Decoration of cotton fibers with a water-stable metal–organic framework (UiO-66) for the decomposition and enhanced adsorption of micropollutants in water

Autores
Schelling, Marion; Kim, Manuela Leticia; Otal, Eugenio Hernan; Hinestroza, Juan
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
We report on the successful functionalization of cotton fabrics with a water-stable metal–organic framework (MOF), UiO-66, under mild solvothermal conditions (80◦ C) and its ability to adsorb and degrade water micropollutants. The functionalized cotton samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FTIR), and X-ray photoelectron spectroscopy (XPS). UiO-66 crystals grew in a uniform and conformal manner over the surface of the cotton fibers. The cotton fabrics functionalized with UiO-66 frameworks exhibited an enhanced uptake capacity for methylchlorophenoxypropionic acid (MCPP), a commonly used herbicide. The functionalized fabrics also showed photocatalytic activity, demonstrated by the degradation of acetaminophen, a common pharmaceutical compound, under simulated sunlight irradiation. These results indicate that UiO-66 can be supported on textile substrates for filtration and photocatalytic purposes and that these substrates can find applications in wastewater decontamination and micropollutant degradation.
Fil: Schelling, Marion. Cornell University; Estados Unidos
Fil: Kim, Manuela Leticia. Consejo Nacional de Investigaciones Científicas y Técnicas. Unidad de Investigación y Desarrollo Estratégico para la Defensa. Ministerio de Defensa. Unidad de Investigación y Desarrollo Estratégico para la Defensa; Argentina. Universidad Tecnológica Nacional. Facultad Reg.rio Grande. Secretaria de Ciencia y Tecnología; Argentina
Fil: Otal, Eugenio Hernan. Consejo Nacional de Investigaciones Científicas y Técnicas. Unidad de Investigación y Desarrollo Estratégico para la Defensa. Ministerio de Defensa. Unidad de Investigación y Desarrollo Estratégico para la Defensa; Argentina. Universidad Tecnológica Nacional. Facultad Reg.rio Grande. Secretaria de Ciencia y Tecnología; Argentina
Fil: Hinestroza, Juan. Cornell University; Estados Unidos
Materia
COTTON FABRIC
FUNCTIONALIZED CELLULOSE
METHYLCHLOROPHENOXYPROPIONIC ACID
MOF
PARACETAMOL
UIO-66
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/82152

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network_name_str CONICET Digital (CONICET)
spelling Decoration of cotton fibers with a water-stable metal–organic framework (UiO-66) for the decomposition and enhanced adsorption of micropollutants in waterSchelling, MarionKim, Manuela LeticiaOtal, Eugenio HernanHinestroza, JuanCOTTON FABRICFUNCTIONALIZED CELLULOSEMETHYLCHLOROPHENOXYPROPIONIC ACIDMOFPARACETAMOLUIO-66https://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2We report on the successful functionalization of cotton fabrics with a water-stable metal–organic framework (MOF), UiO-66, under mild solvothermal conditions (80◦ C) and its ability to adsorb and degrade water micropollutants. The functionalized cotton samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FTIR), and X-ray photoelectron spectroscopy (XPS). UiO-66 crystals grew in a uniform and conformal manner over the surface of the cotton fibers. The cotton fabrics functionalized with UiO-66 frameworks exhibited an enhanced uptake capacity for methylchlorophenoxypropionic acid (MCPP), a commonly used herbicide. The functionalized fabrics also showed photocatalytic activity, demonstrated by the degradation of acetaminophen, a common pharmaceutical compound, under simulated sunlight irradiation. These results indicate that UiO-66 can be supported on textile substrates for filtration and photocatalytic purposes and that these substrates can find applications in wastewater decontamination and micropollutant degradation.Fil: Schelling, Marion. Cornell University; Estados UnidosFil: Kim, Manuela Leticia. Consejo Nacional de Investigaciones Científicas y Técnicas. Unidad de Investigación y Desarrollo Estratégico para la Defensa. Ministerio de Defensa. Unidad de Investigación y Desarrollo Estratégico para la Defensa; Argentina. Universidad Tecnológica Nacional. Facultad Reg.rio Grande. Secretaria de Ciencia y Tecnología; ArgentinaFil: Otal, Eugenio Hernan. Consejo Nacional de Investigaciones Científicas y Técnicas. Unidad de Investigación y Desarrollo Estratégico para la Defensa. Ministerio de Defensa. Unidad de Investigación y Desarrollo Estratégico para la Defensa; Argentina. Universidad Tecnológica Nacional. Facultad Reg.rio Grande. Secretaria de Ciencia y Tecnología; ArgentinaFil: Hinestroza, Juan. Cornell University; Estados UnidosMDPI AG2018-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/82152Schelling, Marion; Kim, Manuela Leticia; Otal, Eugenio Hernan; Hinestroza, Juan; Decoration of cotton fibers with a water-stable metal–organic framework (UiO-66) for the decomposition and enhanced adsorption of micropollutants in water; MDPI AG; Bioengineering; 5; 1; 3-2018; 14-252306-5354CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2306-5354/5/1/14info:eu-repo/semantics/altIdentifier/doi/10.3390/bioengineering5010014info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:29:15Zoai:ri.conicet.gov.ar:11336/82152instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:29:15.467CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Decoration of cotton fibers with a water-stable metal–organic framework (UiO-66) for the decomposition and enhanced adsorption of micropollutants in water
title Decoration of cotton fibers with a water-stable metal–organic framework (UiO-66) for the decomposition and enhanced adsorption of micropollutants in water
spellingShingle Decoration of cotton fibers with a water-stable metal–organic framework (UiO-66) for the decomposition and enhanced adsorption of micropollutants in water
Schelling, Marion
COTTON FABRIC
FUNCTIONALIZED CELLULOSE
METHYLCHLOROPHENOXYPROPIONIC ACID
MOF
PARACETAMOL
UIO-66
title_short Decoration of cotton fibers with a water-stable metal–organic framework (UiO-66) for the decomposition and enhanced adsorption of micropollutants in water
title_full Decoration of cotton fibers with a water-stable metal–organic framework (UiO-66) for the decomposition and enhanced adsorption of micropollutants in water
title_fullStr Decoration of cotton fibers with a water-stable metal–organic framework (UiO-66) for the decomposition and enhanced adsorption of micropollutants in water
title_full_unstemmed Decoration of cotton fibers with a water-stable metal–organic framework (UiO-66) for the decomposition and enhanced adsorption of micropollutants in water
title_sort Decoration of cotton fibers with a water-stable metal–organic framework (UiO-66) for the decomposition and enhanced adsorption of micropollutants in water
dc.creator.none.fl_str_mv Schelling, Marion
Kim, Manuela Leticia
Otal, Eugenio Hernan
Hinestroza, Juan
author Schelling, Marion
author_facet Schelling, Marion
Kim, Manuela Leticia
Otal, Eugenio Hernan
Hinestroza, Juan
author_role author
author2 Kim, Manuela Leticia
Otal, Eugenio Hernan
Hinestroza, Juan
author2_role author
author
author
dc.subject.none.fl_str_mv COTTON FABRIC
FUNCTIONALIZED CELLULOSE
METHYLCHLOROPHENOXYPROPIONIC ACID
MOF
PARACETAMOL
UIO-66
topic COTTON FABRIC
FUNCTIONALIZED CELLULOSE
METHYLCHLOROPHENOXYPROPIONIC ACID
MOF
PARACETAMOL
UIO-66
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv We report on the successful functionalization of cotton fabrics with a water-stable metal–organic framework (MOF), UiO-66, under mild solvothermal conditions (80◦ C) and its ability to adsorb and degrade water micropollutants. The functionalized cotton samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FTIR), and X-ray photoelectron spectroscopy (XPS). UiO-66 crystals grew in a uniform and conformal manner over the surface of the cotton fibers. The cotton fabrics functionalized with UiO-66 frameworks exhibited an enhanced uptake capacity for methylchlorophenoxypropionic acid (MCPP), a commonly used herbicide. The functionalized fabrics also showed photocatalytic activity, demonstrated by the degradation of acetaminophen, a common pharmaceutical compound, under simulated sunlight irradiation. These results indicate that UiO-66 can be supported on textile substrates for filtration and photocatalytic purposes and that these substrates can find applications in wastewater decontamination and micropollutant degradation.
Fil: Schelling, Marion. Cornell University; Estados Unidos
Fil: Kim, Manuela Leticia. Consejo Nacional de Investigaciones Científicas y Técnicas. Unidad de Investigación y Desarrollo Estratégico para la Defensa. Ministerio de Defensa. Unidad de Investigación y Desarrollo Estratégico para la Defensa; Argentina. Universidad Tecnológica Nacional. Facultad Reg.rio Grande. Secretaria de Ciencia y Tecnología; Argentina
Fil: Otal, Eugenio Hernan. Consejo Nacional de Investigaciones Científicas y Técnicas. Unidad de Investigación y Desarrollo Estratégico para la Defensa. Ministerio de Defensa. Unidad de Investigación y Desarrollo Estratégico para la Defensa; Argentina. Universidad Tecnológica Nacional. Facultad Reg.rio Grande. Secretaria de Ciencia y Tecnología; Argentina
Fil: Hinestroza, Juan. Cornell University; Estados Unidos
description We report on the successful functionalization of cotton fabrics with a water-stable metal–organic framework (MOF), UiO-66, under mild solvothermal conditions (80◦ C) and its ability to adsorb and degrade water micropollutants. The functionalized cotton samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FTIR), and X-ray photoelectron spectroscopy (XPS). UiO-66 crystals grew in a uniform and conformal manner over the surface of the cotton fibers. The cotton fabrics functionalized with UiO-66 frameworks exhibited an enhanced uptake capacity for methylchlorophenoxypropionic acid (MCPP), a commonly used herbicide. The functionalized fabrics also showed photocatalytic activity, demonstrated by the degradation of acetaminophen, a common pharmaceutical compound, under simulated sunlight irradiation. These results indicate that UiO-66 can be supported on textile substrates for filtration and photocatalytic purposes and that these substrates can find applications in wastewater decontamination and micropollutant degradation.
publishDate 2018
dc.date.none.fl_str_mv 2018-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/82152
Schelling, Marion; Kim, Manuela Leticia; Otal, Eugenio Hernan; Hinestroza, Juan; Decoration of cotton fibers with a water-stable metal–organic framework (UiO-66) for the decomposition and enhanced adsorption of micropollutants in water; MDPI AG; Bioengineering; 5; 1; 3-2018; 14-25
2306-5354
CONICET Digital
CONICET
url http://hdl.handle.net/11336/82152
identifier_str_mv Schelling, Marion; Kim, Manuela Leticia; Otal, Eugenio Hernan; Hinestroza, Juan; Decoration of cotton fibers with a water-stable metal–organic framework (UiO-66) for the decomposition and enhanced adsorption of micropollutants in water; MDPI AG; Bioengineering; 5; 1; 3-2018; 14-25
2306-5354
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2306-5354/5/1/14
info:eu-repo/semantics/altIdentifier/doi/10.3390/bioengineering5010014
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv MDPI AG
publisher.none.fl_str_mv MDPI AG
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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