Conformal functionalization of cotton fibers via isoreticular expansion of UiO-66 metal-organic frameworks

Autores
Schelling, Marion; Otal, Eugenio Hernan; Kim, Manuela Leticia; Hinestroza, Juan P.
Año de publicación
2020
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
We report on the growing of metal-organic frameworks that are isoreticular and isostructural to UiO-66, onto cotton fabrics via a solvothermal method. Four different metal-organic frameworks (MOFs) (UiO-66, UiO-66-NH2, UiO-66-NDC, and UiO-67) were chosen as a case study. The presence of the UiO-based MOFs was confirmed through X-ray diffraction and Scanning Electron Microscopy. We used thermogravimetric analysis to quantify the amount of the MOF loading, which ranged from 0.8% to 2.6% m/m. We also explored the role of ligand size, growth time, and reaction temperature on the conformal coating of cotton fibers with these Zr-based MOFs. Cotton fabrics coated with Zr-based MOFs can find applications as selective filters in aggressive environments due to their enhanced chemical and thermal stabilities.
Fil: Schelling, Marion. Cornell University; Estados Unidos
Fil: Otal, Eugenio Hernan. Consejo Nacional de Investigaciones Científicas y Técnicas. Unidad de Investigación y Desarrollo Estratégico para la Defensa. Ministerio de Defensa. Unidad de Investigación y Desarrollo Estratégico para la Defensa; Argentina. Shinshu University. Faculty of Textile Science and Technology. Department of Chemistry and Materials; Japón
Fil: Kim, Manuela Leticia. Consejo Nacional de Investigaciones Científicas y Técnicas. Unidad de Investigación y Desarrollo Estratégico para la Defensa. Ministerio de Defensa. Unidad de Investigación y Desarrollo Estratégico para la Defensa; Argentina. Shinshu University. Faculty of Textile Science and Technology. Department of Chemistry and Materials; Japón
Fil: Hinestroza, Juan P.. Cornell University; Estados Unidos
Materia
COTTON
METAL-ORGANIC FRAMEWORK
UIO-66
UIO-67
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/169188
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Conformal functionalization of cotton fibers via isoreticular expansion of UiO-66 metal-organic frameworksSchelling, MarionOtal, Eugenio HernanKim, Manuela LeticiaHinestroza, Juan P.COTTONMETAL-ORGANIC FRAMEWORKUIO-66UIO-67https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1We report on the growing of metal-organic frameworks that are isoreticular and isostructural to UiO-66, onto cotton fabrics via a solvothermal method. Four different metal-organic frameworks (MOFs) (UiO-66, UiO-66-NH2, UiO-66-NDC, and UiO-67) were chosen as a case study. The presence of the UiO-based MOFs was confirmed through X-ray diffraction and Scanning Electron Microscopy. We used thermogravimetric analysis to quantify the amount of the MOF loading, which ranged from 0.8% to 2.6% m/m. We also explored the role of ligand size, growth time, and reaction temperature on the conformal coating of cotton fibers with these Zr-based MOFs. Cotton fabrics coated with Zr-based MOFs can find applications as selective filters in aggressive environments due to their enhanced chemical and thermal stabilities.Fil: Schelling, Marion. Cornell University; Estados UnidosFil: Otal, Eugenio Hernan. Consejo Nacional de Investigaciones Científicas y Técnicas. Unidad de Investigación y Desarrollo Estratégico para la Defensa. Ministerio de Defensa. Unidad de Investigación y Desarrollo Estratégico para la Defensa; Argentina. Shinshu University. Faculty of Textile Science and Technology. Department of Chemistry and Materials; JapónFil: Kim, Manuela Leticia. Consejo Nacional de Investigaciones Científicas y Técnicas. Unidad de Investigación y Desarrollo Estratégico para la Defensa. Ministerio de Defensa. Unidad de Investigación y Desarrollo Estratégico para la Defensa; Argentina. Shinshu University. Faculty of Textile Science and Technology. Department of Chemistry and Materials; JapónFil: Hinestroza, Juan P.. Cornell University; Estados UnidosMultidisciplinary Digital Publishing Institute2020-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/169188Schelling, Marion; Otal, Eugenio Hernan; Kim, Manuela Leticia; Hinestroza, Juan P.; Conformal functionalization of cotton fibers via isoreticular expansion of UiO-66 metal-organic frameworks; Multidisciplinary Digital Publishing Institute; Coatings; 10; 12; 11-2020; 1-102079-6412CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2079-6412/10/12/1172info:eu-repo/semantics/altIdentifier/doi/10.3390/coatings10121172info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:44:25Zoai:ri.conicet.gov.ar:11336/169188instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:44:25.715CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Conformal functionalization of cotton fibers via isoreticular expansion of UiO-66 metal-organic frameworks
title Conformal functionalization of cotton fibers via isoreticular expansion of UiO-66 metal-organic frameworks
spellingShingle Conformal functionalization of cotton fibers via isoreticular expansion of UiO-66 metal-organic frameworks
Schelling, Marion
COTTON
METAL-ORGANIC FRAMEWORK
UIO-66
UIO-67
title_short Conformal functionalization of cotton fibers via isoreticular expansion of UiO-66 metal-organic frameworks
title_full Conformal functionalization of cotton fibers via isoreticular expansion of UiO-66 metal-organic frameworks
title_fullStr Conformal functionalization of cotton fibers via isoreticular expansion of UiO-66 metal-organic frameworks
title_full_unstemmed Conformal functionalization of cotton fibers via isoreticular expansion of UiO-66 metal-organic frameworks
title_sort Conformal functionalization of cotton fibers via isoreticular expansion of UiO-66 metal-organic frameworks
dc.creator.none.fl_str_mv Schelling, Marion
Otal, Eugenio Hernan
Kim, Manuela Leticia
Hinestroza, Juan P.
author Schelling, Marion
author_facet Schelling, Marion
Otal, Eugenio Hernan
Kim, Manuela Leticia
Hinestroza, Juan P.
author_role author
author2 Otal, Eugenio Hernan
Kim, Manuela Leticia
Hinestroza, Juan P.
author2_role author
author
author
dc.subject.none.fl_str_mv COTTON
METAL-ORGANIC FRAMEWORK
UIO-66
UIO-67
topic COTTON
METAL-ORGANIC FRAMEWORK
UIO-66
UIO-67
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv We report on the growing of metal-organic frameworks that are isoreticular and isostructural to UiO-66, onto cotton fabrics via a solvothermal method. Four different metal-organic frameworks (MOFs) (UiO-66, UiO-66-NH2, UiO-66-NDC, and UiO-67) were chosen as a case study. The presence of the UiO-based MOFs was confirmed through X-ray diffraction and Scanning Electron Microscopy. We used thermogravimetric analysis to quantify the amount of the MOF loading, which ranged from 0.8% to 2.6% m/m. We also explored the role of ligand size, growth time, and reaction temperature on the conformal coating of cotton fibers with these Zr-based MOFs. Cotton fabrics coated with Zr-based MOFs can find applications as selective filters in aggressive environments due to their enhanced chemical and thermal stabilities.
Fil: Schelling, Marion. Cornell University; Estados Unidos
Fil: Otal, Eugenio Hernan. Consejo Nacional de Investigaciones Científicas y Técnicas. Unidad de Investigación y Desarrollo Estratégico para la Defensa. Ministerio de Defensa. Unidad de Investigación y Desarrollo Estratégico para la Defensa; Argentina. Shinshu University. Faculty of Textile Science and Technology. Department of Chemistry and Materials; Japón
Fil: Kim, Manuela Leticia. Consejo Nacional de Investigaciones Científicas y Técnicas. Unidad de Investigación y Desarrollo Estratégico para la Defensa. Ministerio de Defensa. Unidad de Investigación y Desarrollo Estratégico para la Defensa; Argentina. Shinshu University. Faculty of Textile Science and Technology. Department of Chemistry and Materials; Japón
Fil: Hinestroza, Juan P.. Cornell University; Estados Unidos
description We report on the growing of metal-organic frameworks that are isoreticular and isostructural to UiO-66, onto cotton fabrics via a solvothermal method. Four different metal-organic frameworks (MOFs) (UiO-66, UiO-66-NH2, UiO-66-NDC, and UiO-67) were chosen as a case study. The presence of the UiO-based MOFs was confirmed through X-ray diffraction and Scanning Electron Microscopy. We used thermogravimetric analysis to quantify the amount of the MOF loading, which ranged from 0.8% to 2.6% m/m. We also explored the role of ligand size, growth time, and reaction temperature on the conformal coating of cotton fibers with these Zr-based MOFs. Cotton fabrics coated with Zr-based MOFs can find applications as selective filters in aggressive environments due to their enhanced chemical and thermal stabilities.
publishDate 2020
dc.date.none.fl_str_mv 2020-11
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/169188
Schelling, Marion; Otal, Eugenio Hernan; Kim, Manuela Leticia; Hinestroza, Juan P.; Conformal functionalization of cotton fibers via isoreticular expansion of UiO-66 metal-organic frameworks; Multidisciplinary Digital Publishing Institute; Coatings; 10; 12; 11-2020; 1-10
2079-6412
CONICET Digital
CONICET
url http://hdl.handle.net/11336/169188
identifier_str_mv Schelling, Marion; Otal, Eugenio Hernan; Kim, Manuela Leticia; Hinestroza, Juan P.; Conformal functionalization of cotton fibers via isoreticular expansion of UiO-66 metal-organic frameworks; Multidisciplinary Digital Publishing Institute; Coatings; 10; 12; 11-2020; 1-10
2079-6412
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2079-6412/10/12/1172
info:eu-repo/semantics/altIdentifier/doi/10.3390/coatings10121172
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute
publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1842268665130516480
score 13.13397

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