Synthesis of fatty acid methyl esters from pomace oil catalyzed by zinc stearate: A kinetic study of the transesterification and esterification reactions

Autores
Alvarez Serafini, Mariana Soledad; Tonetto, Gabriela Marta
Año de publicación
2019
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In this work, the simultaneous transesterification and esterification reactions of olive pomace oil with methanol catalyzed by zinc stearate were studied. This catalyst is a crystalline solid at room temperature, but it is soluble in the reaction medium at reaction temperature. Zinc stearate has surfactant properties that cause the formation of an emulsion in the reaction system. The stability of the emulsion formed in the oil-methanol-catalyst system was compared to that in the FAME (fatty acid methyl esters)-methanol-catalyst system. It was observed that the emulsion formed in the presence of high amounts of FAME is much more unstable, which makes the catalyst easy to separate from the reaction products. The kinetics of esterification and transesterification were also studied. All the kinetic and equilibrium constants were determined with a complete model, considering the three stepwise reactions corresponding to the transesterification of triglycerides and the esterification of free fatty acids. The parameters obtained were used to model the operating conditions that would allow obtaining biodiesel that meets the quality standards.
Fil: Alvarez Serafini, Mariana Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Tonetto, Gabriela Marta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Materia
ESTERIFICATION
FATTY ACID METHYL ESTERS
KINETIC MODEL
POMACE OIL
TRANSESTERIFICATION
ZINC STEARATE
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/120057
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/120057
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Synthesis of fatty acid methyl esters from pomace oil catalyzed by zinc stearate: A kinetic study of the transesterification and esterification reactionsAlvarez Serafini, Mariana SoledadTonetto, Gabriela MartaESTERIFICATIONFATTY ACID METHYL ESTERSKINETIC MODELPOMACE OILTRANSESTERIFICATIONZINC STEARATEhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2In this work, the simultaneous transesterification and esterification reactions of olive pomace oil with methanol catalyzed by zinc stearate were studied. This catalyst is a crystalline solid at room temperature, but it is soluble in the reaction medium at reaction temperature. Zinc stearate has surfactant properties that cause the formation of an emulsion in the reaction system. The stability of the emulsion formed in the oil-methanol-catalyst system was compared to that in the FAME (fatty acid methyl esters)-methanol-catalyst system. It was observed that the emulsion formed in the presence of high amounts of FAME is much more unstable, which makes the catalyst easy to separate from the reaction products. The kinetics of esterification and transesterification were also studied. All the kinetic and equilibrium constants were determined with a complete model, considering the three stepwise reactions corresponding to the transesterification of triglycerides and the esterification of free fatty acids. The parameters obtained were used to model the operating conditions that would allow obtaining biodiesel that meets the quality standards.Fil: Alvarez Serafini, Mariana Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Tonetto, Gabriela Marta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaMultidisciplinary Digital Publishing Institute2019-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/120057Alvarez Serafini, Mariana Soledad; Tonetto, Gabriela Marta; Synthesis of fatty acid methyl esters from pomace oil catalyzed by zinc stearate: A kinetic study of the transesterification and esterification reactions; Multidisciplinary Digital Publishing Institute; Catalysts; 9; 12; 12-2019; 1-152073-4344CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2073-4344/9/12/978info:eu-repo/semantics/altIdentifier/doi/10.3390/catal9120978info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:57:24Zoai:ri.conicet.gov.ar:11336/120057instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:57:24.495CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Synthesis of fatty acid methyl esters from pomace oil catalyzed by zinc stearate: A kinetic study of the transesterification and esterification reactions
title Synthesis of fatty acid methyl esters from pomace oil catalyzed by zinc stearate: A kinetic study of the transesterification and esterification reactions
spellingShingle Synthesis of fatty acid methyl esters from pomace oil catalyzed by zinc stearate: A kinetic study of the transesterification and esterification reactions
Alvarez Serafini, Mariana Soledad
ESTERIFICATION
FATTY ACID METHYL ESTERS
KINETIC MODEL
POMACE OIL
TRANSESTERIFICATION
ZINC STEARATE
title_short Synthesis of fatty acid methyl esters from pomace oil catalyzed by zinc stearate: A kinetic study of the transesterification and esterification reactions
title_full Synthesis of fatty acid methyl esters from pomace oil catalyzed by zinc stearate: A kinetic study of the transesterification and esterification reactions
title_fullStr Synthesis of fatty acid methyl esters from pomace oil catalyzed by zinc stearate: A kinetic study of the transesterification and esterification reactions
title_full_unstemmed Synthesis of fatty acid methyl esters from pomace oil catalyzed by zinc stearate: A kinetic study of the transesterification and esterification reactions
title_sort Synthesis of fatty acid methyl esters from pomace oil catalyzed by zinc stearate: A kinetic study of the transesterification and esterification reactions
dc.creator.none.fl_str_mv Alvarez Serafini, Mariana Soledad
Tonetto, Gabriela Marta
author Alvarez Serafini, Mariana Soledad
author_facet Alvarez Serafini, Mariana Soledad
Tonetto, Gabriela Marta
author_role author
author2 Tonetto, Gabriela Marta
author2_role author
dc.subject.none.fl_str_mv ESTERIFICATION
FATTY ACID METHYL ESTERS
KINETIC MODEL
POMACE OIL
TRANSESTERIFICATION
ZINC STEARATE
topic ESTERIFICATION
FATTY ACID METHYL ESTERS
KINETIC MODEL
POMACE OIL
TRANSESTERIFICATION
ZINC STEARATE
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv In this work, the simultaneous transesterification and esterification reactions of olive pomace oil with methanol catalyzed by zinc stearate were studied. This catalyst is a crystalline solid at room temperature, but it is soluble in the reaction medium at reaction temperature. Zinc stearate has surfactant properties that cause the formation of an emulsion in the reaction system. The stability of the emulsion formed in the oil-methanol-catalyst system was compared to that in the FAME (fatty acid methyl esters)-methanol-catalyst system. It was observed that the emulsion formed in the presence of high amounts of FAME is much more unstable, which makes the catalyst easy to separate from the reaction products. The kinetics of esterification and transesterification were also studied. All the kinetic and equilibrium constants were determined with a complete model, considering the three stepwise reactions corresponding to the transesterification of triglycerides and the esterification of free fatty acids. The parameters obtained were used to model the operating conditions that would allow obtaining biodiesel that meets the quality standards.
Fil: Alvarez Serafini, Mariana Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Tonetto, Gabriela Marta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
description In this work, the simultaneous transesterification and esterification reactions of olive pomace oil with methanol catalyzed by zinc stearate were studied. This catalyst is a crystalline solid at room temperature, but it is soluble in the reaction medium at reaction temperature. Zinc stearate has surfactant properties that cause the formation of an emulsion in the reaction system. The stability of the emulsion formed in the oil-methanol-catalyst system was compared to that in the FAME (fatty acid methyl esters)-methanol-catalyst system. It was observed that the emulsion formed in the presence of high amounts of FAME is much more unstable, which makes the catalyst easy to separate from the reaction products. The kinetics of esterification and transesterification were also studied. All the kinetic and equilibrium constants were determined with a complete model, considering the three stepwise reactions corresponding to the transesterification of triglycerides and the esterification of free fatty acids. The parameters obtained were used to model the operating conditions that would allow obtaining biodiesel that meets the quality standards.
publishDate 2019
dc.date.none.fl_str_mv 2019-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/120057
Alvarez Serafini, Mariana Soledad; Tonetto, Gabriela Marta; Synthesis of fatty acid methyl esters from pomace oil catalyzed by zinc stearate: A kinetic study of the transesterification and esterification reactions; Multidisciplinary Digital Publishing Institute; Catalysts; 9; 12; 12-2019; 1-15
2073-4344
CONICET Digital
CONICET
url http://hdl.handle.net/11336/120057
identifier_str_mv Alvarez Serafini, Mariana Soledad; Tonetto, Gabriela Marta; Synthesis of fatty acid methyl esters from pomace oil catalyzed by zinc stearate: A kinetic study of the transesterification and esterification reactions; Multidisciplinary Digital Publishing Institute; Catalysts; 9; 12; 12-2019; 1-15
2073-4344
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2073-4344/9/12/978
info:eu-repo/semantics/altIdentifier/doi/10.3390/catal9120978
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute
publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844613717722923008
score 13.070432

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