Mathematical modeling of the catalytic degradation of polystyrene in the presence of aluminum chloride

Autores
Gianoglio Pantano, Ioana Agustina; Diaz, Monica Fatima; Brandolin, Adriana; Sarmoria, Claudia
Año de publicación
2009
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
We model the effect of the catalyst AlCl3 on polystyrene (PS). Detailed experimental studies were previously carried out on the effect of AlCl3 on PS, as part of an effort to understand how to minimize the degradation of PS during the Friedel–Crafts alkylation performed to obtain a graft copolymer from immiscible blends of PS and a polyolefin (PO). In the present work three mathematical models for the catalytic degradation of PS are proposed, all of which consider that reaction starts with the elimination of a phenyl group from the PS chain, followed by either chain scission or a change in the chain structure. The models vary in the way they consider the strength of the main chain bonds, or the reactivity of modified PS chains. Kinetic parameters for each model are estimated. Although the three proposed models could be used to represent our own experimental data, one is more accurate. Experimental data from other authors are used to evaluate its capabilities. Based on the predictions of the better model, we discuss conditions to minimize PS scission, such as operating at low temperatures and AlCl3 concentrations, and using short processing times.
Fil: Gianoglio Pantano, Ioana Agustina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Diaz, Monica Fatima. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Brandolin, Adriana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Sarmoria, Claudia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Materia
Mathematical Modeling
Polystyrene Degradation
Lewis Acid
Molecular Weight
Kinetics
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/42341
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/42341
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Mathematical modeling of the catalytic degradation of polystyrene in the presence of aluminum chlorideGianoglio Pantano, Ioana AgustinaDiaz, Monica FatimaBrandolin, AdrianaSarmoria, ClaudiaMathematical ModelingPolystyrene DegradationLewis AcidMolecular WeightKineticshttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2We model the effect of the catalyst AlCl3 on polystyrene (PS). Detailed experimental studies were previously carried out on the effect of AlCl3 on PS, as part of an effort to understand how to minimize the degradation of PS during the Friedel–Crafts alkylation performed to obtain a graft copolymer from immiscible blends of PS and a polyolefin (PO). In the present work three mathematical models for the catalytic degradation of PS are proposed, all of which consider that reaction starts with the elimination of a phenyl group from the PS chain, followed by either chain scission or a change in the chain structure. The models vary in the way they consider the strength of the main chain bonds, or the reactivity of modified PS chains. Kinetic parameters for each model are estimated. Although the three proposed models could be used to represent our own experimental data, one is more accurate. Experimental data from other authors are used to evaluate its capabilities. Based on the predictions of the better model, we discuss conditions to minimize PS scission, such as operating at low temperatures and AlCl3 concentrations, and using short processing times.Fil: Gianoglio Pantano, Ioana Agustina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Diaz, Monica Fatima. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Brandolin, Adriana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Sarmoria, Claudia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaElsevier2009-04-28info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/42341Gianoglio Pantano, Ioana Agustina; Diaz, Monica Fatima; Brandolin, Adriana; Sarmoria, Claudia; Mathematical modeling of the catalytic degradation of polystyrene in the presence of aluminum chloride; Elsevier; Polymer Degradation And Stability; 94; 4; 28-4-2009; 566-5740141-3910CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.polymdegradstab.2009.01.015info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0141391009000196info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:02:39Zoai:ri.conicet.gov.ar:11336/42341instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:02:39.388CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Mathematical modeling of the catalytic degradation of polystyrene in the presence of aluminum chloride
title Mathematical modeling of the catalytic degradation of polystyrene in the presence of aluminum chloride
spellingShingle Mathematical modeling of the catalytic degradation of polystyrene in the presence of aluminum chloride
Gianoglio Pantano, Ioana Agustina
Mathematical Modeling
Polystyrene Degradation
Lewis Acid
Molecular Weight
Kinetics
title_short Mathematical modeling of the catalytic degradation of polystyrene in the presence of aluminum chloride
title_full Mathematical modeling of the catalytic degradation of polystyrene in the presence of aluminum chloride
title_fullStr Mathematical modeling of the catalytic degradation of polystyrene in the presence of aluminum chloride
title_full_unstemmed Mathematical modeling of the catalytic degradation of polystyrene in the presence of aluminum chloride
title_sort Mathematical modeling of the catalytic degradation of polystyrene in the presence of aluminum chloride
dc.creator.none.fl_str_mv Gianoglio Pantano, Ioana Agustina
Diaz, Monica Fatima
Brandolin, Adriana
Sarmoria, Claudia
author Gianoglio Pantano, Ioana Agustina
author_facet Gianoglio Pantano, Ioana Agustina
Diaz, Monica Fatima
Brandolin, Adriana
Sarmoria, Claudia
author_role author
author2 Diaz, Monica Fatima
Brandolin, Adriana
Sarmoria, Claudia
author2_role author
author
author
dc.subject.none.fl_str_mv Mathematical Modeling
Polystyrene Degradation
Lewis Acid
Molecular Weight
Kinetics
topic Mathematical Modeling
Polystyrene Degradation
Lewis Acid
Molecular Weight
Kinetics
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv We model the effect of the catalyst AlCl3 on polystyrene (PS). Detailed experimental studies were previously carried out on the effect of AlCl3 on PS, as part of an effort to understand how to minimize the degradation of PS during the Friedel–Crafts alkylation performed to obtain a graft copolymer from immiscible blends of PS and a polyolefin (PO). In the present work three mathematical models for the catalytic degradation of PS are proposed, all of which consider that reaction starts with the elimination of a phenyl group from the PS chain, followed by either chain scission or a change in the chain structure. The models vary in the way they consider the strength of the main chain bonds, or the reactivity of modified PS chains. Kinetic parameters for each model are estimated. Although the three proposed models could be used to represent our own experimental data, one is more accurate. Experimental data from other authors are used to evaluate its capabilities. Based on the predictions of the better model, we discuss conditions to minimize PS scission, such as operating at low temperatures and AlCl3 concentrations, and using short processing times.
Fil: Gianoglio Pantano, Ioana Agustina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Diaz, Monica Fatima. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Brandolin, Adriana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Sarmoria, Claudia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
description We model the effect of the catalyst AlCl3 on polystyrene (PS). Detailed experimental studies were previously carried out on the effect of AlCl3 on PS, as part of an effort to understand how to minimize the degradation of PS during the Friedel–Crafts alkylation performed to obtain a graft copolymer from immiscible blends of PS and a polyolefin (PO). In the present work three mathematical models for the catalytic degradation of PS are proposed, all of which consider that reaction starts with the elimination of a phenyl group from the PS chain, followed by either chain scission or a change in the chain structure. The models vary in the way they consider the strength of the main chain bonds, or the reactivity of modified PS chains. Kinetic parameters for each model are estimated. Although the three proposed models could be used to represent our own experimental data, one is more accurate. Experimental data from other authors are used to evaluate its capabilities. Based on the predictions of the better model, we discuss conditions to minimize PS scission, such as operating at low temperatures and AlCl3 concentrations, and using short processing times.
publishDate 2009
dc.date.none.fl_str_mv 2009-04-28
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/42341
Gianoglio Pantano, Ioana Agustina; Diaz, Monica Fatima; Brandolin, Adriana; Sarmoria, Claudia; Mathematical modeling of the catalytic degradation of polystyrene in the presence of aluminum chloride; Elsevier; Polymer Degradation And Stability; 94; 4; 28-4-2009; 566-574
0141-3910
CONICET Digital
CONICET
url http://hdl.handle.net/11336/42341
identifier_str_mv Gianoglio Pantano, Ioana Agustina; Diaz, Monica Fatima; Brandolin, Adriana; Sarmoria, Claudia; Mathematical modeling of the catalytic degradation of polystyrene in the presence of aluminum chloride; Elsevier; Polymer Degradation And Stability; 94; 4; 28-4-2009; 566-574
0141-3910
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.polymdegradstab.2009.01.015
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0141391009000196
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844613833483616256
score 13.070432

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