Ultrafiltration of oil/water emulsions using PVDF/PC blend membranes
- Autores
- Masuelli, Martin Alberto
- Año de publicación
- 2015
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Membranes with varying degrees of hydrophilicity made from blends of poly(vinylidene fluoride) (PVDF) and polycarbonate (PC) were prepared to recover water from emulsified oily wastewater. The effects of different amounts of PC content on the structure, hydrophilicity, and functionality of these PVDF/PC membranes were analyzed using contact angle measurements, scanning electron microscope and energy dispersion X-ray analysis, liquid–liquid displacement, and a fouling test with an oil/water emulsion. The slightly hydrophilic character of the PC decreases the hydrophobicity of the blend membranes compared to a pure PVDF membrane. Increasing the amount of PC in the casting solution causes little change in average pore size but a substantial change in the membrane’s porosity and surface structure, with these changes reflected in the efficiency of the membranes with respect to recovering water from the emulsified oily wastewater. The best performance, meaning less membrane fouling and better permeate quality, was obtained using a blend membrane containing 20% PC, which achieved an initial permeate flux of 28.59 L/m2 h with a limiting permeate flux of 22.11 L/m2 h, a COD of 88 ppm in the permeate solution, and 97.8% oil retention.
Fil: Masuelli, Martin Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Física Aplicada; Argentina - Materia
-
Poly(Vinylidene Fluoride)
Polycarbonate
Blend Membranes
Oily Wastewater Emulsion - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/5687
Ver los metadatos del registro completo
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Ultrafiltration of oil/water emulsions using PVDF/PC blend membranesMasuelli, Martin AlbertoPoly(Vinylidene Fluoride)PolycarbonateBlend MembranesOily Wastewater Emulsionhttps://purl.org/becyt/ford/1.5https://purl.org/becyt/ford/1Membranes with varying degrees of hydrophilicity made from blends of poly(vinylidene fluoride) (PVDF) and polycarbonate (PC) were prepared to recover water from emulsified oily wastewater. The effects of different amounts of PC content on the structure, hydrophilicity, and functionality of these PVDF/PC membranes were analyzed using contact angle measurements, scanning electron microscope and energy dispersion X-ray analysis, liquid–liquid displacement, and a fouling test with an oil/water emulsion. The slightly hydrophilic character of the PC decreases the hydrophobicity of the blend membranes compared to a pure PVDF membrane. Increasing the amount of PC in the casting solution causes little change in average pore size but a substantial change in the membrane’s porosity and surface structure, with these changes reflected in the efficiency of the membranes with respect to recovering water from the emulsified oily wastewater. The best performance, meaning less membrane fouling and better permeate quality, was obtained using a blend membrane containing 20% PC, which achieved an initial permeate flux of 28.59 L/m2 h with a limiting permeate flux of 22.11 L/m2 h, a COD of 88 ppm in the permeate solution, and 97.8% oil retention.Fil: Masuelli, Martin Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Física Aplicada; ArgentinaTaylor & Francis2015-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/5687Masuelli, Martin Alberto; Ultrafiltration of oil/water emulsions using PVDF/PC blend membranes; Taylor & Francis; Desalination and Water Treatment; 53; 3; 3-2015; 569-5781944-3994enginfo:eu-repo/semantics/altIdentifier/doi/10.1080/19443994.2013.846539info:eu-repo/semantics/altIdentifier/url/http://www.tandfonline.com/doi/abs/10.1080/19443994.2013.846539info:eu-repo/semantics/altIdentifier/doi/info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:07:32Zoai:ri.conicet.gov.ar:11336/5687instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:07:33.072CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Ultrafiltration of oil/water emulsions using PVDF/PC blend membranes |
title |
Ultrafiltration of oil/water emulsions using PVDF/PC blend membranes |
spellingShingle |
Ultrafiltration of oil/water emulsions using PVDF/PC blend membranes Masuelli, Martin Alberto Poly(Vinylidene Fluoride) Polycarbonate Blend Membranes Oily Wastewater Emulsion |
title_short |
Ultrafiltration of oil/water emulsions using PVDF/PC blend membranes |
title_full |
Ultrafiltration of oil/water emulsions using PVDF/PC blend membranes |
title_fullStr |
Ultrafiltration of oil/water emulsions using PVDF/PC blend membranes |
title_full_unstemmed |
Ultrafiltration of oil/water emulsions using PVDF/PC blend membranes |
title_sort |
Ultrafiltration of oil/water emulsions using PVDF/PC blend membranes |
dc.creator.none.fl_str_mv |
Masuelli, Martin Alberto |
author |
Masuelli, Martin Alberto |
author_facet |
Masuelli, Martin Alberto |
author_role |
author |
dc.subject.none.fl_str_mv |
Poly(Vinylidene Fluoride) Polycarbonate Blend Membranes Oily Wastewater Emulsion |
topic |
Poly(Vinylidene Fluoride) Polycarbonate Blend Membranes Oily Wastewater Emulsion |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.5 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
Membranes with varying degrees of hydrophilicity made from blends of poly(vinylidene fluoride) (PVDF) and polycarbonate (PC) were prepared to recover water from emulsified oily wastewater. The effects of different amounts of PC content on the structure, hydrophilicity, and functionality of these PVDF/PC membranes were analyzed using contact angle measurements, scanning electron microscope and energy dispersion X-ray analysis, liquid–liquid displacement, and a fouling test with an oil/water emulsion. The slightly hydrophilic character of the PC decreases the hydrophobicity of the blend membranes compared to a pure PVDF membrane. Increasing the amount of PC in the casting solution causes little change in average pore size but a substantial change in the membrane’s porosity and surface structure, with these changes reflected in the efficiency of the membranes with respect to recovering water from the emulsified oily wastewater. The best performance, meaning less membrane fouling and better permeate quality, was obtained using a blend membrane containing 20% PC, which achieved an initial permeate flux of 28.59 L/m2 h with a limiting permeate flux of 22.11 L/m2 h, a COD of 88 ppm in the permeate solution, and 97.8% oil retention. Fil: Masuelli, Martin Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Física Aplicada; Argentina |
description |
Membranes with varying degrees of hydrophilicity made from blends of poly(vinylidene fluoride) (PVDF) and polycarbonate (PC) were prepared to recover water from emulsified oily wastewater. The effects of different amounts of PC content on the structure, hydrophilicity, and functionality of these PVDF/PC membranes were analyzed using contact angle measurements, scanning electron microscope and energy dispersion X-ray analysis, liquid–liquid displacement, and a fouling test with an oil/water emulsion. The slightly hydrophilic character of the PC decreases the hydrophobicity of the blend membranes compared to a pure PVDF membrane. Increasing the amount of PC in the casting solution causes little change in average pore size but a substantial change in the membrane’s porosity and surface structure, with these changes reflected in the efficiency of the membranes with respect to recovering water from the emulsified oily wastewater. The best performance, meaning less membrane fouling and better permeate quality, was obtained using a blend membrane containing 20% PC, which achieved an initial permeate flux of 28.59 L/m2 h with a limiting permeate flux of 22.11 L/m2 h, a COD of 88 ppm in the permeate solution, and 97.8% oil retention. |
publishDate |
2015 |
dc.date.none.fl_str_mv |
2015-03 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/5687 Masuelli, Martin Alberto; Ultrafiltration of oil/water emulsions using PVDF/PC blend membranes; Taylor & Francis; Desalination and Water Treatment; 53; 3; 3-2015; 569-578 1944-3994 |
url |
http://hdl.handle.net/11336/5687 |
identifier_str_mv |
Masuelli, Martin Alberto; Ultrafiltration of oil/water emulsions using PVDF/PC blend membranes; Taylor & Francis; Desalination and Water Treatment; 53; 3; 3-2015; 569-578 1944-3994 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1080/19443994.2013.846539 info:eu-repo/semantics/altIdentifier/url/http://www.tandfonline.com/doi/abs/10.1080/19443994.2013.846539 info:eu-repo/semantics/altIdentifier/doi/ |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Taylor & Francis |
publisher.none.fl_str_mv |
Taylor & Francis |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1842270006485712896 |
score |
13.13397 |