Study of the reaction stages and kinetics of the europium oxide carbochlorination

Autores
Pomiro, Federico José; Fouga, Gastón Galo; Gaviría, Juan Pablo; Bohe, Ana Ester
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The europium oxide (Eu2O3(s)) chlorination reaction with sucrose carbon was studied by thermogravimetry between room temperature and 1223 K (950 °C). The nonisothermal thermogravimetry showed that the reaction consists of three stages, and their stoichiometries were studied. The product of the first stage was europium oxychloride, and it showed independence of the reaction kinetics with the carbon content. Subsequently, in the second stage, the EuOCl(s) was carbochlorinated with formation of EuCl3(l) and its evaporation is observed in the third stage. The analysis by Fourier transform infrared spectroscopy of gaseous species showed that the reaction at second stage occurs with the formation of CO2(g) and CO(g). Both reactants and products were analyzed by X-ray diffraction, scanning electron microscopy and wavelength-dispersive X-ray fluorescence spectroscopy. The influence of carbon content, total flow rate, sample initial mass, chlorine partial pressure, and temperature were evaluated. The second stage kinetics was analyzed, which showed an anomalous behavior caused by generation of chlorine radicals during interaction of Cl2(g) and carbon. It was found that the reaction rate at 933 K (660 °C) was proportional to a potential function of the chlorine partial pressure whose exponent is 0.56. The conversion curves were analyzed with the Avrami-Erofeev model and it was obtained an activation energy of 154 ± 5 kJ mol–1.
Fil: Pomiro, Federico José. Comisión Nacional de Energía Atómica. Gerencia Complejo Tecnológico Pilcaniyeu; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina
Fil: Fouga, Gastón Galo. Comisión Nacional de Energía Atómica. Gerencia Complejo Tecnológico Pilcaniyeu; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina
Fil: Gaviría, Juan Pablo. Comisión Nacional de Energía Atómica. Gerencia Complejo Tecnológico Pilcaniyeu; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina
Fil: Bohe, Ana Ester. Universidad Nacional del Comahue. Centro Regional Universitario Bariloche; Argentina. Comisión Nacional de Energía Atómica. Gerencia Complejo Tecnológico Pilcaniyeu; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina
Materia
Rare Earth
Chlorination
Kinetics
Thermogravimetric
Europium Oxide
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/127355
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/127355
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Study of the reaction stages and kinetics of the europium oxide carbochlorinationPomiro, Federico JoséFouga, Gastón GaloGaviría, Juan PabloBohe, Ana EsterRare EarthChlorinationKineticsThermogravimetricEuropium Oxidehttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The europium oxide (Eu2O3(s)) chlorination reaction with sucrose carbon was studied by thermogravimetry between room temperature and 1223 K (950 °C). The nonisothermal thermogravimetry showed that the reaction consists of three stages, and their stoichiometries were studied. The product of the first stage was europium oxychloride, and it showed independence of the reaction kinetics with the carbon content. Subsequently, in the second stage, the EuOCl(s) was carbochlorinated with formation of EuCl3(l) and its evaporation is observed in the third stage. The analysis by Fourier transform infrared spectroscopy of gaseous species showed that the reaction at second stage occurs with the formation of CO2(g) and CO(g). Both reactants and products were analyzed by X-ray diffraction, scanning electron microscopy and wavelength-dispersive X-ray fluorescence spectroscopy. The influence of carbon content, total flow rate, sample initial mass, chlorine partial pressure, and temperature were evaluated. The second stage kinetics was analyzed, which showed an anomalous behavior caused by generation of chlorine radicals during interaction of Cl2(g) and carbon. It was found that the reaction rate at 933 K (660 °C) was proportional to a potential function of the chlorine partial pressure whose exponent is 0.56. The conversion curves were analyzed with the Avrami-Erofeev model and it was obtained an activation energy of 154 ± 5 kJ mol–1.Fil: Pomiro, Federico José. Comisión Nacional de Energía Atómica. Gerencia Complejo Tecnológico Pilcaniyeu; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; ArgentinaFil: Fouga, Gastón Galo. Comisión Nacional de Energía Atómica. Gerencia Complejo Tecnológico Pilcaniyeu; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; ArgentinaFil: Gaviría, Juan Pablo. Comisión Nacional de Energía Atómica. Gerencia Complejo Tecnológico Pilcaniyeu; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; ArgentinaFil: Bohe, Ana Ester. Universidad Nacional del Comahue. Centro Regional Universitario Bariloche; Argentina. Comisión Nacional de Energía Atómica. Gerencia Complejo Tecnológico Pilcaniyeu; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; ArgentinaSpringer2014-10-15info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/127355Pomiro, Federico José; Fouga, Gastón Galo; Gaviría, Juan Pablo; Bohe, Ana Ester; Study of the reaction stages and kinetics of the europium oxide carbochlorination; Springer; Metallurgical And Materials Transactions B-process Metallurgy And Materials Processing Science; 46; 1; 15-10-2014; 304-3151073-5615CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1007/s11663-014-0196-7info:eu-repo/semantics/altIdentifier/url/https://link.springer.com/article/10.1007%2Fs11663-014-0196-7info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:34:00Zoai:ri.conicet.gov.ar:11336/127355instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:34:00.586CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Study of the reaction stages and kinetics of the europium oxide carbochlorination
title Study of the reaction stages and kinetics of the europium oxide carbochlorination
spellingShingle Study of the reaction stages and kinetics of the europium oxide carbochlorination
Pomiro, Federico José
Rare Earth
Chlorination
Kinetics
Thermogravimetric
Europium Oxide
title_short Study of the reaction stages and kinetics of the europium oxide carbochlorination
title_full Study of the reaction stages and kinetics of the europium oxide carbochlorination
title_fullStr Study of the reaction stages and kinetics of the europium oxide carbochlorination
title_full_unstemmed Study of the reaction stages and kinetics of the europium oxide carbochlorination
title_sort Study of the reaction stages and kinetics of the europium oxide carbochlorination
dc.creator.none.fl_str_mv Pomiro, Federico José
Fouga, Gastón Galo
Gaviría, Juan Pablo
Bohe, Ana Ester
author Pomiro, Federico José
author_facet Pomiro, Federico José
Fouga, Gastón Galo
Gaviría, Juan Pablo
Bohe, Ana Ester
author_role author
author2 Fouga, Gastón Galo
Gaviría, Juan Pablo
Bohe, Ana Ester
author2_role author
author
author
dc.subject.none.fl_str_mv Rare Earth
Chlorination
Kinetics
Thermogravimetric
Europium Oxide
topic Rare Earth
Chlorination
Kinetics
Thermogravimetric
Europium Oxide
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The europium oxide (Eu2O3(s)) chlorination reaction with sucrose carbon was studied by thermogravimetry between room temperature and 1223 K (950 °C). The nonisothermal thermogravimetry showed that the reaction consists of three stages, and their stoichiometries were studied. The product of the first stage was europium oxychloride, and it showed independence of the reaction kinetics with the carbon content. Subsequently, in the second stage, the EuOCl(s) was carbochlorinated with formation of EuCl3(l) and its evaporation is observed in the third stage. The analysis by Fourier transform infrared spectroscopy of gaseous species showed that the reaction at second stage occurs with the formation of CO2(g) and CO(g). Both reactants and products were analyzed by X-ray diffraction, scanning electron microscopy and wavelength-dispersive X-ray fluorescence spectroscopy. The influence of carbon content, total flow rate, sample initial mass, chlorine partial pressure, and temperature were evaluated. The second stage kinetics was analyzed, which showed an anomalous behavior caused by generation of chlorine radicals during interaction of Cl2(g) and carbon. It was found that the reaction rate at 933 K (660 °C) was proportional to a potential function of the chlorine partial pressure whose exponent is 0.56. The conversion curves were analyzed with the Avrami-Erofeev model and it was obtained an activation energy of 154 ± 5 kJ mol–1.
Fil: Pomiro, Federico José. Comisión Nacional de Energía Atómica. Gerencia Complejo Tecnológico Pilcaniyeu; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina
Fil: Fouga, Gastón Galo. Comisión Nacional de Energía Atómica. Gerencia Complejo Tecnológico Pilcaniyeu; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina
Fil: Gaviría, Juan Pablo. Comisión Nacional de Energía Atómica. Gerencia Complejo Tecnológico Pilcaniyeu; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina
Fil: Bohe, Ana Ester. Universidad Nacional del Comahue. Centro Regional Universitario Bariloche; Argentina. Comisión Nacional de Energía Atómica. Gerencia Complejo Tecnológico Pilcaniyeu; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina
description The europium oxide (Eu2O3(s)) chlorination reaction with sucrose carbon was studied by thermogravimetry between room temperature and 1223 K (950 °C). The nonisothermal thermogravimetry showed that the reaction consists of three stages, and their stoichiometries were studied. The product of the first stage was europium oxychloride, and it showed independence of the reaction kinetics with the carbon content. Subsequently, in the second stage, the EuOCl(s) was carbochlorinated with formation of EuCl3(l) and its evaporation is observed in the third stage. The analysis by Fourier transform infrared spectroscopy of gaseous species showed that the reaction at second stage occurs with the formation of CO2(g) and CO(g). Both reactants and products were analyzed by X-ray diffraction, scanning electron microscopy and wavelength-dispersive X-ray fluorescence spectroscopy. The influence of carbon content, total flow rate, sample initial mass, chlorine partial pressure, and temperature were evaluated. The second stage kinetics was analyzed, which showed an anomalous behavior caused by generation of chlorine radicals during interaction of Cl2(g) and carbon. It was found that the reaction rate at 933 K (660 °C) was proportional to a potential function of the chlorine partial pressure whose exponent is 0.56. The conversion curves were analyzed with the Avrami-Erofeev model and it was obtained an activation energy of 154 ± 5 kJ mol–1.
publishDate 2014
dc.date.none.fl_str_mv 2014-10-15
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/127355
Pomiro, Federico José; Fouga, Gastón Galo; Gaviría, Juan Pablo; Bohe, Ana Ester; Study of the reaction stages and kinetics of the europium oxide carbochlorination; Springer; Metallurgical And Materials Transactions B-process Metallurgy And Materials Processing Science; 46; 1; 15-10-2014; 304-315
1073-5615
CONICET Digital
CONICET
url http://hdl.handle.net/11336/127355
identifier_str_mv Pomiro, Federico José; Fouga, Gastón Galo; Gaviría, Juan Pablo; Bohe, Ana Ester; Study of the reaction stages and kinetics of the europium oxide carbochlorination; Springer; Metallurgical And Materials Transactions B-process Metallurgy And Materials Processing Science; 46; 1; 15-10-2014; 304-315
1073-5615
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1007/s11663-014-0196-7
info:eu-repo/semantics/altIdentifier/url/https://link.springer.com/article/10.1007%2Fs11663-014-0196-7
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Springer
publisher.none.fl_str_mv Springer
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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