Synthesis of 1,1-Bis(trimethylstannyl)cyclopropanes by the SRN1 Mechanism
- Autores
- Guastavino, Javier Fernando; Rossi, Roberto Arturo
- Año de publicación
- 2009
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The reactions of readily aVailable 1,1-dichlorocyclopropanes, obtained by addition of dichlorocarbene to alkenes, with Me3Sn- anions are reported. The process is described in terms of a photoinduced SRN1 substitution. The 1,1-bis(trimethylstannyl) cyclopropanes were obtained in good to excellent isolated yield (71-90%); 7,7-dichloro-2-oxa-bicyclo[4.1.0]heptane gaVe the 1,1-bis(trimethylstannyl) product in only 40% yield.
Fil: Guastavino, Javier Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Rossi, Roberto Arturo. Universidad Nacional de Córdoba; Argentina - Materia
-
1,1-Dichlorocyclopropanes
Srn1 Reaction
1,1-Bis(Trimethylstannyl)Cyclopropanes - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/21698
Ver los metadatos del registro completo
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Synthesis of 1,1-Bis(trimethylstannyl)cyclopropanes by the SRN1 MechanismGuastavino, Javier FernandoRossi, Roberto Arturo1,1-DichlorocyclopropanesSrn1 Reaction1,1-Bis(Trimethylstannyl)Cyclopropaneshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The reactions of readily aVailable 1,1-dichlorocyclopropanes, obtained by addition of dichlorocarbene to alkenes, with Me3Sn- anions are reported. The process is described in terms of a photoinduced SRN1 substitution. The 1,1-bis(trimethylstannyl) cyclopropanes were obtained in good to excellent isolated yield (71-90%); 7,7-dichloro-2-oxa-bicyclo[4.1.0]heptane gaVe the 1,1-bis(trimethylstannyl) product in only 40% yield.Fil: Guastavino, Javier Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Rossi, Roberto Arturo. Universidad Nacional de Córdoba; ArgentinaAmerican Chemical Society2009-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/21698Guastavino, Javier Fernando; Rossi, Roberto Arturo; Synthesis of 1,1-Bis(trimethylstannyl)cyclopropanes by the SRN1 Mechanism; American Chemical Society; Organometallics; 28; 8; 12-2009; 2646-26490276-7333CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1021/om801104einfo:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/om801104einfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:33:31Zoai:ri.conicet.gov.ar:11336/21698instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:33:31.471CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Synthesis of 1,1-Bis(trimethylstannyl)cyclopropanes by the SRN1 Mechanism |
title |
Synthesis of 1,1-Bis(trimethylstannyl)cyclopropanes by the SRN1 Mechanism |
spellingShingle |
Synthesis of 1,1-Bis(trimethylstannyl)cyclopropanes by the SRN1 Mechanism Guastavino, Javier Fernando 1,1-Dichlorocyclopropanes Srn1 Reaction 1,1-Bis(Trimethylstannyl)Cyclopropanes |
title_short |
Synthesis of 1,1-Bis(trimethylstannyl)cyclopropanes by the SRN1 Mechanism |
title_full |
Synthesis of 1,1-Bis(trimethylstannyl)cyclopropanes by the SRN1 Mechanism |
title_fullStr |
Synthesis of 1,1-Bis(trimethylstannyl)cyclopropanes by the SRN1 Mechanism |
title_full_unstemmed |
Synthesis of 1,1-Bis(trimethylstannyl)cyclopropanes by the SRN1 Mechanism |
title_sort |
Synthesis of 1,1-Bis(trimethylstannyl)cyclopropanes by the SRN1 Mechanism |
dc.creator.none.fl_str_mv |
Guastavino, Javier Fernando Rossi, Roberto Arturo |
author |
Guastavino, Javier Fernando |
author_facet |
Guastavino, Javier Fernando Rossi, Roberto Arturo |
author_role |
author |
author2 |
Rossi, Roberto Arturo |
author2_role |
author |
dc.subject.none.fl_str_mv |
1,1-Dichlorocyclopropanes Srn1 Reaction 1,1-Bis(Trimethylstannyl)Cyclopropanes |
topic |
1,1-Dichlorocyclopropanes Srn1 Reaction 1,1-Bis(Trimethylstannyl)Cyclopropanes |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
The reactions of readily aVailable 1,1-dichlorocyclopropanes, obtained by addition of dichlorocarbene to alkenes, with Me3Sn- anions are reported. The process is described in terms of a photoinduced SRN1 substitution. The 1,1-bis(trimethylstannyl) cyclopropanes were obtained in good to excellent isolated yield (71-90%); 7,7-dichloro-2-oxa-bicyclo[4.1.0]heptane gaVe the 1,1-bis(trimethylstannyl) product in only 40% yield. Fil: Guastavino, Javier Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina Fil: Rossi, Roberto Arturo. Universidad Nacional de Córdoba; Argentina |
description |
The reactions of readily aVailable 1,1-dichlorocyclopropanes, obtained by addition of dichlorocarbene to alkenes, with Me3Sn- anions are reported. The process is described in terms of a photoinduced SRN1 substitution. The 1,1-bis(trimethylstannyl) cyclopropanes were obtained in good to excellent isolated yield (71-90%); 7,7-dichloro-2-oxa-bicyclo[4.1.0]heptane gaVe the 1,1-bis(trimethylstannyl) product in only 40% yield. |
publishDate |
2009 |
dc.date.none.fl_str_mv |
2009-12 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/21698 Guastavino, Javier Fernando; Rossi, Roberto Arturo; Synthesis of 1,1-Bis(trimethylstannyl)cyclopropanes by the SRN1 Mechanism; American Chemical Society; Organometallics; 28; 8; 12-2009; 2646-2649 0276-7333 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/21698 |
identifier_str_mv |
Guastavino, Javier Fernando; Rossi, Roberto Arturo; Synthesis of 1,1-Bis(trimethylstannyl)cyclopropanes by the SRN1 Mechanism; American Chemical Society; Organometallics; 28; 8; 12-2009; 2646-2649 0276-7333 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1021/om801104e info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/om801104e |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
American Chemical Society |
publisher.none.fl_str_mv |
American Chemical Society |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844614350390689792 |
score |
13.070432 |