Ultrafiltration of oil/water emulsions using PVDF/PC blend membranes

Autores
Masuelli, Martin Alberto
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Membranes with varying degrees of hydrophilicity made from blends of poly(vinylidene fluoride) (PVDF) and polycarbonate (PC) were prepared to recover water from emulsified oily wastewater. The effects of different amounts of PC content on the structure, hydrophilicity, and functionality of these PVDF/PC membranes were analyzed using contact angle measurements, scanning electron microscope and energy dispersion X-ray analysis, liquid–liquid displacement, and a fouling test with an oil/water emulsion. The slightly hydrophilic character of the PC decreases the hydrophobicity of the blend membranes compared to a pure PVDF membrane. Increasing the amount of PC in the casting solution causes little change in average pore size but a substantial change in the membrane’s porosity and surface structure, with these changes reflected in the efficiency of the membranes with respect to recovering water from the emulsified oily wastewater. The best performance, meaning less membrane fouling and better permeate quality, was obtained using a blend membrane containing 20% PC, which achieved an initial permeate flux of 28.59 L/m2 h with a limiting permeate flux of 22.11 L/m2 h, a COD of 88 ppm in the permeate solution, and 97.8% oil retention.
Fil: Masuelli, Martin Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Física Aplicada; Argentina
Materia
Poly(Vinylidene Fluoride)
Polycarbonate
Blend Membranes
Oily Wastewater Emulsion
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/5687
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Ultrafiltration of oil/water emulsions using PVDF/PC blend membranesMasuelli, Martin AlbertoPoly(Vinylidene Fluoride)PolycarbonateBlend MembranesOily Wastewater Emulsionhttps://purl.org/becyt/ford/1.5https://purl.org/becyt/ford/1Membranes with varying degrees of hydrophilicity made from blends of poly(vinylidene fluoride) (PVDF) and polycarbonate (PC) were prepared to recover water from emulsified oily wastewater. The effects of different amounts of PC content on the structure, hydrophilicity, and functionality of these PVDF/PC membranes were analyzed using contact angle measurements, scanning electron microscope and energy dispersion X-ray analysis, liquid–liquid displacement, and a fouling test with an oil/water emulsion. The slightly hydrophilic character of the PC decreases the hydrophobicity of the blend membranes compared to a pure PVDF membrane. Increasing the amount of PC in the casting solution causes little change in average pore size but a substantial change in the membrane’s porosity and surface structure, with these changes reflected in the efficiency of the membranes with respect to recovering water from the emulsified oily wastewater. The best performance, meaning less membrane fouling and better permeate quality, was obtained using a blend membrane containing 20% PC, which achieved an initial permeate flux of 28.59 L/m2 h with a limiting permeate flux of 22.11 L/m2 h, a COD of 88 ppm in the permeate solution, and 97.8% oil retention.Fil: Masuelli, Martin Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Física Aplicada; ArgentinaTaylor & Francis2015-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/5687Masuelli, Martin Alberto; Ultrafiltration of oil/water emulsions using PVDF/PC blend membranes; Taylor & Francis; Desalination and Water Treatment; 53; 3; 3-2015; 569-5781944-3994enginfo:eu-repo/semantics/altIdentifier/doi/10.1080/19443994.2013.846539info:eu-repo/semantics/altIdentifier/url/http://www.tandfonline.com/doi/abs/10.1080/19443994.2013.846539info:eu-repo/semantics/altIdentifier/doi/info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:33:45Zoai:ri.conicet.gov.ar:11336/5687instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:33:45.525CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Ultrafiltration of oil/water emulsions using PVDF/PC blend membranes
title Ultrafiltration of oil/water emulsions using PVDF/PC blend membranes
spellingShingle Ultrafiltration of oil/water emulsions using PVDF/PC blend membranes
Masuelli, Martin Alberto
Poly(Vinylidene Fluoride)
Polycarbonate
Blend Membranes
Oily Wastewater Emulsion
title_short Ultrafiltration of oil/water emulsions using PVDF/PC blend membranes
title_full Ultrafiltration of oil/water emulsions using PVDF/PC blend membranes
title_fullStr Ultrafiltration of oil/water emulsions using PVDF/PC blend membranes
title_full_unstemmed Ultrafiltration of oil/water emulsions using PVDF/PC blend membranes
title_sort Ultrafiltration of oil/water emulsions using PVDF/PC blend membranes
dc.creator.none.fl_str_mv Masuelli, Martin Alberto
author Masuelli, Martin Alberto
author_facet Masuelli, Martin Alberto
author_role author
dc.subject.none.fl_str_mv Poly(Vinylidene Fluoride)
Polycarbonate
Blend Membranes
Oily Wastewater Emulsion
topic Poly(Vinylidene Fluoride)
Polycarbonate
Blend Membranes
Oily Wastewater Emulsion
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.5
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Membranes with varying degrees of hydrophilicity made from blends of poly(vinylidene fluoride) (PVDF) and polycarbonate (PC) were prepared to recover water from emulsified oily wastewater. The effects of different amounts of PC content on the structure, hydrophilicity, and functionality of these PVDF/PC membranes were analyzed using contact angle measurements, scanning electron microscope and energy dispersion X-ray analysis, liquid–liquid displacement, and a fouling test with an oil/water emulsion. The slightly hydrophilic character of the PC decreases the hydrophobicity of the blend membranes compared to a pure PVDF membrane. Increasing the amount of PC in the casting solution causes little change in average pore size but a substantial change in the membrane’s porosity and surface structure, with these changes reflected in the efficiency of the membranes with respect to recovering water from the emulsified oily wastewater. The best performance, meaning less membrane fouling and better permeate quality, was obtained using a blend membrane containing 20% PC, which achieved an initial permeate flux of 28.59 L/m2 h with a limiting permeate flux of 22.11 L/m2 h, a COD of 88 ppm in the permeate solution, and 97.8% oil retention.
Fil: Masuelli, Martin Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Física Aplicada; Argentina
description Membranes with varying degrees of hydrophilicity made from blends of poly(vinylidene fluoride) (PVDF) and polycarbonate (PC) were prepared to recover water from emulsified oily wastewater. The effects of different amounts of PC content on the structure, hydrophilicity, and functionality of these PVDF/PC membranes were analyzed using contact angle measurements, scanning electron microscope and energy dispersion X-ray analysis, liquid–liquid displacement, and a fouling test with an oil/water emulsion. The slightly hydrophilic character of the PC decreases the hydrophobicity of the blend membranes compared to a pure PVDF membrane. Increasing the amount of PC in the casting solution causes little change in average pore size but a substantial change in the membrane’s porosity and surface structure, with these changes reflected in the efficiency of the membranes with respect to recovering water from the emulsified oily wastewater. The best performance, meaning less membrane fouling and better permeate quality, was obtained using a blend membrane containing 20% PC, which achieved an initial permeate flux of 28.59 L/m2 h with a limiting permeate flux of 22.11 L/m2 h, a COD of 88 ppm in the permeate solution, and 97.8% oil retention.
publishDate 2015
dc.date.none.fl_str_mv 2015-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/5687
Masuelli, Martin Alberto; Ultrafiltration of oil/water emulsions using PVDF/PC blend membranes; Taylor & Francis; Desalination and Water Treatment; 53; 3; 3-2015; 569-578
1944-3994
url http://hdl.handle.net/11336/5687
identifier_str_mv Masuelli, Martin Alberto; Ultrafiltration of oil/water emulsions using PVDF/PC blend membranes; Taylor & Francis; Desalination and Water Treatment; 53; 3; 3-2015; 569-578
1944-3994
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1080/19443994.2013.846539
info:eu-repo/semantics/altIdentifier/url/http://www.tandfonline.com/doi/abs/10.1080/19443994.2013.846539
info:eu-repo/semantics/altIdentifier/doi/
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Taylor & Francis
publisher.none.fl_str_mv Taylor & Francis
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.069144

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