Characterization of Pyrolytic Tars Derived from Different Biomasses

Autores
Saires, Paula Judith; Ariza Barraza, Cindy Skarlett; Bertero, Melisa Paola; Pujro Tarquino, Richard Alfonzo; Falco, Marisa Guadalupe; Sedran, Ulises Anselmo
Año de publicación
2024
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The pyrolysis of three different biomasses, rice husk (RH), zoita wood sawdust (ZW) and pine wood sawdust (PW), was studied at 500 ºC in a multipurpose unit at the bench scale to determine the yields of the different products and the compositions and properties of the liquid products, particular emphasis being given to the alquitranous fractions (tars). It was possible to link the characteristics of the tars with the compositions of the raw biomasses and verify their potential in various applications. Analytical techniques employed in the characterization of biomasses included ultimate and proximate analysis, lignocellulosic material and thermogravimetry-mass spectrometry analysis (TG-MS). Elemental analysis, gas chromatography-mass spectrometry (GC-MS), nuclear magnetic resonance spectroscopy (1H NMR), Fourier transform infrared spectroscopy (FTIR) and size exclusion chromatography (SEC) were used to characterize tars. Tar yields were 1.8, 7.4 and 4.0 %wt. in the cases of RH, ZW y PW, respectively. Tars showed higher carbon contents, between 60.3 and 62.2 %wt., and lower oxygen content, between 28.8 and 31.6 %wt., than the corresponding raw biomasses. The main components of tars had aromatic base, phenols representing more than 50 %. Tar RH included more guaiacols, while Tar ZW and PW included more phenols and alkylated phenols.
Fil: Saires, Paula Judith. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Ariza Barraza, Cindy Skarlett. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Bertero, Melisa Paola. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Pujro Tarquino, Richard Alfonzo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Falco, Marisa Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Sedran, Ulises Anselmo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Materia
PYROLYSIS
TAR
PHENOLS
LIGNOCELLULOSIC BIOMASS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/257457
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/257457
network_acronym_str CONICETDig
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network_name_str CONICET Digital (CONICET)
spelling Characterization of Pyrolytic Tars Derived from Different BiomassesSaires, Paula JudithAriza Barraza, Cindy SkarlettBertero, Melisa PaolaPujro Tarquino, Richard AlfonzoFalco, Marisa GuadalupeSedran, Ulises AnselmoPYROLYSISTARPHENOLSLIGNOCELLULOSIC BIOMASShttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The pyrolysis of three different biomasses, rice husk (RH), zoita wood sawdust (ZW) and pine wood sawdust (PW), was studied at 500 ºC in a multipurpose unit at the bench scale to determine the yields of the different products and the compositions and properties of the liquid products, particular emphasis being given to the alquitranous fractions (tars). It was possible to link the characteristics of the tars with the compositions of the raw biomasses and verify their potential in various applications. Analytical techniques employed in the characterization of biomasses included ultimate and proximate analysis, lignocellulosic material and thermogravimetry-mass spectrometry analysis (TG-MS). Elemental analysis, gas chromatography-mass spectrometry (GC-MS), nuclear magnetic resonance spectroscopy (1H NMR), Fourier transform infrared spectroscopy (FTIR) and size exclusion chromatography (SEC) were used to characterize tars. Tar yields were 1.8, 7.4 and 4.0 %wt. in the cases of RH, ZW y PW, respectively. Tars showed higher carbon contents, between 60.3 and 62.2 %wt., and lower oxygen content, between 28.8 and 31.6 %wt., than the corresponding raw biomasses. The main components of tars had aromatic base, phenols representing more than 50 %. Tar RH included more guaiacols, while Tar ZW and PW included more phenols and alkylated phenols.Fil: Saires, Paula Judith. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Ariza Barraza, Cindy Skarlett. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Bertero, Melisa Paola. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Pujro Tarquino, Richard Alfonzo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Falco, Marisa Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Sedran, Ulises Anselmo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaMDPI2024-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/257457Saires, Paula Judith; Ariza Barraza, Cindy Skarlett; Bertero, Melisa Paola; Pujro Tarquino, Richard Alfonzo; Falco, Marisa Guadalupe; et al.; Characterization of Pyrolytic Tars Derived from Different Biomasses; MDPI; Processes; 12; 4; 4-2024; 1-272227-9717CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2227-9717/12/4/817info:eu-repo/semantics/altIdentifier/doi/10.3390/pr12040817info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:52:50Zoai:ri.conicet.gov.ar:11336/257457instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:52:50.317CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Characterization of Pyrolytic Tars Derived from Different Biomasses
title Characterization of Pyrolytic Tars Derived from Different Biomasses
spellingShingle Characterization of Pyrolytic Tars Derived from Different Biomasses
Saires, Paula Judith
PYROLYSIS
TAR
PHENOLS
LIGNOCELLULOSIC BIOMASS
title_short Characterization of Pyrolytic Tars Derived from Different Biomasses
title_full Characterization of Pyrolytic Tars Derived from Different Biomasses
title_fullStr Characterization of Pyrolytic Tars Derived from Different Biomasses
title_full_unstemmed Characterization of Pyrolytic Tars Derived from Different Biomasses
title_sort Characterization of Pyrolytic Tars Derived from Different Biomasses
dc.creator.none.fl_str_mv Saires, Paula Judith
Ariza Barraza, Cindy Skarlett
Bertero, Melisa Paola
Pujro Tarquino, Richard Alfonzo
Falco, Marisa Guadalupe
Sedran, Ulises Anselmo
author Saires, Paula Judith
author_facet Saires, Paula Judith
Ariza Barraza, Cindy Skarlett
Bertero, Melisa Paola
Pujro Tarquino, Richard Alfonzo
Falco, Marisa Guadalupe
Sedran, Ulises Anselmo
author_role author
author2 Ariza Barraza, Cindy Skarlett
Bertero, Melisa Paola
Pujro Tarquino, Richard Alfonzo
Falco, Marisa Guadalupe
Sedran, Ulises Anselmo
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv PYROLYSIS
TAR
PHENOLS
LIGNOCELLULOSIC BIOMASS
topic PYROLYSIS
TAR
PHENOLS
LIGNOCELLULOSIC BIOMASS
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The pyrolysis of three different biomasses, rice husk (RH), zoita wood sawdust (ZW) and pine wood sawdust (PW), was studied at 500 ºC in a multipurpose unit at the bench scale to determine the yields of the different products and the compositions and properties of the liquid products, particular emphasis being given to the alquitranous fractions (tars). It was possible to link the characteristics of the tars with the compositions of the raw biomasses and verify their potential in various applications. Analytical techniques employed in the characterization of biomasses included ultimate and proximate analysis, lignocellulosic material and thermogravimetry-mass spectrometry analysis (TG-MS). Elemental analysis, gas chromatography-mass spectrometry (GC-MS), nuclear magnetic resonance spectroscopy (1H NMR), Fourier transform infrared spectroscopy (FTIR) and size exclusion chromatography (SEC) were used to characterize tars. Tar yields were 1.8, 7.4 and 4.0 %wt. in the cases of RH, ZW y PW, respectively. Tars showed higher carbon contents, between 60.3 and 62.2 %wt., and lower oxygen content, between 28.8 and 31.6 %wt., than the corresponding raw biomasses. The main components of tars had aromatic base, phenols representing more than 50 %. Tar RH included more guaiacols, while Tar ZW and PW included more phenols and alkylated phenols.
Fil: Saires, Paula Judith. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Ariza Barraza, Cindy Skarlett. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Bertero, Melisa Paola. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Pujro Tarquino, Richard Alfonzo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Falco, Marisa Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Sedran, Ulises Anselmo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
description The pyrolysis of three different biomasses, rice husk (RH), zoita wood sawdust (ZW) and pine wood sawdust (PW), was studied at 500 ºC in a multipurpose unit at the bench scale to determine the yields of the different products and the compositions and properties of the liquid products, particular emphasis being given to the alquitranous fractions (tars). It was possible to link the characteristics of the tars with the compositions of the raw biomasses and verify their potential in various applications. Analytical techniques employed in the characterization of biomasses included ultimate and proximate analysis, lignocellulosic material and thermogravimetry-mass spectrometry analysis (TG-MS). Elemental analysis, gas chromatography-mass spectrometry (GC-MS), nuclear magnetic resonance spectroscopy (1H NMR), Fourier transform infrared spectroscopy (FTIR) and size exclusion chromatography (SEC) were used to characterize tars. Tar yields were 1.8, 7.4 and 4.0 %wt. in the cases of RH, ZW y PW, respectively. Tars showed higher carbon contents, between 60.3 and 62.2 %wt., and lower oxygen content, between 28.8 and 31.6 %wt., than the corresponding raw biomasses. The main components of tars had aromatic base, phenols representing more than 50 %. Tar RH included more guaiacols, while Tar ZW and PW included more phenols and alkylated phenols.
publishDate 2024
dc.date.none.fl_str_mv 2024-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/257457
Saires, Paula Judith; Ariza Barraza, Cindy Skarlett; Bertero, Melisa Paola; Pujro Tarquino, Richard Alfonzo; Falco, Marisa Guadalupe; et al.; Characterization of Pyrolytic Tars Derived from Different Biomasses; MDPI; Processes; 12; 4; 4-2024; 1-27
2227-9717
CONICET Digital
CONICET
url http://hdl.handle.net/11336/257457
identifier_str_mv Saires, Paula Judith; Ariza Barraza, Cindy Skarlett; Bertero, Melisa Paola; Pujro Tarquino, Richard Alfonzo; Falco, Marisa Guadalupe; et al.; Characterization of Pyrolytic Tars Derived from Different Biomasses; MDPI; Processes; 12; 4; 4-2024; 1-27
2227-9717
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2227-9717/12/4/817
info:eu-repo/semantics/altIdentifier/doi/10.3390/pr12040817
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv MDPI
publisher.none.fl_str_mv MDPI
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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