Evaluation of the hydration of Portland cement modified with polyvinyl alcohol and nano clay

Autores
Piqué, Teresa María; Balzamo, Humberto Marcelo; Vázquez, Analía
Año de publicación
2011
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Polyvinylalcohol (PVA) is a polymer soluble in hot water, it has the property of film formation and it can improve the concrete performance. The effects of PVA modified with nano clay on the cement hydration reaction have been investigated by means of semiadiabatic calorimeter, FTIR spectroscopy and SEM. FTIR spectroscopy was employed to monitor chemical transformation of cement. The morphology of the different samples was compared by means of SEM micrographs. With the semiadiabatic calorimeter the hydration kinetic was measured to compare the heat rate of the admixtures materials. Fixing the water-cement ratio, w/c, in 0,45, the ratio of polymer to cement (p/c) was 2 wt% and the ratio of clay to polymer was 4 wt% (0.8wt.% related to cement). The polymer and modified polymer admixtures produced a retardation effect on the kinetic of cement hydration, but the clay acts as nucleating agent. The increase of the temperature with time was measured and a new model with four parameters was employed and the kinetic parameters were determined for each sample.
Fil: Piqué, Teresa María. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Oficina de Coordinacion Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingenieria "Hilario Fernandez Long". Grupo Vinculado al Intecin - Grupo Interdisciplinario en Materiales; Argentina
Fil: Balzamo, Humberto Marcelo. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Oficina de Coordinacion Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingenieria "Hilario Fernandez Long". Grupo Vinculado al Intecin - Grupo Interdisciplinario en Materiales; Argentina
Fil: Vázquez, Analía. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Oficina de Coordinacion Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingenieria "Hilario Fernandez Long". Grupo Vinculado al Intecin - Grupo Interdisciplinario en Materiales; Argentina
Materia
BENTONITE
CEMENT
CLAY
HYDRATION
POLYMER
POLYVINYLALCOHOL
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/217692
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/217692
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Evaluation of the hydration of Portland cement modified with polyvinyl alcohol and nano clayPiqué, Teresa MaríaBalzamo, Humberto MarceloVázquez, AnalíaBENTONITECEMENTCLAYHYDRATIONPOLYMERPOLYVINYLALCOHOLhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2https://purl.org/becyt/ford/2.1https://purl.org/becyt/ford/2Polyvinylalcohol (PVA) is a polymer soluble in hot water, it has the property of film formation and it can improve the concrete performance. The effects of PVA modified with nano clay on the cement hydration reaction have been investigated by means of semiadiabatic calorimeter, FTIR spectroscopy and SEM. FTIR spectroscopy was employed to monitor chemical transformation of cement. The morphology of the different samples was compared by means of SEM micrographs. With the semiadiabatic calorimeter the hydration kinetic was measured to compare the heat rate of the admixtures materials. Fixing the water-cement ratio, w/c, in 0,45, the ratio of polymer to cement (p/c) was 2 wt% and the ratio of clay to polymer was 4 wt% (0.8wt.% related to cement). The polymer and modified polymer admixtures produced a retardation effect on the kinetic of cement hydration, but the clay acts as nucleating agent. The increase of the temperature with time was measured and a new model with four parameters was employed and the kinetic parameters were determined for each sample.Fil: Piqué, Teresa María. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Oficina de Coordinacion Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingenieria "Hilario Fernandez Long". Grupo Vinculado al Intecin - Grupo Interdisciplinario en Materiales; ArgentinaFil: Balzamo, Humberto Marcelo. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Oficina de Coordinacion Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingenieria "Hilario Fernandez Long". Grupo Vinculado al Intecin - Grupo Interdisciplinario en Materiales; ArgentinaFil: Vázquez, Analía. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Oficina de Coordinacion Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingenieria "Hilario Fernandez Long". Grupo Vinculado al Intecin - Grupo Interdisciplinario en Materiales; ArgentinaTrans TEch Publishers2011-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/217692Piqué, Teresa María; Balzamo, Humberto Marcelo; Vázquez, Analía; Evaluation of the hydration of Portland cement modified with polyvinyl alcohol and nano clay; Trans TEch Publishers; Key Engineering Materials; 466; 1-2011; 47-561013-9826CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://www.scientific.net/KEM.466.47info:eu-repo/semantics/altIdentifier/doi/10.4028/www.scientific.net/KEM.466.47info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:48:17Zoai:ri.conicet.gov.ar:11336/217692instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:48:17.948CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Evaluation of the hydration of Portland cement modified with polyvinyl alcohol and nano clay
title Evaluation of the hydration of Portland cement modified with polyvinyl alcohol and nano clay
spellingShingle Evaluation of the hydration of Portland cement modified with polyvinyl alcohol and nano clay
Piqué, Teresa María
BENTONITE
CEMENT
CLAY
HYDRATION
POLYMER
POLYVINYLALCOHOL
title_short Evaluation of the hydration of Portland cement modified with polyvinyl alcohol and nano clay
title_full Evaluation of the hydration of Portland cement modified with polyvinyl alcohol and nano clay
title_fullStr Evaluation of the hydration of Portland cement modified with polyvinyl alcohol and nano clay
title_full_unstemmed Evaluation of the hydration of Portland cement modified with polyvinyl alcohol and nano clay
title_sort Evaluation of the hydration of Portland cement modified with polyvinyl alcohol and nano clay
dc.creator.none.fl_str_mv Piqué, Teresa María
Balzamo, Humberto Marcelo
Vázquez, Analía
author Piqué, Teresa María
author_facet Piqué, Teresa María
Balzamo, Humberto Marcelo
Vázquez, Analía
author_role author
author2 Balzamo, Humberto Marcelo
Vázquez, Analía
author2_role author
author
dc.subject.none.fl_str_mv BENTONITE
CEMENT
CLAY
HYDRATION
POLYMER
POLYVINYLALCOHOL
topic BENTONITE
CEMENT
CLAY
HYDRATION
POLYMER
POLYVINYLALCOHOL
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/2.1
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Polyvinylalcohol (PVA) is a polymer soluble in hot water, it has the property of film formation and it can improve the concrete performance. The effects of PVA modified with nano clay on the cement hydration reaction have been investigated by means of semiadiabatic calorimeter, FTIR spectroscopy and SEM. FTIR spectroscopy was employed to monitor chemical transformation of cement. The morphology of the different samples was compared by means of SEM micrographs. With the semiadiabatic calorimeter the hydration kinetic was measured to compare the heat rate of the admixtures materials. Fixing the water-cement ratio, w/c, in 0,45, the ratio of polymer to cement (p/c) was 2 wt% and the ratio of clay to polymer was 4 wt% (0.8wt.% related to cement). The polymer and modified polymer admixtures produced a retardation effect on the kinetic of cement hydration, but the clay acts as nucleating agent. The increase of the temperature with time was measured and a new model with four parameters was employed and the kinetic parameters were determined for each sample.
Fil: Piqué, Teresa María. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Oficina de Coordinacion Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingenieria "Hilario Fernandez Long". Grupo Vinculado al Intecin - Grupo Interdisciplinario en Materiales; Argentina
Fil: Balzamo, Humberto Marcelo. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Oficina de Coordinacion Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingenieria "Hilario Fernandez Long". Grupo Vinculado al Intecin - Grupo Interdisciplinario en Materiales; Argentina
Fil: Vázquez, Analía. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Oficina de Coordinacion Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingenieria "Hilario Fernandez Long". Grupo Vinculado al Intecin - Grupo Interdisciplinario en Materiales; Argentina
description Polyvinylalcohol (PVA) is a polymer soluble in hot water, it has the property of film formation and it can improve the concrete performance. The effects of PVA modified with nano clay on the cement hydration reaction have been investigated by means of semiadiabatic calorimeter, FTIR spectroscopy and SEM. FTIR spectroscopy was employed to monitor chemical transformation of cement. The morphology of the different samples was compared by means of SEM micrographs. With the semiadiabatic calorimeter the hydration kinetic was measured to compare the heat rate of the admixtures materials. Fixing the water-cement ratio, w/c, in 0,45, the ratio of polymer to cement (p/c) was 2 wt% and the ratio of clay to polymer was 4 wt% (0.8wt.% related to cement). The polymer and modified polymer admixtures produced a retardation effect on the kinetic of cement hydration, but the clay acts as nucleating agent. The increase of the temperature with time was measured and a new model with four parameters was employed and the kinetic parameters were determined for each sample.
publishDate 2011
dc.date.none.fl_str_mv 2011-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/217692
Piqué, Teresa María; Balzamo, Humberto Marcelo; Vázquez, Analía; Evaluation of the hydration of Portland cement modified with polyvinyl alcohol and nano clay; Trans TEch Publishers; Key Engineering Materials; 466; 1-2011; 47-56
1013-9826
CONICET Digital
CONICET
url http://hdl.handle.net/11336/217692
identifier_str_mv Piqué, Teresa María; Balzamo, Humberto Marcelo; Vázquez, Analía; Evaluation of the hydration of Portland cement modified with polyvinyl alcohol and nano clay; Trans TEch Publishers; Key Engineering Materials; 466; 1-2011; 47-56
1013-9826
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.scientific.net/KEM.466.47
info:eu-repo/semantics/altIdentifier/doi/10.4028/www.scientific.net/KEM.466.47
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Trans TEch Publishers
publisher.none.fl_str_mv Trans TEch Publishers
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844613500675031040
score 13.070432

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