Synthesis and characterization of Bi1−x Ndx FeO3 (0 ≤ x ≤ 0.3) prepared by thermal decomposition of Bi1−x Ndx [Fe(CN)6 ]·4H2 O

Autores
Navarro, Maria Carolina; Jorge, Guillermo Antonio; Negri, Ricardo Martin; Saleh Medina, Leila María; Gómez, M. I.
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The series of polycrystalline heteronuclear complexes, Bi1−xNdx[Fe(CN)6]·4H2O (0 ≤ x ≤ 0.3), was successfully synthesized and characterized, by means of powder X-ray diffraction (PXRD) and infrared spectroscopy. The thermal behaviour was studied by thermogravimetric and differential thermal analysis. The crystal structure of the complexes was refined by Rietveld analysis. It was found that they crystallized in the orthorhombic crystal system, space group Cmcm. The lattice parameters and unit cell volume decrease with an increase in Nd concentration. In order to obtain the oxides Bi1−xNdxFeO3, the thermal decomposition of the inorganic complexes, Bi1−xNdx[Fe(CN)6]·4H2O, has been investigated. By Rietveld analysis of PXRD data, the synthesis of the oxides was confirmed, evidencing in the series, a gradual change in crystal structure from rhombohedra to triclinic. Furthermore, with an increase in Nd content in Bi1−xNdxFeO3 oxides, impurity phases, such as Bi2O3, Bi2Fe4O9 and Bi25FeO39 associated with the synthesis of BiFeO3, are reduced. The morphology and chemical composition were investigated by microscopy electronic scattering and energy-dispersive X-ray spectroscopy. The electrical and magnetic properties have been determined to characterize the obtained oxides.
Fil: Navarro, Maria Carolina. Universidad Nacional de Tucuman. Facultad de Bioquímica, Química y Farmacia. Instituto de Química Inorganica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Jorge, Guillermo Antonio. Universidad Nacional de General Sarmiento. Instituto de Ciencias; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Negri, Ricardo Martin. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Saleh Medina, Leila María. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Gómez, M. I.. Universidad Nacional de Tucuman. Facultad de Bioquímica, Química y Farmacia. Instituto de Química Inorganica; Argentina
Materia
Hexacyanoferrate (Iii)
Rietveld Method
X-Ray Diffraction
Thermal Decomposition
Mixed Oxides
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/42287
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/42287
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Synthesis and characterization of Bi1−x Ndx FeO3 (0 ≤ x ≤ 0.3) prepared by thermal decomposition of Bi1−x Ndx [Fe(CN)6 ]·4H2 ONavarro, Maria CarolinaJorge, Guillermo AntonioNegri, Ricardo MartinSaleh Medina, Leila MaríaGómez, M. I.Hexacyanoferrate (Iii)Rietveld MethodX-Ray DiffractionThermal DecompositionMixed Oxideshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The series of polycrystalline heteronuclear complexes, Bi1−xNdx[Fe(CN)6]·4H2O (0 ≤ x ≤ 0.3), was successfully synthesized and characterized, by means of powder X-ray diffraction (PXRD) and infrared spectroscopy. The thermal behaviour was studied by thermogravimetric and differential thermal analysis. The crystal structure of the complexes was refined by Rietveld analysis. It was found that they crystallized in the orthorhombic crystal system, space group Cmcm. The lattice parameters and unit cell volume decrease with an increase in Nd concentration. In order to obtain the oxides Bi1−xNdxFeO3, the thermal decomposition of the inorganic complexes, Bi1−xNdx[Fe(CN)6]·4H2O, has been investigated. By Rietveld analysis of PXRD data, the synthesis of the oxides was confirmed, evidencing in the series, a gradual change in crystal structure from rhombohedra to triclinic. Furthermore, with an increase in Nd content in Bi1−xNdxFeO3 oxides, impurity phases, such as Bi2O3, Bi2Fe4O9 and Bi25FeO39 associated with the synthesis of BiFeO3, are reduced. The morphology and chemical composition were investigated by microscopy electronic scattering and energy-dispersive X-ray spectroscopy. The electrical and magnetic properties have been determined to characterize the obtained oxides.Fil: Navarro, Maria Carolina. Universidad Nacional de Tucuman. Facultad de Bioquímica, Química y Farmacia. Instituto de Química Inorganica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Jorge, Guillermo Antonio. Universidad Nacional de General Sarmiento. Instituto de Ciencias; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Negri, Ricardo Martin. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaFil: Saleh Medina, Leila María. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaFil: Gómez, M. I.. Universidad Nacional de Tucuman. Facultad de Bioquímica, Química y Farmacia. Instituto de Química Inorganica; ArgentinaSpringer2015-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/42287Navarro, Maria Carolina; Jorge, Guillermo Antonio; Negri, Ricardo Martin; Saleh Medina, Leila María; Gómez, M. I.; Synthesis and characterization of Bi1−x Ndx FeO3 (0 ≤ x ≤ 0.3) prepared by thermal decomposition of Bi1−x Ndx [Fe(CN)6 ]·4H2 O; Springer; Journal of Thermal Analysis and Calorimetry; 122; 1; 10-2015; 73-801388-61501588-2926CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://link.springer.com/article/10.1007/s10973-015-4669-yinfo:eu-repo/semantics/altIdentifier/doi/10.1007/s10973-015-4669-yinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:31:25Zoai:ri.conicet.gov.ar:11336/42287instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:31:26.013CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Synthesis and characterization of Bi1−x Ndx FeO3 (0 ≤ x ≤ 0.3) prepared by thermal decomposition of Bi1−x Ndx [Fe(CN)6 ]·4H2 O
title Synthesis and characterization of Bi1−x Ndx FeO3 (0 ≤ x ≤ 0.3) prepared by thermal decomposition of Bi1−x Ndx [Fe(CN)6 ]·4H2 O
spellingShingle Synthesis and characterization of Bi1−x Ndx FeO3 (0 ≤ x ≤ 0.3) prepared by thermal decomposition of Bi1−x Ndx [Fe(CN)6 ]·4H2 O
Navarro, Maria Carolina
Hexacyanoferrate (Iii)
Rietveld Method
X-Ray Diffraction
Thermal Decomposition
Mixed Oxides
title_short Synthesis and characterization of Bi1−x Ndx FeO3 (0 ≤ x ≤ 0.3) prepared by thermal decomposition of Bi1−x Ndx [Fe(CN)6 ]·4H2 O
title_full Synthesis and characterization of Bi1−x Ndx FeO3 (0 ≤ x ≤ 0.3) prepared by thermal decomposition of Bi1−x Ndx [Fe(CN)6 ]·4H2 O
title_fullStr Synthesis and characterization of Bi1−x Ndx FeO3 (0 ≤ x ≤ 0.3) prepared by thermal decomposition of Bi1−x Ndx [Fe(CN)6 ]·4H2 O
title_full_unstemmed Synthesis and characterization of Bi1−x Ndx FeO3 (0 ≤ x ≤ 0.3) prepared by thermal decomposition of Bi1−x Ndx [Fe(CN)6 ]·4H2 O
title_sort Synthesis and characterization of Bi1−x Ndx FeO3 (0 ≤ x ≤ 0.3) prepared by thermal decomposition of Bi1−x Ndx [Fe(CN)6 ]·4H2 O
dc.creator.none.fl_str_mv Navarro, Maria Carolina
Jorge, Guillermo Antonio
Negri, Ricardo Martin
Saleh Medina, Leila María
Gómez, M. I.
author Navarro, Maria Carolina
author_facet Navarro, Maria Carolina
Jorge, Guillermo Antonio
Negri, Ricardo Martin
Saleh Medina, Leila María
Gómez, M. I.
author_role author
author2 Jorge, Guillermo Antonio
Negri, Ricardo Martin
Saleh Medina, Leila María
Gómez, M. I.
author2_role author
author
author
author
dc.subject.none.fl_str_mv Hexacyanoferrate (Iii)
Rietveld Method
X-Ray Diffraction
Thermal Decomposition
Mixed Oxides
topic Hexacyanoferrate (Iii)
Rietveld Method
X-Ray Diffraction
Thermal Decomposition
Mixed Oxides
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The series of polycrystalline heteronuclear complexes, Bi1−xNdx[Fe(CN)6]·4H2O (0 ≤ x ≤ 0.3), was successfully synthesized and characterized, by means of powder X-ray diffraction (PXRD) and infrared spectroscopy. The thermal behaviour was studied by thermogravimetric and differential thermal analysis. The crystal structure of the complexes was refined by Rietveld analysis. It was found that they crystallized in the orthorhombic crystal system, space group Cmcm. The lattice parameters and unit cell volume decrease with an increase in Nd concentration. In order to obtain the oxides Bi1−xNdxFeO3, the thermal decomposition of the inorganic complexes, Bi1−xNdx[Fe(CN)6]·4H2O, has been investigated. By Rietveld analysis of PXRD data, the synthesis of the oxides was confirmed, evidencing in the series, a gradual change in crystal structure from rhombohedra to triclinic. Furthermore, with an increase in Nd content in Bi1−xNdxFeO3 oxides, impurity phases, such as Bi2O3, Bi2Fe4O9 and Bi25FeO39 associated with the synthesis of BiFeO3, are reduced. The morphology and chemical composition were investigated by microscopy electronic scattering and energy-dispersive X-ray spectroscopy. The electrical and magnetic properties have been determined to characterize the obtained oxides.
Fil: Navarro, Maria Carolina. Universidad Nacional de Tucuman. Facultad de Bioquímica, Química y Farmacia. Instituto de Química Inorganica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Jorge, Guillermo Antonio. Universidad Nacional de General Sarmiento. Instituto de Ciencias; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Negri, Ricardo Martin. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Saleh Medina, Leila María. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Gómez, M. I.. Universidad Nacional de Tucuman. Facultad de Bioquímica, Química y Farmacia. Instituto de Química Inorganica; Argentina
description The series of polycrystalline heteronuclear complexes, Bi1−xNdx[Fe(CN)6]·4H2O (0 ≤ x ≤ 0.3), was successfully synthesized and characterized, by means of powder X-ray diffraction (PXRD) and infrared spectroscopy. The thermal behaviour was studied by thermogravimetric and differential thermal analysis. The crystal structure of the complexes was refined by Rietveld analysis. It was found that they crystallized in the orthorhombic crystal system, space group Cmcm. The lattice parameters and unit cell volume decrease with an increase in Nd concentration. In order to obtain the oxides Bi1−xNdxFeO3, the thermal decomposition of the inorganic complexes, Bi1−xNdx[Fe(CN)6]·4H2O, has been investigated. By Rietveld analysis of PXRD data, the synthesis of the oxides was confirmed, evidencing in the series, a gradual change in crystal structure from rhombohedra to triclinic. Furthermore, with an increase in Nd content in Bi1−xNdxFeO3 oxides, impurity phases, such as Bi2O3, Bi2Fe4O9 and Bi25FeO39 associated with the synthesis of BiFeO3, are reduced. The morphology and chemical composition were investigated by microscopy electronic scattering and energy-dispersive X-ray spectroscopy. The electrical and magnetic properties have been determined to characterize the obtained oxides.
publishDate 2015
dc.date.none.fl_str_mv 2015-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/42287
Navarro, Maria Carolina; Jorge, Guillermo Antonio; Negri, Ricardo Martin; Saleh Medina, Leila María; Gómez, M. I.; Synthesis and characterization of Bi1−x Ndx FeO3 (0 ≤ x ≤ 0.3) prepared by thermal decomposition of Bi1−x Ndx [Fe(CN)6 ]·4H2 O; Springer; Journal of Thermal Analysis and Calorimetry; 122; 1; 10-2015; 73-80
1388-6150
1588-2926
CONICET Digital
CONICET
url http://hdl.handle.net/11336/42287
identifier_str_mv Navarro, Maria Carolina; Jorge, Guillermo Antonio; Negri, Ricardo Martin; Saleh Medina, Leila María; Gómez, M. I.; Synthesis and characterization of Bi1−x Ndx FeO3 (0 ≤ x ≤ 0.3) prepared by thermal decomposition of Bi1−x Ndx [Fe(CN)6 ]·4H2 O; Springer; Journal of Thermal Analysis and Calorimetry; 122; 1; 10-2015; 73-80
1388-6150
1588-2926
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://link.springer.com/article/10.1007/s10973-015-4669-y
info:eu-repo/semantics/altIdentifier/doi/10.1007/s10973-015-4669-y
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Springer
publisher.none.fl_str_mv Springer
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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