Photocatalytic reactors for treating water pollution with solar illumination: A simplified analysis for n-steps flow reactors with recirculation

Autores
Sagawe, Gerd; Brandi, Rodolfo Juan; Bahnemann, Detlef; Cassano, Alberto Enrique
Año de publicación
2005
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The concentration of dissolved oxygen in water, in equilibrium with atmospheric air (ca. 8 ppm at 20 C), defines the limits of all practical oxidizing processes for removing pollutants in photocatalytic reactors. To solve this limitation, an alternative approach to that of a continuously aerated reactor is the use of a recirculating system with aeration performed after every cycle at the reactor entering stream. As defined by the nature of a single recirculating step (the need of a reactor operation at a rather low concentration range), this procedure results in a very low photonic efficiency (thus requiring a large photon collecting area and consequently increasing the capital cost). The design engineer will have to resort to a series of several reactors with recirculation. This solution may then lead to a very high Photonic Efficiency for the entire process (i.e., a reduced light harvesting area) at the price of an increase in the required capital cost (due to the larger number of reactors). This paper provides a very simple analysis and analytical expressions that can be used to estimate, for a desired degree of degradation, a trade-off solution between a high number of reactors and a very large surface area to collect the solar photons.
Fil: Sagawe, Gerd. Universitaet Hannover Callinstrasse 3; Alemania
Fil: Brandi, Rodolfo Juan. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Bahnemann, Detlef. Universitaet Hannover Callinstrasse 3; Alemania
Fil: Cassano, Alberto Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Materia
Photocatalytic Reactor
Photonic Efficiency
Reactor Modelling
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/23490
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Photocatalytic reactors for treating water pollution with solar illumination: A simplified analysis for n-steps flow reactors with recirculationSagawe, GerdBrandi, Rodolfo JuanBahnemann, DetlefCassano, Alberto EnriquePhotocatalytic ReactorPhotonic EfficiencyReactor Modellinghttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The concentration of dissolved oxygen in water, in equilibrium with atmospheric air (ca. 8 ppm at 20 C), defines the limits of all practical oxidizing processes for removing pollutants in photocatalytic reactors. To solve this limitation, an alternative approach to that of a continuously aerated reactor is the use of a recirculating system with aeration performed after every cycle at the reactor entering stream. As defined by the nature of a single recirculating step (the need of a reactor operation at a rather low concentration range), this procedure results in a very low photonic efficiency (thus requiring a large photon collecting area and consequently increasing the capital cost). The design engineer will have to resort to a series of several reactors with recirculation. This solution may then lead to a very high Photonic Efficiency for the entire process (i.e., a reduced light harvesting area) at the price of an increase in the required capital cost (due to the larger number of reactors). This paper provides a very simple analysis and analytical expressions that can be used to estimate, for a desired degree of degradation, a trade-off solution between a high number of reactors and a very large surface area to collect the solar photons.Fil: Sagawe, Gerd. Universitaet Hannover Callinstrasse 3; AlemaniaFil: Brandi, Rodolfo Juan. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Bahnemann, Detlef. Universitaet Hannover Callinstrasse 3; AlemaniaFil: Cassano, Alberto Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaElsevier2005-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/23490Sagawe, Gerd; Brandi, Rodolfo Juan; Bahnemann, Detlef; Cassano, Alberto Enrique; Photocatalytic reactors for treating water pollution with solar illumination: A simplified analysis for n-steps flow reactors with recirculation; Elsevier; Solar Energy; 79; 3; 12-2005; 262-2690038-092XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.solener.2004.11.010info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0038092X04003494info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-10T13:01:37Zoai:ri.conicet.gov.ar:11336/23490instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-10 13:01:37.417CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Photocatalytic reactors for treating water pollution with solar illumination: A simplified analysis for n-steps flow reactors with recirculation
title Photocatalytic reactors for treating water pollution with solar illumination: A simplified analysis for n-steps flow reactors with recirculation
spellingShingle Photocatalytic reactors for treating water pollution with solar illumination: A simplified analysis for n-steps flow reactors with recirculation
Sagawe, Gerd
Photocatalytic Reactor
Photonic Efficiency
Reactor Modelling
title_short Photocatalytic reactors for treating water pollution with solar illumination: A simplified analysis for n-steps flow reactors with recirculation
title_full Photocatalytic reactors for treating water pollution with solar illumination: A simplified analysis for n-steps flow reactors with recirculation
title_fullStr Photocatalytic reactors for treating water pollution with solar illumination: A simplified analysis for n-steps flow reactors with recirculation
title_full_unstemmed Photocatalytic reactors for treating water pollution with solar illumination: A simplified analysis for n-steps flow reactors with recirculation
title_sort Photocatalytic reactors for treating water pollution with solar illumination: A simplified analysis for n-steps flow reactors with recirculation
dc.creator.none.fl_str_mv Sagawe, Gerd
Brandi, Rodolfo Juan
Bahnemann, Detlef
Cassano, Alberto Enrique
author Sagawe, Gerd
author_facet Sagawe, Gerd
Brandi, Rodolfo Juan
Bahnemann, Detlef
Cassano, Alberto Enrique
author_role author
author2 Brandi, Rodolfo Juan
Bahnemann, Detlef
Cassano, Alberto Enrique
author2_role author
author
author
dc.subject.none.fl_str_mv Photocatalytic Reactor
Photonic Efficiency
Reactor Modelling
topic Photocatalytic Reactor
Photonic Efficiency
Reactor Modelling
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The concentration of dissolved oxygen in water, in equilibrium with atmospheric air (ca. 8 ppm at 20 C), defines the limits of all practical oxidizing processes for removing pollutants in photocatalytic reactors. To solve this limitation, an alternative approach to that of a continuously aerated reactor is the use of a recirculating system with aeration performed after every cycle at the reactor entering stream. As defined by the nature of a single recirculating step (the need of a reactor operation at a rather low concentration range), this procedure results in a very low photonic efficiency (thus requiring a large photon collecting area and consequently increasing the capital cost). The design engineer will have to resort to a series of several reactors with recirculation. This solution may then lead to a very high Photonic Efficiency for the entire process (i.e., a reduced light harvesting area) at the price of an increase in the required capital cost (due to the larger number of reactors). This paper provides a very simple analysis and analytical expressions that can be used to estimate, for a desired degree of degradation, a trade-off solution between a high number of reactors and a very large surface area to collect the solar photons.
Fil: Sagawe, Gerd. Universitaet Hannover Callinstrasse 3; Alemania
Fil: Brandi, Rodolfo Juan. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Bahnemann, Detlef. Universitaet Hannover Callinstrasse 3; Alemania
Fil: Cassano, Alberto Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
description The concentration of dissolved oxygen in water, in equilibrium with atmospheric air (ca. 8 ppm at 20 C), defines the limits of all practical oxidizing processes for removing pollutants in photocatalytic reactors. To solve this limitation, an alternative approach to that of a continuously aerated reactor is the use of a recirculating system with aeration performed after every cycle at the reactor entering stream. As defined by the nature of a single recirculating step (the need of a reactor operation at a rather low concentration range), this procedure results in a very low photonic efficiency (thus requiring a large photon collecting area and consequently increasing the capital cost). The design engineer will have to resort to a series of several reactors with recirculation. This solution may then lead to a very high Photonic Efficiency for the entire process (i.e., a reduced light harvesting area) at the price of an increase in the required capital cost (due to the larger number of reactors). This paper provides a very simple analysis and analytical expressions that can be used to estimate, for a desired degree of degradation, a trade-off solution between a high number of reactors and a very large surface area to collect the solar photons.
publishDate 2005
dc.date.none.fl_str_mv 2005-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/23490
Sagawe, Gerd; Brandi, Rodolfo Juan; Bahnemann, Detlef; Cassano, Alberto Enrique; Photocatalytic reactors for treating water pollution with solar illumination: A simplified analysis for n-steps flow reactors with recirculation; Elsevier; Solar Energy; 79; 3; 12-2005; 262-269
0038-092X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/23490
identifier_str_mv Sagawe, Gerd; Brandi, Rodolfo Juan; Bahnemann, Detlef; Cassano, Alberto Enrique; Photocatalytic reactors for treating water pollution with solar illumination: A simplified analysis for n-steps flow reactors with recirculation; Elsevier; Solar Energy; 79; 3; 12-2005; 262-269
0038-092X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.solener.2004.11.010
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0038092X04003494
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.993085

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