Study of the reaction stages and kinetics of the europium oxide carbochlorination
- Autores
- Pomiro, Federico José; Fouga, Gastón Galo; Gaviría, Juan Pablo; Bohe, Ana Ester
- Año de publicación
- 2014
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The europium oxide (Eu2O3(s)) chlorination reaction with sucrose carbon was studied by thermogravimetry between room temperature and 1223 K (950 °C). The nonisothermal thermogravimetry showed that the reaction consists of three stages, and their stoichiometries were studied. The product of the first stage was europium oxychloride, and it showed independence of the reaction kinetics with the carbon content. Subsequently, in the second stage, the EuOCl(s) was carbochlorinated with formation of EuCl3(l) and its evaporation is observed in the third stage. The analysis by Fourier transform infrared spectroscopy of gaseous species showed that the reaction at second stage occurs with the formation of CO2(g) and CO(g). Both reactants and products were analyzed by X-ray diffraction, scanning electron microscopy and wavelength-dispersive X-ray fluorescence spectroscopy. The influence of carbon content, total flow rate, sample initial mass, chlorine partial pressure, and temperature were evaluated. The second stage kinetics was analyzed, which showed an anomalous behavior caused by generation of chlorine radicals during interaction of Cl2(g) and carbon. It was found that the reaction rate at 933 K (660 °C) was proportional to a potential function of the chlorine partial pressure whose exponent is 0.56. The conversion curves were analyzed with the Avrami-Erofeev model and it was obtained an activation energy of 154 ± 5 kJ mol–1.
Fil: Pomiro, Federico José. Comisión Nacional de Energía Atómica. Gerencia Complejo Tecnológico Pilcaniyeu; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina
Fil: Fouga, Gastón Galo. Comisión Nacional de Energía Atómica. Gerencia Complejo Tecnológico Pilcaniyeu; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina
Fil: Gaviría, Juan Pablo. Comisión Nacional de Energía Atómica. Gerencia Complejo Tecnológico Pilcaniyeu; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina
Fil: Bohe, Ana Ester. Universidad Nacional del Comahue. Centro Regional Universitario Bariloche; Argentina. Comisión Nacional de Energía Atómica. Gerencia Complejo Tecnológico Pilcaniyeu; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina - Materia
-
Rare Earth
Chlorination
Kinetics
Thermogravimetric
Europium Oxide - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/127355
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Study of the reaction stages and kinetics of the europium oxide carbochlorinationPomiro, Federico JoséFouga, Gastón GaloGaviría, Juan PabloBohe, Ana EsterRare EarthChlorinationKineticsThermogravimetricEuropium Oxidehttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The europium oxide (Eu2O3(s)) chlorination reaction with sucrose carbon was studied by thermogravimetry between room temperature and 1223 K (950 °C). The nonisothermal thermogravimetry showed that the reaction consists of three stages, and their stoichiometries were studied. The product of the first stage was europium oxychloride, and it showed independence of the reaction kinetics with the carbon content. Subsequently, in the second stage, the EuOCl(s) was carbochlorinated with formation of EuCl3(l) and its evaporation is observed in the third stage. The analysis by Fourier transform infrared spectroscopy of gaseous species showed that the reaction at second stage occurs with the formation of CO2(g) and CO(g). Both reactants and products were analyzed by X-ray diffraction, scanning electron microscopy and wavelength-dispersive X-ray fluorescence spectroscopy. The influence of carbon content, total flow rate, sample initial mass, chlorine partial pressure, and temperature were evaluated. The second stage kinetics was analyzed, which showed an anomalous behavior caused by generation of chlorine radicals during interaction of Cl2(g) and carbon. It was found that the reaction rate at 933 K (660 °C) was proportional to a potential function of the chlorine partial pressure whose exponent is 0.56. The conversion curves were analyzed with the Avrami-Erofeev model and it was obtained an activation energy of 154 ± 5 kJ mol–1.Fil: Pomiro, Federico José. Comisión Nacional de Energía Atómica. Gerencia Complejo Tecnológico Pilcaniyeu; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; ArgentinaFil: Fouga, Gastón Galo. Comisión Nacional de Energía Atómica. Gerencia Complejo Tecnológico Pilcaniyeu; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; ArgentinaFil: Gaviría, Juan Pablo. Comisión Nacional de Energía Atómica. Gerencia Complejo Tecnológico Pilcaniyeu; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; ArgentinaFil: Bohe, Ana Ester. Universidad Nacional del Comahue. Centro Regional Universitario Bariloche; Argentina. Comisión Nacional de Energía Atómica. Gerencia Complejo Tecnológico Pilcaniyeu; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; ArgentinaSpringer2014-10-15info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/127355Pomiro, Federico José; Fouga, Gastón Galo; Gaviría, Juan Pablo; Bohe, Ana Ester; Study of the reaction stages and kinetics of the europium oxide carbochlorination; Springer; Metallurgical And Materials Transactions B-process Metallurgy And Materials Processing Science; 46; 1; 15-10-2014; 304-3151073-5615CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1007/s11663-014-0196-7info:eu-repo/semantics/altIdentifier/url/https://link.springer.com/article/10.1007%2Fs11663-014-0196-7info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:44:16Zoai:ri.conicet.gov.ar:11336/127355instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:44:17.093CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Study of the reaction stages and kinetics of the europium oxide carbochlorination |
title |
Study of the reaction stages and kinetics of the europium oxide carbochlorination |
spellingShingle |
Study of the reaction stages and kinetics of the europium oxide carbochlorination Pomiro, Federico José Rare Earth Chlorination Kinetics Thermogravimetric Europium Oxide |
title_short |
Study of the reaction stages and kinetics of the europium oxide carbochlorination |
title_full |
Study of the reaction stages and kinetics of the europium oxide carbochlorination |
title_fullStr |
Study of the reaction stages and kinetics of the europium oxide carbochlorination |
title_full_unstemmed |
Study of the reaction stages and kinetics of the europium oxide carbochlorination |
title_sort |
Study of the reaction stages and kinetics of the europium oxide carbochlorination |
dc.creator.none.fl_str_mv |
Pomiro, Federico José Fouga, Gastón Galo Gaviría, Juan Pablo Bohe, Ana Ester |
author |
Pomiro, Federico José |
author_facet |
Pomiro, Federico José Fouga, Gastón Galo Gaviría, Juan Pablo Bohe, Ana Ester |
author_role |
author |
author2 |
Fouga, Gastón Galo Gaviría, Juan Pablo Bohe, Ana Ester |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
Rare Earth Chlorination Kinetics Thermogravimetric Europium Oxide |
topic |
Rare Earth Chlorination Kinetics Thermogravimetric Europium Oxide |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
The europium oxide (Eu2O3(s)) chlorination reaction with sucrose carbon was studied by thermogravimetry between room temperature and 1223 K (950 °C). The nonisothermal thermogravimetry showed that the reaction consists of three stages, and their stoichiometries were studied. The product of the first stage was europium oxychloride, and it showed independence of the reaction kinetics with the carbon content. Subsequently, in the second stage, the EuOCl(s) was carbochlorinated with formation of EuCl3(l) and its evaporation is observed in the third stage. The analysis by Fourier transform infrared spectroscopy of gaseous species showed that the reaction at second stage occurs with the formation of CO2(g) and CO(g). Both reactants and products were analyzed by X-ray diffraction, scanning electron microscopy and wavelength-dispersive X-ray fluorescence spectroscopy. The influence of carbon content, total flow rate, sample initial mass, chlorine partial pressure, and temperature were evaluated. The second stage kinetics was analyzed, which showed an anomalous behavior caused by generation of chlorine radicals during interaction of Cl2(g) and carbon. It was found that the reaction rate at 933 K (660 °C) was proportional to a potential function of the chlorine partial pressure whose exponent is 0.56. The conversion curves were analyzed with the Avrami-Erofeev model and it was obtained an activation energy of 154 ± 5 kJ mol–1. Fil: Pomiro, Federico José. Comisión Nacional de Energía Atómica. Gerencia Complejo Tecnológico Pilcaniyeu; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina Fil: Fouga, Gastón Galo. Comisión Nacional de Energía Atómica. Gerencia Complejo Tecnológico Pilcaniyeu; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina Fil: Gaviría, Juan Pablo. Comisión Nacional de Energía Atómica. Gerencia Complejo Tecnológico Pilcaniyeu; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina Fil: Bohe, Ana Ester. Universidad Nacional del Comahue. Centro Regional Universitario Bariloche; Argentina. Comisión Nacional de Energía Atómica. Gerencia Complejo Tecnológico Pilcaniyeu; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina |
description |
The europium oxide (Eu2O3(s)) chlorination reaction with sucrose carbon was studied by thermogravimetry between room temperature and 1223 K (950 °C). The nonisothermal thermogravimetry showed that the reaction consists of three stages, and their stoichiometries were studied. The product of the first stage was europium oxychloride, and it showed independence of the reaction kinetics with the carbon content. Subsequently, in the second stage, the EuOCl(s) was carbochlorinated with formation of EuCl3(l) and its evaporation is observed in the third stage. The analysis by Fourier transform infrared spectroscopy of gaseous species showed that the reaction at second stage occurs with the formation of CO2(g) and CO(g). Both reactants and products were analyzed by X-ray diffraction, scanning electron microscopy and wavelength-dispersive X-ray fluorescence spectroscopy. The influence of carbon content, total flow rate, sample initial mass, chlorine partial pressure, and temperature were evaluated. The second stage kinetics was analyzed, which showed an anomalous behavior caused by generation of chlorine radicals during interaction of Cl2(g) and carbon. It was found that the reaction rate at 933 K (660 °C) was proportional to a potential function of the chlorine partial pressure whose exponent is 0.56. The conversion curves were analyzed with the Avrami-Erofeev model and it was obtained an activation energy of 154 ± 5 kJ mol–1. |
publishDate |
2014 |
dc.date.none.fl_str_mv |
2014-10-15 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/127355 Pomiro, Federico José; Fouga, Gastón Galo; Gaviría, Juan Pablo; Bohe, Ana Ester; Study of the reaction stages and kinetics of the europium oxide carbochlorination; Springer; Metallurgical And Materials Transactions B-process Metallurgy And Materials Processing Science; 46; 1; 15-10-2014; 304-315 1073-5615 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/127355 |
identifier_str_mv |
Pomiro, Federico José; Fouga, Gastón Galo; Gaviría, Juan Pablo; Bohe, Ana Ester; Study of the reaction stages and kinetics of the europium oxide carbochlorination; Springer; Metallurgical And Materials Transactions B-process Metallurgy And Materials Processing Science; 46; 1; 15-10-2014; 304-315 1073-5615 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1007/s11663-014-0196-7 info:eu-repo/semantics/altIdentifier/url/https://link.springer.com/article/10.1007%2Fs11663-014-0196-7 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Springer |
publisher.none.fl_str_mv |
Springer |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
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Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1842268655833841664 |
score |
13.13397 |