Selective liquid-phase hydrogenation of fructose to D-mannitol over copper-supported metallic nanoparticles

Autores
Zelin, Juan; Meyer, Camilo Ignacio; Regenhardt, Silvina Andrea; Sebastian, V.; Garetto, Teresita Francisca; Marchi, Alberto Julio
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The selective liquid-phase hydrogenation of d-fructose was studied on Cu-based catalyst, using an ethanol-water (70:30) mixture as solvent. The catalysts were prepared by three different methods: incipient wetness impregnation (Cu/SiO2-I and Cu/Al2O3-I), precipitation–deposition (Cu/SiO2-PD) and co-precipitation (CuMgAl and CuZnAl). After the thermal treatment, the samples were characterized by X-ray diffraction (XRD) and temperature-programmed reduction (TPR). Only a tenorite-like polycrystalline phase, formed by large CuO crystallites, was identified in Cu/SiO2-I, while none crystalline phase was observed in the case of Cu/SiO2-PD. Instead, a unique spinel-like phase was detected with Cu/Al2O3-I, CuMgAl and CuZnAl. Combining XRD and TPR results, we concluded that Cu2+ is highly dispersed in the Cu/SiO2-PD, Cu/Al2O3-I, CuMgAl and CuZnAl calcined precursors. As a consequence, after reduction in H2 flow, the metal dispersion and hydrogen chemisorption capacity of these four samples were one order higher than for Cu/SiO2-I. The catalytic tests showed that Cu/SiO2-PD was not only the most active but also the most selective and stable catalyst of these series: a D-fructose conversion of around 100% was reached after 6 h reaction, with a selectivity to d-mannitol of around 78–80%. These results show that selective hydrogenation of fructose to d-mannitol is favoured over metal Cu nanoparticles dispersed on the surface of a neutral support as SiO2. Additional catalytic tests, varying fructose initial concentration (0.028–0.220 M) and hydrogen pressure (20–40 bar), were carried out with Cu/SiO2-PD. A zero reaction order respect to D-fructose and a second reaction order respect to H2 were estimated. In addition, it was found that d-mannitol selectivity is not dependent on reactant initial concentration and hydrogen pressure.
Fil: Zelin, Juan. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Meyer, Camilo Ignacio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Regenhardt, Silvina Andrea. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Sebastian, V.. Universidad de Zaragoza; España. CIBER de Bioingeniería, Biomateriales y Nanomedicina (CIBER-BBN); España
Fil: Garetto, Teresita Francisca. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Marchi, Alberto Julio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Materia
Cu-Based Catalyst
D-Fructose
D-Mannitol
Liquid-Phase Hydrogenation
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/44589
Acceder
id CONICETDig_c424af06fba21403db47f1eff6269765
oai_identifier_str oai:ri.conicet.gov.ar:11336/44589
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Selective liquid-phase hydrogenation of fructose to D-mannitol over copper-supported metallic nanoparticlesZelin, JuanMeyer, Camilo IgnacioRegenhardt, Silvina AndreaSebastian, V.Garetto, Teresita FranciscaMarchi, Alberto JulioCu-Based CatalystD-FructoseD-MannitolLiquid-Phase Hydrogenationhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2https://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The selective liquid-phase hydrogenation of d-fructose was studied on Cu-based catalyst, using an ethanol-water (70:30) mixture as solvent. The catalysts were prepared by three different methods: incipient wetness impregnation (Cu/SiO2-I and Cu/Al2O3-I), precipitation–deposition (Cu/SiO2-PD) and co-precipitation (CuMgAl and CuZnAl). After the thermal treatment, the samples were characterized by X-ray diffraction (XRD) and temperature-programmed reduction (TPR). Only a tenorite-like polycrystalline phase, formed by large CuO crystallites, was identified in Cu/SiO2-I, while none crystalline phase was observed in the case of Cu/SiO2-PD. Instead, a unique spinel-like phase was detected with Cu/Al2O3-I, CuMgAl and CuZnAl. Combining XRD and TPR results, we concluded that Cu2+ is highly dispersed in the Cu/SiO2-PD, Cu/Al2O3-I, CuMgAl and CuZnAl calcined precursors. As a consequence, after reduction in H2 flow, the metal dispersion and hydrogen chemisorption capacity of these four samples were one order higher than for Cu/SiO2-I. The catalytic tests showed that Cu/SiO2-PD was not only the most active but also the most selective and stable catalyst of these series: a D-fructose conversion of around 100% was reached after 6 h reaction, with a selectivity to d-mannitol of around 78–80%. These results show that selective hydrogenation of fructose to d-mannitol is favoured over metal Cu nanoparticles dispersed on the surface of a neutral support as SiO2. Additional catalytic tests, varying fructose initial concentration (0.028–0.220 M) and hydrogen pressure (20–40 bar), were carried out with Cu/SiO2-PD. A zero reaction order respect to D-fructose and a second reaction order respect to H2 were estimated. In addition, it was found that d-mannitol selectivity is not dependent on reactant initial concentration and hydrogen pressure.Fil: Zelin, Juan. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Meyer, Camilo Ignacio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Regenhardt, Silvina Andrea. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Sebastian, V.. Universidad de Zaragoza; España. CIBER de Bioingeniería, Biomateriales y Nanomedicina (CIBER-BBN); EspañaFil: Garetto, Teresita Francisca. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Marchi, Alberto Julio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaElsevier Science Sa2017-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/44589Zelin, Juan; Meyer, Camilo Ignacio; Regenhardt, Silvina Andrea; Sebastian, V.; Garetto, Teresita Francisca; et al.; Selective liquid-phase hydrogenation of fructose to D-mannitol over copper-supported metallic nanoparticles; Elsevier Science Sa; Chemical Engineering Journal; 319; 7-2017; 48-561385-8947CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.cej.2017.02.127info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T14:27:47Zoai:ri.conicet.gov.ar:11336/44589instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 14:27:47.599CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Selective liquid-phase hydrogenation of fructose to D-mannitol over copper-supported metallic nanoparticles
title Selective liquid-phase hydrogenation of fructose to D-mannitol over copper-supported metallic nanoparticles
spellingShingle Selective liquid-phase hydrogenation of fructose to D-mannitol over copper-supported metallic nanoparticles
Zelin, Juan
Cu-Based Catalyst
D-Fructose
D-Mannitol
Liquid-Phase Hydrogenation
title_short Selective liquid-phase hydrogenation of fructose to D-mannitol over copper-supported metallic nanoparticles
title_full Selective liquid-phase hydrogenation of fructose to D-mannitol over copper-supported metallic nanoparticles
title_fullStr Selective liquid-phase hydrogenation of fructose to D-mannitol over copper-supported metallic nanoparticles
title_full_unstemmed Selective liquid-phase hydrogenation of fructose to D-mannitol over copper-supported metallic nanoparticles
title_sort Selective liquid-phase hydrogenation of fructose to D-mannitol over copper-supported metallic nanoparticles
dc.creator.none.fl_str_mv Zelin, Juan
Meyer, Camilo Ignacio
Regenhardt, Silvina Andrea
Sebastian, V.
Garetto, Teresita Francisca
Marchi, Alberto Julio
author Zelin, Juan
author_facet Zelin, Juan
Meyer, Camilo Ignacio
Regenhardt, Silvina Andrea
Sebastian, V.
Garetto, Teresita Francisca
Marchi, Alberto Julio
author_role author
author2 Meyer, Camilo Ignacio
Regenhardt, Silvina Andrea
Sebastian, V.
Garetto, Teresita Francisca
Marchi, Alberto Julio
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Cu-Based Catalyst
D-Fructose
D-Mannitol
Liquid-Phase Hydrogenation
topic Cu-Based Catalyst
D-Fructose
D-Mannitol
Liquid-Phase Hydrogenation
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The selective liquid-phase hydrogenation of d-fructose was studied on Cu-based catalyst, using an ethanol-water (70:30) mixture as solvent. The catalysts were prepared by three different methods: incipient wetness impregnation (Cu/SiO2-I and Cu/Al2O3-I), precipitation–deposition (Cu/SiO2-PD) and co-precipitation (CuMgAl and CuZnAl). After the thermal treatment, the samples were characterized by X-ray diffraction (XRD) and temperature-programmed reduction (TPR). Only a tenorite-like polycrystalline phase, formed by large CuO crystallites, was identified in Cu/SiO2-I, while none crystalline phase was observed in the case of Cu/SiO2-PD. Instead, a unique spinel-like phase was detected with Cu/Al2O3-I, CuMgAl and CuZnAl. Combining XRD and TPR results, we concluded that Cu2+ is highly dispersed in the Cu/SiO2-PD, Cu/Al2O3-I, CuMgAl and CuZnAl calcined precursors. As a consequence, after reduction in H2 flow, the metal dispersion and hydrogen chemisorption capacity of these four samples were one order higher than for Cu/SiO2-I. The catalytic tests showed that Cu/SiO2-PD was not only the most active but also the most selective and stable catalyst of these series: a D-fructose conversion of around 100% was reached after 6 h reaction, with a selectivity to d-mannitol of around 78–80%. These results show that selective hydrogenation of fructose to d-mannitol is favoured over metal Cu nanoparticles dispersed on the surface of a neutral support as SiO2. Additional catalytic tests, varying fructose initial concentration (0.028–0.220 M) and hydrogen pressure (20–40 bar), were carried out with Cu/SiO2-PD. A zero reaction order respect to D-fructose and a second reaction order respect to H2 were estimated. In addition, it was found that d-mannitol selectivity is not dependent on reactant initial concentration and hydrogen pressure.
Fil: Zelin, Juan. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Meyer, Camilo Ignacio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Regenhardt, Silvina Andrea. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Sebastian, V.. Universidad de Zaragoza; España. CIBER de Bioingeniería, Biomateriales y Nanomedicina (CIBER-BBN); España
Fil: Garetto, Teresita Francisca. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Marchi, Alberto Julio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
description The selective liquid-phase hydrogenation of d-fructose was studied on Cu-based catalyst, using an ethanol-water (70:30) mixture as solvent. The catalysts were prepared by three different methods: incipient wetness impregnation (Cu/SiO2-I and Cu/Al2O3-I), precipitation–deposition (Cu/SiO2-PD) and co-precipitation (CuMgAl and CuZnAl). After the thermal treatment, the samples were characterized by X-ray diffraction (XRD) and temperature-programmed reduction (TPR). Only a tenorite-like polycrystalline phase, formed by large CuO crystallites, was identified in Cu/SiO2-I, while none crystalline phase was observed in the case of Cu/SiO2-PD. Instead, a unique spinel-like phase was detected with Cu/Al2O3-I, CuMgAl and CuZnAl. Combining XRD and TPR results, we concluded that Cu2+ is highly dispersed in the Cu/SiO2-PD, Cu/Al2O3-I, CuMgAl and CuZnAl calcined precursors. As a consequence, after reduction in H2 flow, the metal dispersion and hydrogen chemisorption capacity of these four samples were one order higher than for Cu/SiO2-I. The catalytic tests showed that Cu/SiO2-PD was not only the most active but also the most selective and stable catalyst of these series: a D-fructose conversion of around 100% was reached after 6 h reaction, with a selectivity to d-mannitol of around 78–80%. These results show that selective hydrogenation of fructose to d-mannitol is favoured over metal Cu nanoparticles dispersed on the surface of a neutral support as SiO2. Additional catalytic tests, varying fructose initial concentration (0.028–0.220 M) and hydrogen pressure (20–40 bar), were carried out with Cu/SiO2-PD. A zero reaction order respect to D-fructose and a second reaction order respect to H2 were estimated. In addition, it was found that d-mannitol selectivity is not dependent on reactant initial concentration and hydrogen pressure.
publishDate 2017
dc.date.none.fl_str_mv 2017-07
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/44589
Zelin, Juan; Meyer, Camilo Ignacio; Regenhardt, Silvina Andrea; Sebastian, V.; Garetto, Teresita Francisca; et al.; Selective liquid-phase hydrogenation of fructose to D-mannitol over copper-supported metallic nanoparticles; Elsevier Science Sa; Chemical Engineering Journal; 319; 7-2017; 48-56
1385-8947
CONICET Digital
CONICET
url http://hdl.handle.net/11336/44589
identifier_str_mv Zelin, Juan; Meyer, Camilo Ignacio; Regenhardt, Silvina Andrea; Sebastian, V.; Garetto, Teresita Francisca; et al.; Selective liquid-phase hydrogenation of fructose to D-mannitol over copper-supported metallic nanoparticles; Elsevier Science Sa; Chemical Engineering Journal; 319; 7-2017; 48-56
1385-8947
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.cej.2017.02.127
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science Sa
publisher.none.fl_str_mv Elsevier Science Sa
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.22299

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