ca(Ti0.6Al0.2Sb0.2)OSiO4
Colombo, Fernando
Doped Titanite
Antimony
Rietveld Refinement
title_short Synthesis and crystal structure refinement by th Rietveld method of an antimony-bearing titanite Ca(Ti0.6Al0.2Sb0.2)OSiO4
title_full Synthesis and crystal structure refinement by th Rietveld method of an antimony-bearing titanite Ca(Ti0.6Al0.2Sb0.2)OSiO4
title_fullStr Synthesis and crystal structure refinement by th Rietveld method of an antimony-bearing titanite Ca(Ti0.6Al0.2Sb0.2)OSiO4
title_full_unstemmed Synthesis and crystal structure refinement by th Rietveld method of an antimony-bearing titanite Ca(Ti0.6Al0.2Sb0.2)OSiO4
title_sort Synthesis and crystal structure refinement by th Rietveld method of an antimony-bearing titanite Ca(Ti0.6Al0.2Sb0.2)OSiO4
dc.creator.none.fl_str_mv Colombo, Fernando
Pannunzio Miner, Elisa Victoria
author Colombo, Fernando
author_facet Colombo, Fernando
Pannunzio Miner, Elisa Victoria
author_role author
author2 Pannunzio Miner, Elisa Victoria
author2_role author
dc.subject.none.fl_str_mv Doped Titanite
Antimony
Rietveld Refinement
topic Doped Titanite
Antimony
Rietveld Refinement
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.5
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv A synthetic analogue, Ca(Ti0.6Al0.2Sb0.2)OSiO4, of antimony-bearing titanite of a composition similar to that found at St. Marcel-Praborna (Italy) was synthesized using ceramic methods and the crystal structure was refined using the Rietveld method. Unit-cell dimensions (in Å) are a=7.0184(1), b=8.7097(2), c=6.5586(1), and β=113.700(1)°. The substitution of 40% Ti by (Al+Sb) in octahedra causes a loss of long-range coherency of the off-centered Ti atoms. The space group of Sb-bearing titanite is A2/a, like other cases of M3+-M5+-doped titanites. This study confirms that titanite with up to 0.2 Sb atom per f.u. can exist and that the substitution scheme is 2Ti4+↔Al3++Sb5+.
Fil: Colombo, Fernando. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas, Físicas y Naturales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Pannunzio Miner, Elisa Victoria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
description A synthetic analogue, Ca(Ti0.6Al0.2Sb0.2)OSiO4, of antimony-bearing titanite of a composition similar to that found at St. Marcel-Praborna (Italy) was synthesized using ceramic methods and the crystal structure was refined using the Rietveld method. Unit-cell dimensions (in Å) are a=7.0184(1), b=8.7097(2), c=6.5586(1), and β=113.700(1)°. The substitution of 40% Ti by (Al+Sb) in octahedra causes a loss of long-range coherency of the off-centered Ti atoms. The space group of Sb-bearing titanite is A2/a, like other cases of M3+-M5+-doped titanites. This study confirms that titanite with up to 0.2 Sb atom per f.u. can exist and that the substitution scheme is 2Ti4+↔Al3++Sb5+.
publishDate 2009
dc.date.none.fl_str_mv 2009-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/58131
Colombo, Fernando; Pannunzio Miner, Elisa Victoria; Synthesis and crystal structure refinement by th Rietveld method of an antimony-bearing titanite Ca(Ti0.6Al0.2Sb0.2)OSiO4; Cambridge University Press; Powder Diffraction; 24; 3; 9-2009; 221-227
0885-7156
1945-7413
CONICET Digital
CONICET
url http://hdl.handle.net/11336/58131
identifier_str_mv Colombo, Fernando; Pannunzio Miner, Elisa Victoria; Synthesis and crystal structure refinement by th Rietveld method of an antimony-bearing titanite Ca(Ti0.6Al0.2Sb0.2)OSiO4; Cambridge University Press; Powder Diffraction; 24; 3; 9-2009; 221-227
0885-7156
1945-7413
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.cambridge.org/core/journals/powder-diffraction/article/synthesis-and-crystal-structure-refinement-by-the-rietveld-method-of-antimony-bearing-titanite-cati06al02sb02osio4/2D0D74FF4C28B8F3F1446DF78F148283
info:eu-repo/semantics/altIdentifier/doi/10.1154/1.3194249
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Cambridge University Press
publisher.none.fl_str_mv Cambridge University Press
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.082534

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