Metastable effects on martensitic transformation in SMAs: Part X. An approach to thermodynamic changes induced for the S-shaped cycles in thick wires of NiTi
- Autores
- Torra, Vicenç; Martorell, F.; Sun, Q. P.; Ahadi, A.; Lovey, Francisco Carlos; Sade Lichtmann, Marcos Leonel
- Año de publicación
- 2017
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The transformation and retransformation paths realized at constant stress in wires of NiTi SMAs show a horizontal or “flat” behavior in the hysteretic cycle. After sinusoidal cycling at 0.01 Hz (i.e., training) with a maximal strain of 8 %, the thicker wires of NiTi SMAs, with a diameter of 2.46 mm, have the stress–strain cycles with one S-shaped behavior. A “similar” change appears by varying the grain sizes in the samples, i.e., from 80 to 20 nm. Furthermore, the local measurements of temperature suggest that cycling induces changes in the transformation mechanisms associated with the evolution from horizontal to S shape. For instance, the associated energy evolves from localized transformation to homogeneous heat production in S-shaped cycles. Thermodynamic analysis establishes a link between heat capacity and the slopes of the coexistence curve in f–x or in σ–ε via the (∂ε/∂σ)coex. The flat cycles were coherent with the classical latent heat, i.e., dissipation at constant stress. In the S-shaped cycles, the heat during the phase change seems redistributed as heat capacity against progressive stress. Preliminary direct measurements are coherent with the evolution of the (∂ε/∂σ)coex against strain.
Fil: Torra, Vicenç. Personal Research Group; España
Fil: Martorell, F.. Personal Research Group; España
Fil: Sun, Q. P.. Hong Kong University of Science and Technology; República de China
Fil: Ahadi, A.. Tsukuba University. National Institute For Materials Science; Japón. Wuhan University; China
Fil: Lovey, Francisco Carlos. Comision Nacional de Energía Atómica. Gerencia de Área Investigaciones y Aplicaciones no Nucleares. Gerencia de Física (Centro Atómico Bariloche). División Física de Metales; Argentina
Fil: Sade Lichtmann, Marcos Leonel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina. Comision Nacional de Energía Atómica. Gerencia de Área Investigaciones y Aplicaciones no Nucleares. Gerencia de Física (Centro Atómico Bariloche). División Física de Metales; Argentina - Materia
-
Grain Size
Heat Capacity
Latent Heat
Martensitic Transformation
Niti
S-Shaped Cycles
Sma
Thinner And Thick Wires - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/79042
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Metastable effects on martensitic transformation in SMAs: Part X. An approach to thermodynamic changes induced for the S-shaped cycles in thick wires of NiTiTorra, VicençMartorell, F.Sun, Q. P.Ahadi, A.Lovey, Francisco CarlosSade Lichtmann, Marcos LeonelGrain SizeHeat CapacityLatent HeatMartensitic TransformationNitiS-Shaped CyclesSmaThinner And Thick Wireshttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1The transformation and retransformation paths realized at constant stress in wires of NiTi SMAs show a horizontal or “flat” behavior in the hysteretic cycle. After sinusoidal cycling at 0.01 Hz (i.e., training) with a maximal strain of 8 %, the thicker wires of NiTi SMAs, with a diameter of 2.46 mm, have the stress–strain cycles with one S-shaped behavior. A “similar” change appears by varying the grain sizes in the samples, i.e., from 80 to 20 nm. Furthermore, the local measurements of temperature suggest that cycling induces changes in the transformation mechanisms associated with the evolution from horizontal to S shape. For instance, the associated energy evolves from localized transformation to homogeneous heat production in S-shaped cycles. Thermodynamic analysis establishes a link between heat capacity and the slopes of the coexistence curve in f–x or in σ–ε via the (∂ε/∂σ)coex. The flat cycles were coherent with the classical latent heat, i.e., dissipation at constant stress. In the S-shaped cycles, the heat during the phase change seems redistributed as heat capacity against progressive stress. Preliminary direct measurements are coherent with the evolution of the (∂ε/∂σ)coex against strain.Fil: Torra, Vicenç. Personal Research Group; EspañaFil: Martorell, F.. Personal Research Group; EspañaFil: Sun, Q. P.. Hong Kong University of Science and Technology; República de ChinaFil: Ahadi, A.. Tsukuba University. National Institute For Materials Science; Japón. Wuhan University; ChinaFil: Lovey, Francisco Carlos. Comision Nacional de Energía Atómica. Gerencia de Área Investigaciones y Aplicaciones no Nucleares. Gerencia de Física (Centro Atómico Bariloche). División Física de Metales; ArgentinaFil: Sade Lichtmann, Marcos Leonel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina. Comision Nacional de Energía Atómica. Gerencia de Área Investigaciones y Aplicaciones no Nucleares. Gerencia de Física (Centro Atómico Bariloche). División Física de Metales; ArgentinaSpringer2017-04-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/79042Torra, Vicenç; Martorell, F.; Sun, Q. P.; Ahadi, A.; Lovey, Francisco Carlos; et al.; Metastable effects on martensitic transformation in SMAs: Part X. An approach to thermodynamic changes induced for the S-shaped cycles in thick wires of NiTi; Springer; Journal of Thermal Analysis and Calorimetry; 128; 1; 1-4-2017; 259-2701388-6150CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1007/s10973-016-5886-8info:eu-repo/semantics/altIdentifier/url/https://link.springer.com/article/10.1007%2Fs10973-016-5886-8info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:47:57Zoai:ri.conicet.gov.ar:11336/79042instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:47:57.458CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Metastable effects on martensitic transformation in SMAs: Part X. An approach to thermodynamic changes induced for the S-shaped cycles in thick wires of NiTi |
title |
Metastable effects on martensitic transformation in SMAs: Part X. An approach to thermodynamic changes induced for the S-shaped cycles in thick wires of NiTi |
spellingShingle |
Metastable effects on martensitic transformation in SMAs: Part X. An approach to thermodynamic changes induced for the S-shaped cycles in thick wires of NiTi Torra, Vicenç Grain Size Heat Capacity Latent Heat Martensitic Transformation Niti S-Shaped Cycles Sma Thinner And Thick Wires |
title_short |
Metastable effects on martensitic transformation in SMAs: Part X. An approach to thermodynamic changes induced for the S-shaped cycles in thick wires of NiTi |
title_full |
Metastable effects on martensitic transformation in SMAs: Part X. An approach to thermodynamic changes induced for the S-shaped cycles in thick wires of NiTi |
title_fullStr |
Metastable effects on martensitic transformation in SMAs: Part X. An approach to thermodynamic changes induced for the S-shaped cycles in thick wires of NiTi |
title_full_unstemmed |
Metastable effects on martensitic transformation in SMAs: Part X. An approach to thermodynamic changes induced for the S-shaped cycles in thick wires of NiTi |
title_sort |
Metastable effects on martensitic transformation in SMAs: Part X. An approach to thermodynamic changes induced for the S-shaped cycles in thick wires of NiTi |
dc.creator.none.fl_str_mv |
Torra, Vicenç Martorell, F. Sun, Q. P. Ahadi, A. Lovey, Francisco Carlos Sade Lichtmann, Marcos Leonel |
author |
Torra, Vicenç |
author_facet |
Torra, Vicenç Martorell, F. Sun, Q. P. Ahadi, A. Lovey, Francisco Carlos Sade Lichtmann, Marcos Leonel |
author_role |
author |
author2 |
Martorell, F. Sun, Q. P. Ahadi, A. Lovey, Francisco Carlos Sade Lichtmann, Marcos Leonel |
author2_role |
author author author author author |
dc.subject.none.fl_str_mv |
Grain Size Heat Capacity Latent Heat Martensitic Transformation Niti S-Shaped Cycles Sma Thinner And Thick Wires |
topic |
Grain Size Heat Capacity Latent Heat Martensitic Transformation Niti S-Shaped Cycles Sma Thinner And Thick Wires |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.3 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
The transformation and retransformation paths realized at constant stress in wires of NiTi SMAs show a horizontal or “flat” behavior in the hysteretic cycle. After sinusoidal cycling at 0.01 Hz (i.e., training) with a maximal strain of 8 %, the thicker wires of NiTi SMAs, with a diameter of 2.46 mm, have the stress–strain cycles with one S-shaped behavior. A “similar” change appears by varying the grain sizes in the samples, i.e., from 80 to 20 nm. Furthermore, the local measurements of temperature suggest that cycling induces changes in the transformation mechanisms associated with the evolution from horizontal to S shape. For instance, the associated energy evolves from localized transformation to homogeneous heat production in S-shaped cycles. Thermodynamic analysis establishes a link between heat capacity and the slopes of the coexistence curve in f–x or in σ–ε via the (∂ε/∂σ)coex. The flat cycles were coherent with the classical latent heat, i.e., dissipation at constant stress. In the S-shaped cycles, the heat during the phase change seems redistributed as heat capacity against progressive stress. Preliminary direct measurements are coherent with the evolution of the (∂ε/∂σ)coex against strain. Fil: Torra, Vicenç. Personal Research Group; España Fil: Martorell, F.. Personal Research Group; España Fil: Sun, Q. P.. Hong Kong University of Science and Technology; República de China Fil: Ahadi, A.. Tsukuba University. National Institute For Materials Science; Japón. Wuhan University; China Fil: Lovey, Francisco Carlos. Comision Nacional de Energía Atómica. Gerencia de Área Investigaciones y Aplicaciones no Nucleares. Gerencia de Física (Centro Atómico Bariloche). División Física de Metales; Argentina Fil: Sade Lichtmann, Marcos Leonel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina. Comision Nacional de Energía Atómica. Gerencia de Área Investigaciones y Aplicaciones no Nucleares. Gerencia de Física (Centro Atómico Bariloche). División Física de Metales; Argentina |
description |
The transformation and retransformation paths realized at constant stress in wires of NiTi SMAs show a horizontal or “flat” behavior in the hysteretic cycle. After sinusoidal cycling at 0.01 Hz (i.e., training) with a maximal strain of 8 %, the thicker wires of NiTi SMAs, with a diameter of 2.46 mm, have the stress–strain cycles with one S-shaped behavior. A “similar” change appears by varying the grain sizes in the samples, i.e., from 80 to 20 nm. Furthermore, the local measurements of temperature suggest that cycling induces changes in the transformation mechanisms associated with the evolution from horizontal to S shape. For instance, the associated energy evolves from localized transformation to homogeneous heat production in S-shaped cycles. Thermodynamic analysis establishes a link between heat capacity and the slopes of the coexistence curve in f–x or in σ–ε via the (∂ε/∂σ)coex. The flat cycles were coherent with the classical latent heat, i.e., dissipation at constant stress. In the S-shaped cycles, the heat during the phase change seems redistributed as heat capacity against progressive stress. Preliminary direct measurements are coherent with the evolution of the (∂ε/∂σ)coex against strain. |
publishDate |
2017 |
dc.date.none.fl_str_mv |
2017-04-01 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/79042 Torra, Vicenç; Martorell, F.; Sun, Q. P.; Ahadi, A.; Lovey, Francisco Carlos; et al.; Metastable effects on martensitic transformation in SMAs: Part X. An approach to thermodynamic changes induced for the S-shaped cycles in thick wires of NiTi; Springer; Journal of Thermal Analysis and Calorimetry; 128; 1; 1-4-2017; 259-270 1388-6150 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/79042 |
identifier_str_mv |
Torra, Vicenç; Martorell, F.; Sun, Q. P.; Ahadi, A.; Lovey, Francisco Carlos; et al.; Metastable effects on martensitic transformation in SMAs: Part X. An approach to thermodynamic changes induced for the S-shaped cycles in thick wires of NiTi; Springer; Journal of Thermal Analysis and Calorimetry; 128; 1; 1-4-2017; 259-270 1388-6150 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1007/s10973-016-5886-8 info:eu-repo/semantics/altIdentifier/url/https://link.springer.com/article/10.1007%2Fs10973-016-5886-8 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Springer |
publisher.none.fl_str_mv |
Springer |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1842268893009149952 |
score |
13.13397 |