Structural and magnetic properties of nanocrystalline Bi1-xLaxFeO3 (0.0 ≤ x ≤ 0.4) synthesized by a mechanochemical route
- Autores
- Cristobal, Adrian Alberto; Ramos, Cinthia Paula; Conconi, María Susana; Bercoff, Paula Gabriela; Botta, Pablo Martín
- Año de publicación
- 2017
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Bi1-xLaxFeO3 (0.0 ≤ x ≤ 0.4) powders were prepared by means of a solid acid-base reaction induced by mechanochemical energy. Bi, La and Fe chlorides were high-energy ball-milled with NaOH, yielding a mixture of Bi1-xLaxFeO3 and NaCl. After heating and washing, nanoparticles of Bi1-xLaxFeO3 were obtained as a main product, with low contents of secondary phases. Structural characterization was performed by X-ray diffraction (Rietveld refinement) and Raman spectroscopy. The hyperfine magnetic behavior was analyzed by means of Mössbauer spectroscopy and the microstructure of the particles was evaluated by transmission electron microscopy. Differential scanning calorimetry was employed to investigate the thermal behavior of the samples and magnetic measurements at room temperature were also carried out. Crystal structure transitions as a function of composition were identified. Moreover, an intricate magnetic behavior was observed, which was explained on the basis of the concomitant contribution of two different canting levels of the antiparallel spins.
Fil: Cristobal, Adrian Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Ramos, Cinthia Paula. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes. Gerencia de Investigación y Aplicaciones; Argentina
Fil: Conconi, María Susana. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina
Fil: Bercoff, Paula Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina
Fil: Botta, Pablo Martín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina - Materia
-
Mechanochemistry
Multiferroics
Bi1-xLaxFe2O4 - Nivel de accesibilidad
- acceso embargado
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/65081
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Structural and magnetic properties of nanocrystalline Bi1-xLaxFeO3 (0.0 ≤ x ≤ 0.4) synthesized by a mechanochemical routeCristobal, Adrian AlbertoRamos, Cinthia PaulaConconi, María SusanaBercoff, Paula GabrielaBotta, Pablo MartínMechanochemistryMultiferroicsBi1-xLaxFe2O4https://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Bi1-xLaxFeO3 (0.0 ≤ x ≤ 0.4) powders were prepared by means of a solid acid-base reaction induced by mechanochemical energy. Bi, La and Fe chlorides were high-energy ball-milled with NaOH, yielding a mixture of Bi1-xLaxFeO3 and NaCl. After heating and washing, nanoparticles of Bi1-xLaxFeO3 were obtained as a main product, with low contents of secondary phases. Structural characterization was performed by X-ray diffraction (Rietveld refinement) and Raman spectroscopy. The hyperfine magnetic behavior was analyzed by means of Mössbauer spectroscopy and the microstructure of the particles was evaluated by transmission electron microscopy. Differential scanning calorimetry was employed to investigate the thermal behavior of the samples and magnetic measurements at room temperature were also carried out. Crystal structure transitions as a function of composition were identified. Moreover, an intricate magnetic behavior was observed, which was explained on the basis of the concomitant contribution of two different canting levels of the antiparallel spins.Fil: Cristobal, Adrian Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Ramos, Cinthia Paula. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes. Gerencia de Investigación y Aplicaciones; ArgentinaFil: Conconi, María Susana. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; ArgentinaFil: Bercoff, Paula Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; ArgentinaFil: Botta, Pablo Martín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaPergamon-Elsevier Science Ltd2017-11info:eu-repo/date/embargoEnd/2019-12-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/65081Cristobal, Adrian Alberto; Ramos, Cinthia Paula; Conconi, María Susana; Bercoff, Paula Gabriela; Botta, Pablo Martín; Structural and magnetic properties of nanocrystalline Bi1-xLaxFeO3 (0.0 ≤ x ≤ 0.4) synthesized by a mechanochemical route; Pergamon-Elsevier Science Ltd; Materials Research Bulletin; 95; 11-2017; 292-2990025-5408CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0025540816324023info:eu-repo/semantics/altIdentifier/doi/10.1016/j.materresbull.2017.07.035info:eu-repo/semantics/embargoedAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:15:44Zoai:ri.conicet.gov.ar:11336/65081instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:15:44.882CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Structural and magnetic properties of nanocrystalline Bi1-xLaxFeO3 (0.0 ≤ x ≤ 0.4) synthesized by a mechanochemical route |
title |
Structural and magnetic properties of nanocrystalline Bi1-xLaxFeO3 (0.0 ≤ x ≤ 0.4) synthesized by a mechanochemical route |
spellingShingle |
Structural and magnetic properties of nanocrystalline Bi1-xLaxFeO3 (0.0 ≤ x ≤ 0.4) synthesized by a mechanochemical route Cristobal, Adrian Alberto Mechanochemistry Multiferroics Bi1-xLaxFe2O4 |
title_short |
Structural and magnetic properties of nanocrystalline Bi1-xLaxFeO3 (0.0 ≤ x ≤ 0.4) synthesized by a mechanochemical route |
title_full |
Structural and magnetic properties of nanocrystalline Bi1-xLaxFeO3 (0.0 ≤ x ≤ 0.4) synthesized by a mechanochemical route |
title_fullStr |
Structural and magnetic properties of nanocrystalline Bi1-xLaxFeO3 (0.0 ≤ x ≤ 0.4) synthesized by a mechanochemical route |
title_full_unstemmed |
Structural and magnetic properties of nanocrystalline Bi1-xLaxFeO3 (0.0 ≤ x ≤ 0.4) synthesized by a mechanochemical route |
title_sort |
Structural and magnetic properties of nanocrystalline Bi1-xLaxFeO3 (0.0 ≤ x ≤ 0.4) synthesized by a mechanochemical route |
dc.creator.none.fl_str_mv |
Cristobal, Adrian Alberto Ramos, Cinthia Paula Conconi, María Susana Bercoff, Paula Gabriela Botta, Pablo Martín |
author |
Cristobal, Adrian Alberto |
author_facet |
Cristobal, Adrian Alberto Ramos, Cinthia Paula Conconi, María Susana Bercoff, Paula Gabriela Botta, Pablo Martín |
author_role |
author |
author2 |
Ramos, Cinthia Paula Conconi, María Susana Bercoff, Paula Gabriela Botta, Pablo Martín |
author2_role |
author author author author |
dc.subject.none.fl_str_mv |
Mechanochemistry Multiferroics Bi1-xLaxFe2O4 |
topic |
Mechanochemistry Multiferroics Bi1-xLaxFe2O4 |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.5 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
Bi1-xLaxFeO3 (0.0 ≤ x ≤ 0.4) powders were prepared by means of a solid acid-base reaction induced by mechanochemical energy. Bi, La and Fe chlorides were high-energy ball-milled with NaOH, yielding a mixture of Bi1-xLaxFeO3 and NaCl. After heating and washing, nanoparticles of Bi1-xLaxFeO3 were obtained as a main product, with low contents of secondary phases. Structural characterization was performed by X-ray diffraction (Rietveld refinement) and Raman spectroscopy. The hyperfine magnetic behavior was analyzed by means of Mössbauer spectroscopy and the microstructure of the particles was evaluated by transmission electron microscopy. Differential scanning calorimetry was employed to investigate the thermal behavior of the samples and magnetic measurements at room temperature were also carried out. Crystal structure transitions as a function of composition were identified. Moreover, an intricate magnetic behavior was observed, which was explained on the basis of the concomitant contribution of two different canting levels of the antiparallel spins. Fil: Cristobal, Adrian Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina Fil: Ramos, Cinthia Paula. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes. Gerencia de Investigación y Aplicaciones; Argentina Fil: Conconi, María Susana. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina Fil: Bercoff, Paula Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina Fil: Botta, Pablo Martín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina |
description |
Bi1-xLaxFeO3 (0.0 ≤ x ≤ 0.4) powders were prepared by means of a solid acid-base reaction induced by mechanochemical energy. Bi, La and Fe chlorides were high-energy ball-milled with NaOH, yielding a mixture of Bi1-xLaxFeO3 and NaCl. After heating and washing, nanoparticles of Bi1-xLaxFeO3 were obtained as a main product, with low contents of secondary phases. Structural characterization was performed by X-ray diffraction (Rietveld refinement) and Raman spectroscopy. The hyperfine magnetic behavior was analyzed by means of Mössbauer spectroscopy and the microstructure of the particles was evaluated by transmission electron microscopy. Differential scanning calorimetry was employed to investigate the thermal behavior of the samples and magnetic measurements at room temperature were also carried out. Crystal structure transitions as a function of composition were identified. Moreover, an intricate magnetic behavior was observed, which was explained on the basis of the concomitant contribution of two different canting levels of the antiparallel spins. |
publishDate |
2017 |
dc.date.none.fl_str_mv |
2017-11 info:eu-repo/date/embargoEnd/2019-12-01 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/65081 Cristobal, Adrian Alberto; Ramos, Cinthia Paula; Conconi, María Susana; Bercoff, Paula Gabriela; Botta, Pablo Martín; Structural and magnetic properties of nanocrystalline Bi1-xLaxFeO3 (0.0 ≤ x ≤ 0.4) synthesized by a mechanochemical route; Pergamon-Elsevier Science Ltd; Materials Research Bulletin; 95; 11-2017; 292-299 0025-5408 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/65081 |
identifier_str_mv |
Cristobal, Adrian Alberto; Ramos, Cinthia Paula; Conconi, María Susana; Bercoff, Paula Gabriela; Botta, Pablo Martín; Structural and magnetic properties of nanocrystalline Bi1-xLaxFeO3 (0.0 ≤ x ≤ 0.4) synthesized by a mechanochemical route; Pergamon-Elsevier Science Ltd; Materials Research Bulletin; 95; 11-2017; 292-299 0025-5408 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0025540816324023 info:eu-repo/semantics/altIdentifier/doi/10.1016/j.materresbull.2017.07.035 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/embargoedAccess https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
eu_rights_str_mv |
embargoedAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Pergamon-Elsevier Science Ltd |
publisher.none.fl_str_mv |
Pergamon-Elsevier Science Ltd |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
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CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
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Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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13.070432 |