Developing alternatives to hydrocarbon via pyrolysis and gasification of industry residual biomass

Autores
Tourn, Silvana Cecilia; Saires, Paula Judith; Bertero, Melisa Paola; Falco, Marisa Guadalupe; Chamorro, Ester Ramona
Año de publicación
2023
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Pyrolysis and gasification are thermal treatment processes using biomass to produce biofuels that can replace fossil fuels in industrial boilers and furnaces. This paper discusses the potential utilization of four types of residual biomass highly produced in the Argentina Northeast (NEA) region, i.e., rice husk, an agricultural waste rich in cotton husk, carob sawdust, and spent red quebracho sawdust, as raw material. Pyrolysis liquid product yields were 34–51 wt% and char yields were 29–40 wt%; tar represented 16–23 wt%. For gasification, gas yields were between 45.6 wt% and 65.7 wt%; as for tar, it represented 2.4–14.1 wt% of initial biomass, and char yields were 31.4–40.3 wt%. Characterization of all products was performed to clarify their potential applications. Bio-oils, i.e., aqueous fractions of pyrolysis liquid products, have high water content (77–88 wt%), that is why they have lower density and viscosity than tars, oil fractions of pyrolysis liquids. However, chemical stability of bio-oils may vary, and their heating values are much lower than the heating values from tars. Based on these, it is possible to concluded that tar is the product with increased added value and higher energy properties. Efficiency of gasification and heating values of the gases obtained were high for waste rich in cotton husk and spent red quebracho sawdust, suggesting a good potential for the utilization in gasification processes. Additionally, char composition and properties for all biomasses, from both process, show that it is feasible to use them in several new applications.
Fil: Tourn, Silvana Cecilia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Modelado e Innovación Tecnológica. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas Naturales y Agrimensura. Instituto de Modelado e Innovación Tecnológica; Argentina. Universidad Tecnológica Nacional. Facultad Regional Resistencia. Centro de Investigación en Química Orgánica Biológica; Argentina
Fil: Saires, Paula Judith. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Bertero, Melisa Paola. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Falco, Marisa Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Chamorro, Ester Ramona. Universidad Tecnológica Nacional. Facultad Regional Resistencia. Centro de Investigación en Química Orgánica Biológica; Argentina
Materia
LIGNOCELLULOSIC RESIDUES
PYROLYSIS
BIO-OIL
TAR
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/229840
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Developing alternatives to hydrocarbon via pyrolysis and gasification of industry residual biomassTourn, Silvana CeciliaSaires, Paula JudithBertero, Melisa PaolaFalco, Marisa GuadalupeChamorro, Ester RamonaLIGNOCELLULOSIC RESIDUESPYROLYSISBIO-OILTARhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Pyrolysis and gasification are thermal treatment processes using biomass to produce biofuels that can replace fossil fuels in industrial boilers and furnaces. This paper discusses the potential utilization of four types of residual biomass highly produced in the Argentina Northeast (NEA) region, i.e., rice husk, an agricultural waste rich in cotton husk, carob sawdust, and spent red quebracho sawdust, as raw material. Pyrolysis liquid product yields were 34–51 wt% and char yields were 29–40 wt%; tar represented 16–23 wt%. For gasification, gas yields were between 45.6 wt% and 65.7 wt%; as for tar, it represented 2.4–14.1 wt% of initial biomass, and char yields were 31.4–40.3 wt%. Characterization of all products was performed to clarify their potential applications. Bio-oils, i.e., aqueous fractions of pyrolysis liquid products, have high water content (77–88 wt%), that is why they have lower density and viscosity than tars, oil fractions of pyrolysis liquids. However, chemical stability of bio-oils may vary, and their heating values are much lower than the heating values from tars. Based on these, it is possible to concluded that tar is the product with increased added value and higher energy properties. Efficiency of gasification and heating values of the gases obtained were high for waste rich in cotton husk and spent red quebracho sawdust, suggesting a good potential for the utilization in gasification processes. Additionally, char composition and properties for all biomasses, from both process, show that it is feasible to use them in several new applications.Fil: Tourn, Silvana Cecilia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Modelado e Innovación Tecnológica. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas Naturales y Agrimensura. Instituto de Modelado e Innovación Tecnológica; Argentina. Universidad Tecnológica Nacional. Facultad Regional Resistencia. Centro de Investigación en Química Orgánica Biológica; ArgentinaFil: Saires, Paula Judith. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Bertero, Melisa Paola. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Falco, Marisa Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Chamorro, Ester Ramona. Universidad Tecnológica Nacional. Facultad Regional Resistencia. Centro de Investigación en Química Orgánica Biológica; ArgentinaPsicoMed Publishing2023-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/229840Tourn, Silvana Cecilia; Saires, Paula Judith; Bertero, Melisa Paola; Falco, Marisa Guadalupe; Chamorro, Ester Ramona; Developing alternatives to hydrocarbon via pyrolysis and gasification of industry residual biomass; PsicoMed Publishing; Progress in Energy & Fuels; 12; 1; 8-2023; 1-232315-4640CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://ojs.piscomed.com/index.php/PEF/article/view/3333info:eu-repo/semantics/altIdentifier/doi/ 10.18282/pef.v12i1.3333info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T14:29:46Zoai:ri.conicet.gov.ar:11336/229840instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 14:29:47.129CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Developing alternatives to hydrocarbon via pyrolysis and gasification of industry residual biomass
title Developing alternatives to hydrocarbon via pyrolysis and gasification of industry residual biomass
spellingShingle Developing alternatives to hydrocarbon via pyrolysis and gasification of industry residual biomass
Tourn, Silvana Cecilia
LIGNOCELLULOSIC RESIDUES
PYROLYSIS
BIO-OIL
TAR
title_short Developing alternatives to hydrocarbon via pyrolysis and gasification of industry residual biomass
title_full Developing alternatives to hydrocarbon via pyrolysis and gasification of industry residual biomass
title_fullStr Developing alternatives to hydrocarbon via pyrolysis and gasification of industry residual biomass
title_full_unstemmed Developing alternatives to hydrocarbon via pyrolysis and gasification of industry residual biomass
title_sort Developing alternatives to hydrocarbon via pyrolysis and gasification of industry residual biomass
dc.creator.none.fl_str_mv Tourn, Silvana Cecilia
Saires, Paula Judith
Bertero, Melisa Paola
Falco, Marisa Guadalupe
Chamorro, Ester Ramona
author Tourn, Silvana Cecilia
author_facet Tourn, Silvana Cecilia
Saires, Paula Judith
Bertero, Melisa Paola
Falco, Marisa Guadalupe
Chamorro, Ester Ramona
author_role author
author2 Saires, Paula Judith
Bertero, Melisa Paola
Falco, Marisa Guadalupe
Chamorro, Ester Ramona
author2_role author
author
author
author
dc.subject.none.fl_str_mv LIGNOCELLULOSIC RESIDUES
PYROLYSIS
BIO-OIL
TAR
topic LIGNOCELLULOSIC RESIDUES
PYROLYSIS
BIO-OIL
TAR
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Pyrolysis and gasification are thermal treatment processes using biomass to produce biofuels that can replace fossil fuels in industrial boilers and furnaces. This paper discusses the potential utilization of four types of residual biomass highly produced in the Argentina Northeast (NEA) region, i.e., rice husk, an agricultural waste rich in cotton husk, carob sawdust, and spent red quebracho sawdust, as raw material. Pyrolysis liquid product yields were 34–51 wt% and char yields were 29–40 wt%; tar represented 16–23 wt%. For gasification, gas yields were between 45.6 wt% and 65.7 wt%; as for tar, it represented 2.4–14.1 wt% of initial biomass, and char yields were 31.4–40.3 wt%. Characterization of all products was performed to clarify their potential applications. Bio-oils, i.e., aqueous fractions of pyrolysis liquid products, have high water content (77–88 wt%), that is why they have lower density and viscosity than tars, oil fractions of pyrolysis liquids. However, chemical stability of bio-oils may vary, and their heating values are much lower than the heating values from tars. Based on these, it is possible to concluded that tar is the product with increased added value and higher energy properties. Efficiency of gasification and heating values of the gases obtained were high for waste rich in cotton husk and spent red quebracho sawdust, suggesting a good potential for the utilization in gasification processes. Additionally, char composition and properties for all biomasses, from both process, show that it is feasible to use them in several new applications.
Fil: Tourn, Silvana Cecilia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Modelado e Innovación Tecnológica. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas Naturales y Agrimensura. Instituto de Modelado e Innovación Tecnológica; Argentina. Universidad Tecnológica Nacional. Facultad Regional Resistencia. Centro de Investigación en Química Orgánica Biológica; Argentina
Fil: Saires, Paula Judith. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Bertero, Melisa Paola. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Falco, Marisa Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Chamorro, Ester Ramona. Universidad Tecnológica Nacional. Facultad Regional Resistencia. Centro de Investigación en Química Orgánica Biológica; Argentina
description Pyrolysis and gasification are thermal treatment processes using biomass to produce biofuels that can replace fossil fuels in industrial boilers and furnaces. This paper discusses the potential utilization of four types of residual biomass highly produced in the Argentina Northeast (NEA) region, i.e., rice husk, an agricultural waste rich in cotton husk, carob sawdust, and spent red quebracho sawdust, as raw material. Pyrolysis liquid product yields were 34–51 wt% and char yields were 29–40 wt%; tar represented 16–23 wt%. For gasification, gas yields were between 45.6 wt% and 65.7 wt%; as for tar, it represented 2.4–14.1 wt% of initial biomass, and char yields were 31.4–40.3 wt%. Characterization of all products was performed to clarify their potential applications. Bio-oils, i.e., aqueous fractions of pyrolysis liquid products, have high water content (77–88 wt%), that is why they have lower density and viscosity than tars, oil fractions of pyrolysis liquids. However, chemical stability of bio-oils may vary, and their heating values are much lower than the heating values from tars. Based on these, it is possible to concluded that tar is the product with increased added value and higher energy properties. Efficiency of gasification and heating values of the gases obtained were high for waste rich in cotton husk and spent red quebracho sawdust, suggesting a good potential for the utilization in gasification processes. Additionally, char composition and properties for all biomasses, from both process, show that it is feasible to use them in several new applications.
publishDate 2023
dc.date.none.fl_str_mv 2023-08
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/229840
Tourn, Silvana Cecilia; Saires, Paula Judith; Bertero, Melisa Paola; Falco, Marisa Guadalupe; Chamorro, Ester Ramona; Developing alternatives to hydrocarbon via pyrolysis and gasification of industry residual biomass; PsicoMed Publishing; Progress in Energy & Fuels; 12; 1; 8-2023; 1-23
2315-4640
CONICET Digital
CONICET
url http://hdl.handle.net/11336/229840
identifier_str_mv Tourn, Silvana Cecilia; Saires, Paula Judith; Bertero, Melisa Paola; Falco, Marisa Guadalupe; Chamorro, Ester Ramona; Developing alternatives to hydrocarbon via pyrolysis and gasification of industry residual biomass; PsicoMed Publishing; Progress in Energy & Fuels; 12; 1; 8-2023; 1-23
2315-4640
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://ojs.piscomed.com/index.php/PEF/article/view/3333
info:eu-repo/semantics/altIdentifier/doi/ 10.18282/pef.v12i1.3333
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv PsicoMed Publishing
publisher.none.fl_str_mv PsicoMed Publishing
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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