Biocomposites of bio-polyethylene reinforced with a hydrothermal-alkaline sugarcane bagasse pulp and coupled with a bio-based compatibilizer

Autores
Ehman, Nanci Vanesa; Ita Nagy, Diana; Felissia, Fernando Esteban; Vallejos, María Evangelina; Quispe, Isabel; Area, Maria Cristina; Chinga Carrasco, Gary
Año de publicación
2020
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Bio-polyethylene (BioPE, derived from sugarcane), sugarcane bagasse pulp, and two compatibilizers (fossil and bio-based), were used to manufacture biocomposite filaments for 3D printing. Biocomposite filaments were manufactured and characterized in detail, including measurement of water absorption, mechanical properties, thermal stability and decomposition temperature (thermo-gravimetric analysis (TGA)). Differential scanning calorimetry (DSC) was performed to measure the glass transition temperature (Tg). Scanning electron microscopy (SEM) was applied to assess the fracture area of the filaments after mechanical testing. Increases of up to 10% in water absorption were measured for the samples with 40 wt% fibers and the fossil compatibilizer. The mechanical properties were improved by increasing the fraction of bagasse fibers from 0% to 20% and 40%. The suitability of the biocomposite filaments was tested for 3D printing, and some shapes were printed as demonstrators. Importantly, in a cradle-to-gate life cycle analysis of the biocomposites, we demonstrated that replacing fossil compatibilizer with a bio-based compatibilizer contributes to a reduction in CO2-eq emissions, and an increase in CO2 capture, achieving a CO2-eq storage of 2.12 kg CO2 eq/kg for the biocomposite containing 40% bagasse fibers and 6% bio-based compatibilizer.Keywords: bio-based filament; 3D printing; sugarcane bagasse pulp
Fil: Ehman, Nanci Vanesa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; Argentina
Fil: Ita Nagy, Diana. Pontificia Universidad Católica de Perú; Perú
Fil: Felissia, Fernando Esteban. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; Argentina
Fil: Vallejos, María Evangelina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; Argentina
Fil: Quispe, Isabel. Pontificia Universidad Católica de Perú; Perú
Fil: Area, Maria Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; Argentina
Fil: Chinga Carrasco, Gary. Rise. Paper And Fibre Research Institute As; Noruega
Materia
BIO-BASED FILAMENTS
3D PRINTING
SUGARCANE BAGASSE PULP
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/109604
Acceder
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network_acronym_str CONICETDig
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network_name_str CONICET Digital (CONICET)
spelling Biocomposites of bio-polyethylene reinforced with a hydrothermal-alkaline sugarcane bagasse pulp and coupled with a bio-based compatibilizerEhman, Nanci VanesaIta Nagy, DianaFelissia, Fernando EstebanVallejos, María EvangelinaQuispe, IsabelArea, Maria CristinaChinga Carrasco, GaryBIO-BASED FILAMENTS3D PRINTINGSUGARCANE BAGASSE PULPhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Bio-polyethylene (BioPE, derived from sugarcane), sugarcane bagasse pulp, and two compatibilizers (fossil and bio-based), were used to manufacture biocomposite filaments for 3D printing. Biocomposite filaments were manufactured and characterized in detail, including measurement of water absorption, mechanical properties, thermal stability and decomposition temperature (thermo-gravimetric analysis (TGA)). Differential scanning calorimetry (DSC) was performed to measure the glass transition temperature (Tg). Scanning electron microscopy (SEM) was applied to assess the fracture area of the filaments after mechanical testing. Increases of up to 10% in water absorption were measured for the samples with 40 wt% fibers and the fossil compatibilizer. The mechanical properties were improved by increasing the fraction of bagasse fibers from 0% to 20% and 40%. The suitability of the biocomposite filaments was tested for 3D printing, and some shapes were printed as demonstrators. Importantly, in a cradle-to-gate life cycle analysis of the biocomposites, we demonstrated that replacing fossil compatibilizer with a bio-based compatibilizer contributes to a reduction in CO2-eq emissions, and an increase in CO2 capture, achieving a CO2-eq storage of 2.12 kg CO2 eq/kg for the biocomposite containing 40% bagasse fibers and 6% bio-based compatibilizer.Keywords: bio-based filament; 3D printing; sugarcane bagasse pulpFil: Ehman, Nanci Vanesa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; ArgentinaFil: Ita Nagy, Diana. Pontificia Universidad Católica de Perú; PerúFil: Felissia, Fernando Esteban. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; ArgentinaFil: Vallejos, María Evangelina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; ArgentinaFil: Quispe, Isabel. Pontificia Universidad Católica de Perú; PerúFil: Area, Maria Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; ArgentinaFil: Chinga Carrasco, Gary. Rise. Paper And Fibre Research Institute As; NoruegaMolecular Diversity Preservation International2020-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/109604Ehman, Nanci Vanesa; Ita Nagy, Diana; Felissia, Fernando Esteban; Vallejos, María Evangelina; Quispe, Isabel; et al.; Biocomposites of bio-polyethylene reinforced with a hydrothermal-alkaline sugarcane bagasse pulp and coupled with a bio-based compatibilizer; Molecular Diversity Preservation International; Molecules; 25; 9; 4-2020; 1-161420-3049CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/1420-3049/25/9/2158info:eu-repo/semantics/altIdentifier/doi/10.3390/molecules25092158info:eu-repo/semantics/altIdentifier/url/https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7249044/info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:28:21Zoai:ri.conicet.gov.ar:11336/109604instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:28:22.016CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Biocomposites of bio-polyethylene reinforced with a hydrothermal-alkaline sugarcane bagasse pulp and coupled with a bio-based compatibilizer
title Biocomposites of bio-polyethylene reinforced with a hydrothermal-alkaline sugarcane bagasse pulp and coupled with a bio-based compatibilizer
spellingShingle Biocomposites of bio-polyethylene reinforced with a hydrothermal-alkaline sugarcane bagasse pulp and coupled with a bio-based compatibilizer
Ehman, Nanci Vanesa
BIO-BASED FILAMENTS
3D PRINTING
SUGARCANE BAGASSE PULP
title_short Biocomposites of bio-polyethylene reinforced with a hydrothermal-alkaline sugarcane bagasse pulp and coupled with a bio-based compatibilizer
title_full Biocomposites of bio-polyethylene reinforced with a hydrothermal-alkaline sugarcane bagasse pulp and coupled with a bio-based compatibilizer
title_fullStr Biocomposites of bio-polyethylene reinforced with a hydrothermal-alkaline sugarcane bagasse pulp and coupled with a bio-based compatibilizer
title_full_unstemmed Biocomposites of bio-polyethylene reinforced with a hydrothermal-alkaline sugarcane bagasse pulp and coupled with a bio-based compatibilizer
title_sort Biocomposites of bio-polyethylene reinforced with a hydrothermal-alkaline sugarcane bagasse pulp and coupled with a bio-based compatibilizer
dc.creator.none.fl_str_mv Ehman, Nanci Vanesa
Ita Nagy, Diana
Felissia, Fernando Esteban
Vallejos, María Evangelina
Quispe, Isabel
Area, Maria Cristina
Chinga Carrasco, Gary
author Ehman, Nanci Vanesa
author_facet Ehman, Nanci Vanesa
Ita Nagy, Diana
Felissia, Fernando Esteban
Vallejos, María Evangelina
Quispe, Isabel
Area, Maria Cristina
Chinga Carrasco, Gary
author_role author
author2 Ita Nagy, Diana
Felissia, Fernando Esteban
Vallejos, María Evangelina
Quispe, Isabel
Area, Maria Cristina
Chinga Carrasco, Gary
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv BIO-BASED FILAMENTS
3D PRINTING
SUGARCANE BAGASSE PULP
topic BIO-BASED FILAMENTS
3D PRINTING
SUGARCANE BAGASSE PULP
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Bio-polyethylene (BioPE, derived from sugarcane), sugarcane bagasse pulp, and two compatibilizers (fossil and bio-based), were used to manufacture biocomposite filaments for 3D printing. Biocomposite filaments were manufactured and characterized in detail, including measurement of water absorption, mechanical properties, thermal stability and decomposition temperature (thermo-gravimetric analysis (TGA)). Differential scanning calorimetry (DSC) was performed to measure the glass transition temperature (Tg). Scanning electron microscopy (SEM) was applied to assess the fracture area of the filaments after mechanical testing. Increases of up to 10% in water absorption were measured for the samples with 40 wt% fibers and the fossil compatibilizer. The mechanical properties were improved by increasing the fraction of bagasse fibers from 0% to 20% and 40%. The suitability of the biocomposite filaments was tested for 3D printing, and some shapes were printed as demonstrators. Importantly, in a cradle-to-gate life cycle analysis of the biocomposites, we demonstrated that replacing fossil compatibilizer with a bio-based compatibilizer contributes to a reduction in CO2-eq emissions, and an increase in CO2 capture, achieving a CO2-eq storage of 2.12 kg CO2 eq/kg for the biocomposite containing 40% bagasse fibers and 6% bio-based compatibilizer.Keywords: bio-based filament; 3D printing; sugarcane bagasse pulp
Fil: Ehman, Nanci Vanesa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; Argentina
Fil: Ita Nagy, Diana. Pontificia Universidad Católica de Perú; Perú
Fil: Felissia, Fernando Esteban. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; Argentina
Fil: Vallejos, María Evangelina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; Argentina
Fil: Quispe, Isabel. Pontificia Universidad Católica de Perú; Perú
Fil: Area, Maria Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; Argentina
Fil: Chinga Carrasco, Gary. Rise. Paper And Fibre Research Institute As; Noruega
description Bio-polyethylene (BioPE, derived from sugarcane), sugarcane bagasse pulp, and two compatibilizers (fossil and bio-based), were used to manufacture biocomposite filaments for 3D printing. Biocomposite filaments were manufactured and characterized in detail, including measurement of water absorption, mechanical properties, thermal stability and decomposition temperature (thermo-gravimetric analysis (TGA)). Differential scanning calorimetry (DSC) was performed to measure the glass transition temperature (Tg). Scanning electron microscopy (SEM) was applied to assess the fracture area of the filaments after mechanical testing. Increases of up to 10% in water absorption were measured for the samples with 40 wt% fibers and the fossil compatibilizer. The mechanical properties were improved by increasing the fraction of bagasse fibers from 0% to 20% and 40%. The suitability of the biocomposite filaments was tested for 3D printing, and some shapes were printed as demonstrators. Importantly, in a cradle-to-gate life cycle analysis of the biocomposites, we demonstrated that replacing fossil compatibilizer with a bio-based compatibilizer contributes to a reduction in CO2-eq emissions, and an increase in CO2 capture, achieving a CO2-eq storage of 2.12 kg CO2 eq/kg for the biocomposite containing 40% bagasse fibers and 6% bio-based compatibilizer.Keywords: bio-based filament; 3D printing; sugarcane bagasse pulp
publishDate 2020
dc.date.none.fl_str_mv 2020-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/109604
Ehman, Nanci Vanesa; Ita Nagy, Diana; Felissia, Fernando Esteban; Vallejos, María Evangelina; Quispe, Isabel; et al.; Biocomposites of bio-polyethylene reinforced with a hydrothermal-alkaline sugarcane bagasse pulp and coupled with a bio-based compatibilizer; Molecular Diversity Preservation International; Molecules; 25; 9; 4-2020; 1-16
1420-3049
CONICET Digital
CONICET
url http://hdl.handle.net/11336/109604
identifier_str_mv Ehman, Nanci Vanesa; Ita Nagy, Diana; Felissia, Fernando Esteban; Vallejos, María Evangelina; Quispe, Isabel; et al.; Biocomposites of bio-polyethylene reinforced with a hydrothermal-alkaline sugarcane bagasse pulp and coupled with a bio-based compatibilizer; Molecular Diversity Preservation International; Molecules; 25; 9; 4-2020; 1-16
1420-3049
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/1420-3049/25/9/2158
info:eu-repo/semantics/altIdentifier/doi/10.3390/molecules25092158
info:eu-repo/semantics/altIdentifier/url/https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7249044/
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Molecular Diversity Preservation International
publisher.none.fl_str_mv Molecular Diversity Preservation International
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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