Mechanosynthesis and magnetic properties of nanocrystalline LaFeO3 using different iron oxides

Autores
Cristobal, Adrian Alberto; Botta, Pablo Martín; Bercoff, Paula Gabriela; Porto Lopez, Jose Manuel
Año de publicación
2009
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The synthesis of the orthoferrite LaFeO3 using high-energy ball-milling of La2O3 and Fe3O4 or α-Fe2O3 oxides and subsequent thermal treatments of resulting powders was studied. The phase evolution during the mechanical treatment was analyzed by X-ray diffraction (XRD), differential thermal analysis (DTA) and scanning electron microscopy (SEM). Also, magnetic properties of the obtained materials were measured at room temperature by vibrating sample magnetometry (VSM). From 30 min of mechanochemical activation the gradual disappearance of reactants and the formation of LaFeO3 were observed. For both reactive mixtures the reaction was completed after 3 h of milling. Magnetic hysteresis loops of these mechanoactivated samples showed a significant ferromagnetic component in LaFeO3. This behavior was interpreted on the basis of a spin-canting effect induced by the mechanochemical treatment. Thermal treatments allowed the relaxation of the distorted structure, resulting in the formation of the conventional antiferromagnetic LaFeO3 phase. © 2008 Elsevier Ltd. All rights reserved.
Fil: Cristobal, Adrian Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Botta, Pablo Martín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Bercoff, Paula Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina
Fil: Porto Lopez, Jose Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Materia
A. Magnetic Materials
A. Oxides
D. Magnetic Properties
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/66064
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/66064
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Mechanosynthesis and magnetic properties of nanocrystalline LaFeO3 using different iron oxidesCristobal, Adrian AlbertoBotta, Pablo MartínBercoff, Paula GabrielaPorto Lopez, Jose ManuelA. Magnetic MaterialsA. OxidesD. Magnetic Propertieshttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1The synthesis of the orthoferrite LaFeO3 using high-energy ball-milling of La2O3 and Fe3O4 or α-Fe2O3 oxides and subsequent thermal treatments of resulting powders was studied. The phase evolution during the mechanical treatment was analyzed by X-ray diffraction (XRD), differential thermal analysis (DTA) and scanning electron microscopy (SEM). Also, magnetic properties of the obtained materials were measured at room temperature by vibrating sample magnetometry (VSM). From 30 min of mechanochemical activation the gradual disappearance of reactants and the formation of LaFeO3 were observed. For both reactive mixtures the reaction was completed after 3 h of milling. Magnetic hysteresis loops of these mechanoactivated samples showed a significant ferromagnetic component in LaFeO3. This behavior was interpreted on the basis of a spin-canting effect induced by the mechanochemical treatment. Thermal treatments allowed the relaxation of the distorted structure, resulting in the formation of the conventional antiferromagnetic LaFeO3 phase. © 2008 Elsevier Ltd. All rights reserved.Fil: Cristobal, Adrian Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Botta, Pablo Martín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Bercoff, Paula Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; ArgentinaFil: Porto Lopez, Jose Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaPergamon-Elsevier Science Ltd2009-05-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/66064Cristobal, Adrian Alberto; Botta, Pablo Martín; Bercoff, Paula Gabriela; Porto Lopez, Jose Manuel; Mechanosynthesis and magnetic properties of nanocrystalline LaFeO3 using different iron oxides; Pergamon-Elsevier Science Ltd; Materials Research Bulletin; 44; 5; 6-5-2009; 1036-10400025-5408CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.materresbull.2008.11.015info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0025540808003826info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:46:14Zoai:ri.conicet.gov.ar:11336/66064instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:46:15.262CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Mechanosynthesis and magnetic properties of nanocrystalline LaFeO3 using different iron oxides
title Mechanosynthesis and magnetic properties of nanocrystalline LaFeO3 using different iron oxides
spellingShingle Mechanosynthesis and magnetic properties of nanocrystalline LaFeO3 using different iron oxides
Cristobal, Adrian Alberto
A. Magnetic Materials
A. Oxides
D. Magnetic Properties
title_short Mechanosynthesis and magnetic properties of nanocrystalline LaFeO3 using different iron oxides
title_full Mechanosynthesis and magnetic properties of nanocrystalline LaFeO3 using different iron oxides
title_fullStr Mechanosynthesis and magnetic properties of nanocrystalline LaFeO3 using different iron oxides
title_full_unstemmed Mechanosynthesis and magnetic properties of nanocrystalline LaFeO3 using different iron oxides
title_sort Mechanosynthesis and magnetic properties of nanocrystalline LaFeO3 using different iron oxides
dc.creator.none.fl_str_mv Cristobal, Adrian Alberto
Botta, Pablo Martín
Bercoff, Paula Gabriela
Porto Lopez, Jose Manuel
author Cristobal, Adrian Alberto
author_facet Cristobal, Adrian Alberto
Botta, Pablo Martín
Bercoff, Paula Gabriela
Porto Lopez, Jose Manuel
author_role author
author2 Botta, Pablo Martín
Bercoff, Paula Gabriela
Porto Lopez, Jose Manuel
author2_role author
author
author
dc.subject.none.fl_str_mv A. Magnetic Materials
A. Oxides
D. Magnetic Properties
topic A. Magnetic Materials
A. Oxides
D. Magnetic Properties
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The synthesis of the orthoferrite LaFeO3 using high-energy ball-milling of La2O3 and Fe3O4 or α-Fe2O3 oxides and subsequent thermal treatments of resulting powders was studied. The phase evolution during the mechanical treatment was analyzed by X-ray diffraction (XRD), differential thermal analysis (DTA) and scanning electron microscopy (SEM). Also, magnetic properties of the obtained materials were measured at room temperature by vibrating sample magnetometry (VSM). From 30 min of mechanochemical activation the gradual disappearance of reactants and the formation of LaFeO3 were observed. For both reactive mixtures the reaction was completed after 3 h of milling. Magnetic hysteresis loops of these mechanoactivated samples showed a significant ferromagnetic component in LaFeO3. This behavior was interpreted on the basis of a spin-canting effect induced by the mechanochemical treatment. Thermal treatments allowed the relaxation of the distorted structure, resulting in the formation of the conventional antiferromagnetic LaFeO3 phase. © 2008 Elsevier Ltd. All rights reserved.
Fil: Cristobal, Adrian Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Botta, Pablo Martín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Bercoff, Paula Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina
Fil: Porto Lopez, Jose Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
description The synthesis of the orthoferrite LaFeO3 using high-energy ball-milling of La2O3 and Fe3O4 or α-Fe2O3 oxides and subsequent thermal treatments of resulting powders was studied. The phase evolution during the mechanical treatment was analyzed by X-ray diffraction (XRD), differential thermal analysis (DTA) and scanning electron microscopy (SEM). Also, magnetic properties of the obtained materials were measured at room temperature by vibrating sample magnetometry (VSM). From 30 min of mechanochemical activation the gradual disappearance of reactants and the formation of LaFeO3 were observed. For both reactive mixtures the reaction was completed after 3 h of milling. Magnetic hysteresis loops of these mechanoactivated samples showed a significant ferromagnetic component in LaFeO3. This behavior was interpreted on the basis of a spin-canting effect induced by the mechanochemical treatment. Thermal treatments allowed the relaxation of the distorted structure, resulting in the formation of the conventional antiferromagnetic LaFeO3 phase. © 2008 Elsevier Ltd. All rights reserved.
publishDate 2009
dc.date.none.fl_str_mv 2009-05-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/66064
Cristobal, Adrian Alberto; Botta, Pablo Martín; Bercoff, Paula Gabriela; Porto Lopez, Jose Manuel; Mechanosynthesis and magnetic properties of nanocrystalline LaFeO3 using different iron oxides; Pergamon-Elsevier Science Ltd; Materials Research Bulletin; 44; 5; 6-5-2009; 1036-1040
0025-5408
CONICET Digital
CONICET
url http://hdl.handle.net/11336/66064
identifier_str_mv Cristobal, Adrian Alberto; Botta, Pablo Martín; Bercoff, Paula Gabriela; Porto Lopez, Jose Manuel; Mechanosynthesis and magnetic properties of nanocrystalline LaFeO3 using different iron oxides; Pergamon-Elsevier Science Ltd; Materials Research Bulletin; 44; 5; 6-5-2009; 1036-1040
0025-5408
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.materresbull.2008.11.015
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0025540808003826
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.069144

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