Study of the photodissociation process of ClC(O)SCH3 using both synchrotron radiation and hei photoelectron spectroscopy in the valence region

Autores
Geronés, Mariana; Erben, Mauricio Federico; Ge, Maofa; Cavasso Filho, Reinaldo L.; Romano, Rosana Mariel; Della Vedova, Carlos Omar
Año de publicación
2010
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The simultaneous evaluation of the PES and valence synchrotron photoionization studies complemented by the results of quantum chemical calculations offers unusually detailed insights into the valence ionization processes of small covalent molecules. Thus, methyl thiochloroformate, ClC(O)SCH3, has been investigated by using results from both photoelectron spectroscopy (PES) and synchrotron radiation in the valence energy range. In an additional series of experiments, total ion yield (TIY) and photoelectron-photoion coincidence (PEPICO) spectra have been recorded. Furthermore, the relative yields for ionic fragments have been determined as a function of the photon energy. Vibronic structure has been observed in the TIY spectrum recorded in the synchrotron experiments. The photodissociation behavior of ClC(O)SCH3 can be divided into two well-defined energy regions. © 2010 American Chemical Society.
Fil: Geronés, Mariana. Universidad Nacional de La Plata; Argentina
Fil: Erben, Mauricio Federico. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Ge, Maofa. Chinese Academy of Sciences; República de China
Fil: Cavasso Filho, Reinaldo L.. Universidad Federal do Abc; Brasil
Fil: Romano, Rosana Mariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Della Vedova, Carlos Omar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Materia
HeI Photoelectron Spectroscopy
Synchrotron
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/152156
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/152156
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Study of the photodissociation process of ClC(O)SCH3 using both synchrotron radiation and hei photoelectron spectroscopy in the valence regionGeronés, MarianaErben, Mauricio FedericoGe, MaofaCavasso Filho, Reinaldo L.Romano, Rosana MarielDella Vedova, Carlos OmarHeI Photoelectron SpectroscopySynchrotronhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The simultaneous evaluation of the PES and valence synchrotron photoionization studies complemented by the results of quantum chemical calculations offers unusually detailed insights into the valence ionization processes of small covalent molecules. Thus, methyl thiochloroformate, ClC(O)SCH3, has been investigated by using results from both photoelectron spectroscopy (PES) and synchrotron radiation in the valence energy range. In an additional series of experiments, total ion yield (TIY) and photoelectron-photoion coincidence (PEPICO) spectra have been recorded. Furthermore, the relative yields for ionic fragments have been determined as a function of the photon energy. Vibronic structure has been observed in the TIY spectrum recorded in the synchrotron experiments. The photodissociation behavior of ClC(O)SCH3 can be divided into two well-defined energy regions. © 2010 American Chemical Society.Fil: Geronés, Mariana. Universidad Nacional de La Plata; ArgentinaFil: Erben, Mauricio Federico. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaFil: Ge, Maofa. Chinese Academy of Sciences; República de ChinaFil: Cavasso Filho, Reinaldo L.. Universidad Federal do Abc; BrasilFil: Romano, Rosana Mariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaFil: Della Vedova, Carlos Omar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaAmerican Chemical Society2010-07-21info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/152156Geronés, Mariana; Erben, Mauricio Federico; Ge, Maofa; Cavasso Filho, Reinaldo L.; Romano, Rosana Mariel; et al.; Study of the photodissociation process of ClC(O)SCH3 using both synchrotron radiation and hei photoelectron spectroscopy in the valence region; American Chemical Society; Journal of Physical Chemistry A; 114; 31; 21-7-2010; 8049-80551089-5639CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1021/jp102179winfo:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/jp102179winfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:04:14Zoai:ri.conicet.gov.ar:11336/152156instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:04:14.905CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Study of the photodissociation process of ClC(O)SCH3 using both synchrotron radiation and hei photoelectron spectroscopy in the valence region
title Study of the photodissociation process of ClC(O)SCH3 using both synchrotron radiation and hei photoelectron spectroscopy in the valence region
spellingShingle Study of the photodissociation process of ClC(O)SCH3 using both synchrotron radiation and hei photoelectron spectroscopy in the valence region
Geronés, Mariana
HeI Photoelectron Spectroscopy
Synchrotron
title_short Study of the photodissociation process of ClC(O)SCH3 using both synchrotron radiation and hei photoelectron spectroscopy in the valence region
title_full Study of the photodissociation process of ClC(O)SCH3 using both synchrotron radiation and hei photoelectron spectroscopy in the valence region
title_fullStr Study of the photodissociation process of ClC(O)SCH3 using both synchrotron radiation and hei photoelectron spectroscopy in the valence region
title_full_unstemmed Study of the photodissociation process of ClC(O)SCH3 using both synchrotron radiation and hei photoelectron spectroscopy in the valence region
title_sort Study of the photodissociation process of ClC(O)SCH3 using both synchrotron radiation and hei photoelectron spectroscopy in the valence region
dc.creator.none.fl_str_mv Geronés, Mariana
Erben, Mauricio Federico
Ge, Maofa
Cavasso Filho, Reinaldo L.
Romano, Rosana Mariel
Della Vedova, Carlos Omar
author Geronés, Mariana
author_facet Geronés, Mariana
Erben, Mauricio Federico
Ge, Maofa
Cavasso Filho, Reinaldo L.
Romano, Rosana Mariel
Della Vedova, Carlos Omar
author_role author
author2 Erben, Mauricio Federico
Ge, Maofa
Cavasso Filho, Reinaldo L.
Romano, Rosana Mariel
Della Vedova, Carlos Omar
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv HeI Photoelectron Spectroscopy
Synchrotron
topic HeI Photoelectron Spectroscopy
Synchrotron
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The simultaneous evaluation of the PES and valence synchrotron photoionization studies complemented by the results of quantum chemical calculations offers unusually detailed insights into the valence ionization processes of small covalent molecules. Thus, methyl thiochloroformate, ClC(O)SCH3, has been investigated by using results from both photoelectron spectroscopy (PES) and synchrotron radiation in the valence energy range. In an additional series of experiments, total ion yield (TIY) and photoelectron-photoion coincidence (PEPICO) spectra have been recorded. Furthermore, the relative yields for ionic fragments have been determined as a function of the photon energy. Vibronic structure has been observed in the TIY spectrum recorded in the synchrotron experiments. The photodissociation behavior of ClC(O)SCH3 can be divided into two well-defined energy regions. © 2010 American Chemical Society.
Fil: Geronés, Mariana. Universidad Nacional de La Plata; Argentina
Fil: Erben, Mauricio Federico. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Ge, Maofa. Chinese Academy of Sciences; República de China
Fil: Cavasso Filho, Reinaldo L.. Universidad Federal do Abc; Brasil
Fil: Romano, Rosana Mariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Della Vedova, Carlos Omar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
description The simultaneous evaluation of the PES and valence synchrotron photoionization studies complemented by the results of quantum chemical calculations offers unusually detailed insights into the valence ionization processes of small covalent molecules. Thus, methyl thiochloroformate, ClC(O)SCH3, has been investigated by using results from both photoelectron spectroscopy (PES) and synchrotron radiation in the valence energy range. In an additional series of experiments, total ion yield (TIY) and photoelectron-photoion coincidence (PEPICO) spectra have been recorded. Furthermore, the relative yields for ionic fragments have been determined as a function of the photon energy. Vibronic structure has been observed in the TIY spectrum recorded in the synchrotron experiments. The photodissociation behavior of ClC(O)SCH3 can be divided into two well-defined energy regions. © 2010 American Chemical Society.
publishDate 2010
dc.date.none.fl_str_mv 2010-07-21
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/152156
Geronés, Mariana; Erben, Mauricio Federico; Ge, Maofa; Cavasso Filho, Reinaldo L.; Romano, Rosana Mariel; et al.; Study of the photodissociation process of ClC(O)SCH3 using both synchrotron radiation and hei photoelectron spectroscopy in the valence region; American Chemical Society; Journal of Physical Chemistry A; 114; 31; 21-7-2010; 8049-8055
1089-5639
CONICET Digital
CONICET
url http://hdl.handle.net/11336/152156
identifier_str_mv Geronés, Mariana; Erben, Mauricio Federico; Ge, Maofa; Cavasso Filho, Reinaldo L.; Romano, Rosana Mariel; et al.; Study of the photodissociation process of ClC(O)SCH3 using both synchrotron radiation and hei photoelectron spectroscopy in the valence region; American Chemical Society; Journal of Physical Chemistry A; 114; 31; 21-7-2010; 8049-8055
1089-5639
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1021/jp102179w
info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/jp102179w
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1842269845829189632
score 13.13397

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