Amphiphilic Surfactants and Amphiphilic Polymers: Principles of Molecular Assembly

Autores
Iborra, Agustin; Rios Valer, Gabriel Bernardo; Giussi, Juan Martín
Año de publicación
2011
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The use of amphiphilic macrosurfactants as emulsifying agents has shown to have higher efficiency with respect to low molecular weight surfactants. Traditionally, block copolymers have been the first macromolecular systems used for this purpose. Due to the introduction of controlled polymerization techniques in the late nineties, the last decade showed an increase in the number of papers that report the preparation of macromolecules with complex architectures. In this mini-review, we report some advances in the preparation of amphiphilic macromolecules, with special emphasis in copolymers with complex architectures, star and cylindrical. We present a summary list about the synthetic methods and monomers employed to obtain amphiphilic systems as possible alternatives to traditional surfactant.
Fil: Iborra, Agustin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Rios Valer, Gabriel Bernardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Giussi, Juan Martín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Materia
macromolecular surfactants
amphiphilic copolymers
controlled polymerization
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/102217

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spelling Amphiphilic Surfactants and Amphiphilic Polymers: Principles of Molecular AssemblyIborra, AgustinRios Valer, Gabriel BernardoGiussi, Juan Martínmacromolecular surfactantsamphiphilic copolymerscontrolled polymerizationhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The use of amphiphilic macrosurfactants as emulsifying agents has shown to have higher efficiency with respect to low molecular weight surfactants. Traditionally, block copolymers have been the first macromolecular systems used for this purpose. Due to the introduction of controlled polymerization techniques in the late nineties, the last decade showed an increase in the number of papers that report the preparation of macromolecules with complex architectures. In this mini-review, we report some advances in the preparation of amphiphilic macromolecules, with special emphasis in copolymers with complex architectures, star and cylindrical. We present a summary list about the synthetic methods and monomers employed to obtain amphiphilic systems as possible alternatives to traditional surfactant.Fil: Iborra, Agustin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: Rios Valer, Gabriel Bernardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: Giussi, Juan Martín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaAsociación Química Argentina2011-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/102217Iborra, Agustin; Rios Valer, Gabriel Bernardo; Giussi, Juan Martín; Amphiphilic Surfactants and Amphiphilic Polymers: Principles of Molecular Assembly; Asociación Química Argentina; Anales de la Asociación Química Argentina; 1070; 1-2011; 1-222545-86551947-5918CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/abs/10.1021/bk-2011-1070.ch001info:eu-repo/semantics/altIdentifier/doi/10.1021/bk-2011-1070.ch001info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-10T13:01:41Zoai:ri.conicet.gov.ar:11336/102217instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-10 13:01:41.463CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Amphiphilic Surfactants and Amphiphilic Polymers: Principles of Molecular Assembly
title Amphiphilic Surfactants and Amphiphilic Polymers: Principles of Molecular Assembly
spellingShingle Amphiphilic Surfactants and Amphiphilic Polymers: Principles of Molecular Assembly
Iborra, Agustin
macromolecular surfactants
amphiphilic copolymers
controlled polymerization
title_short Amphiphilic Surfactants and Amphiphilic Polymers: Principles of Molecular Assembly
title_full Amphiphilic Surfactants and Amphiphilic Polymers: Principles of Molecular Assembly
title_fullStr Amphiphilic Surfactants and Amphiphilic Polymers: Principles of Molecular Assembly
title_full_unstemmed Amphiphilic Surfactants and Amphiphilic Polymers: Principles of Molecular Assembly
title_sort Amphiphilic Surfactants and Amphiphilic Polymers: Principles of Molecular Assembly
dc.creator.none.fl_str_mv Iborra, Agustin
Rios Valer, Gabriel Bernardo
Giussi, Juan Martín
author Iborra, Agustin
author_facet Iborra, Agustin
Rios Valer, Gabriel Bernardo
Giussi, Juan Martín
author_role author
author2 Rios Valer, Gabriel Bernardo
Giussi, Juan Martín
author2_role author
author
dc.subject.none.fl_str_mv macromolecular surfactants
amphiphilic copolymers
controlled polymerization
topic macromolecular surfactants
amphiphilic copolymers
controlled polymerization
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The use of amphiphilic macrosurfactants as emulsifying agents has shown to have higher efficiency with respect to low molecular weight surfactants. Traditionally, block copolymers have been the first macromolecular systems used for this purpose. Due to the introduction of controlled polymerization techniques in the late nineties, the last decade showed an increase in the number of papers that report the preparation of macromolecules with complex architectures. In this mini-review, we report some advances in the preparation of amphiphilic macromolecules, with special emphasis in copolymers with complex architectures, star and cylindrical. We present a summary list about the synthetic methods and monomers employed to obtain amphiphilic systems as possible alternatives to traditional surfactant.
Fil: Iborra, Agustin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Rios Valer, Gabriel Bernardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Giussi, Juan Martín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
description The use of amphiphilic macrosurfactants as emulsifying agents has shown to have higher efficiency with respect to low molecular weight surfactants. Traditionally, block copolymers have been the first macromolecular systems used for this purpose. Due to the introduction of controlled polymerization techniques in the late nineties, the last decade showed an increase in the number of papers that report the preparation of macromolecules with complex architectures. In this mini-review, we report some advances in the preparation of amphiphilic macromolecules, with special emphasis in copolymers with complex architectures, star and cylindrical. We present a summary list about the synthetic methods and monomers employed to obtain amphiphilic systems as possible alternatives to traditional surfactant.
publishDate 2011
dc.date.none.fl_str_mv 2011-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/102217
Iborra, Agustin; Rios Valer, Gabriel Bernardo; Giussi, Juan Martín; Amphiphilic Surfactants and Amphiphilic Polymers: Principles of Molecular Assembly; Asociación Química Argentina; Anales de la Asociación Química Argentina; 1070; 1-2011; 1-22
2545-8655
1947-5918
CONICET Digital
CONICET
url http://hdl.handle.net/11336/102217
identifier_str_mv Iborra, Agustin; Rios Valer, Gabriel Bernardo; Giussi, Juan Martín; Amphiphilic Surfactants and Amphiphilic Polymers: Principles of Molecular Assembly; Asociación Química Argentina; Anales de la Asociación Química Argentina; 1070; 1-2011; 1-22
2545-8655
1947-5918
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/abs/10.1021/bk-2011-1070.ch001
info:eu-repo/semantics/altIdentifier/doi/10.1021/bk-2011-1070.ch001
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Asociación Química Argentina
publisher.none.fl_str_mv Asociación Química Argentina
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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