Structural and magnetic properties of nanocrystalline Bi1-xLaxFeO3 (0.0 ≤ x ≤ 0.4) synthesized by a mechanochemical route

Autores
Cristobal, Adrian Alberto; Ramos, Cinthia Paula; Conconi, María Susana; Bercoff, Paula Gabriela; Botta, Pablo Martín
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Bi1-xLaxFeO3 (0.0 ≤ x ≤ 0.4) powders were prepared by means of a solid acid-base reaction induced by mechanochemical energy. Bi, La and Fe chlorides were high-energy ball-milled with NaOH, yielding a mixture of Bi1-xLaxFeO3 and NaCl. After heating and washing, nanoparticles of Bi1-xLaxFeO3 were obtained as a main product, with low contents of secondary phases. Structural characterization was performed by X-ray diffraction (Rietveld refinement) and Raman spectroscopy. The hyperfine magnetic behavior was analyzed by means of Mössbauer spectroscopy and the microstructure of the particles was evaluated by transmission electron microscopy. Differential scanning calorimetry was employed to investigate the thermal behavior of the samples and magnetic measurements at room temperature were also carried out. Crystal structure transitions as a function of composition were identified. Moreover, an intricate magnetic behavior was observed, which was explained on the basis of the concomitant contribution of two different canting levels of the antiparallel spins.
Fil: Cristobal, Adrian Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Ramos, Cinthia Paula. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes. Gerencia de Investigación y Aplicaciones; Argentina
Fil: Conconi, María Susana. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina
Fil: Bercoff, Paula Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina
Fil: Botta, Pablo Martín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Materia
Mechanochemistry
Multiferroics
Bi1-xLaxFe2O4
Nivel de accesibilidad
acceso embargado
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/65081
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/65081
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Structural and magnetic properties of nanocrystalline Bi1-xLaxFeO3 (0.0 ≤ x ≤ 0.4) synthesized by a mechanochemical routeCristobal, Adrian AlbertoRamos, Cinthia PaulaConconi, María SusanaBercoff, Paula GabrielaBotta, Pablo MartínMechanochemistryMultiferroicsBi1-xLaxFe2O4https://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Bi1-xLaxFeO3 (0.0 ≤ x ≤ 0.4) powders were prepared by means of a solid acid-base reaction induced by mechanochemical energy. Bi, La and Fe chlorides were high-energy ball-milled with NaOH, yielding a mixture of Bi1-xLaxFeO3 and NaCl. After heating and washing, nanoparticles of Bi1-xLaxFeO3 were obtained as a main product, with low contents of secondary phases. Structural characterization was performed by X-ray diffraction (Rietveld refinement) and Raman spectroscopy. The hyperfine magnetic behavior was analyzed by means of Mössbauer spectroscopy and the microstructure of the particles was evaluated by transmission electron microscopy. Differential scanning calorimetry was employed to investigate the thermal behavior of the samples and magnetic measurements at room temperature were also carried out. Crystal structure transitions as a function of composition were identified. Moreover, an intricate magnetic behavior was observed, which was explained on the basis of the concomitant contribution of two different canting levels of the antiparallel spins.Fil: Cristobal, Adrian Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Ramos, Cinthia Paula. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes. Gerencia de Investigación y Aplicaciones; ArgentinaFil: Conconi, María Susana. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; ArgentinaFil: Bercoff, Paula Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; ArgentinaFil: Botta, Pablo Martín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaPergamon-Elsevier Science Ltd2017-11info:eu-repo/date/embargoEnd/2019-12-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/65081Cristobal, Adrian Alberto; Ramos, Cinthia Paula; Conconi, María Susana; Bercoff, Paula Gabriela; Botta, Pablo Martín; Structural and magnetic properties of nanocrystalline Bi1-xLaxFeO3 (0.0 ≤ x ≤ 0.4) synthesized by a mechanochemical route; Pergamon-Elsevier Science Ltd; Materials Research Bulletin; 95; 11-2017; 292-2990025-5408CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0025540816324023info:eu-repo/semantics/altIdentifier/doi/10.1016/j.materresbull.2017.07.035info:eu-repo/semantics/embargoedAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T15:12:55Zoai:ri.conicet.gov.ar:11336/65081instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 15:12:55.717CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Structural and magnetic properties of nanocrystalline Bi1-xLaxFeO3 (0.0 ≤ x ≤ 0.4) synthesized by a mechanochemical route
title Structural and magnetic properties of nanocrystalline Bi1-xLaxFeO3 (0.0 ≤ x ≤ 0.4) synthesized by a mechanochemical route
spellingShingle Structural and magnetic properties of nanocrystalline Bi1-xLaxFeO3 (0.0 ≤ x ≤ 0.4) synthesized by a mechanochemical route
Cristobal, Adrian Alberto
Mechanochemistry
Multiferroics
Bi1-xLaxFe2O4
title_short Structural and magnetic properties of nanocrystalline Bi1-xLaxFeO3 (0.0 ≤ x ≤ 0.4) synthesized by a mechanochemical route
title_full Structural and magnetic properties of nanocrystalline Bi1-xLaxFeO3 (0.0 ≤ x ≤ 0.4) synthesized by a mechanochemical route
title_fullStr Structural and magnetic properties of nanocrystalline Bi1-xLaxFeO3 (0.0 ≤ x ≤ 0.4) synthesized by a mechanochemical route
title_full_unstemmed Structural and magnetic properties of nanocrystalline Bi1-xLaxFeO3 (0.0 ≤ x ≤ 0.4) synthesized by a mechanochemical route
title_sort Structural and magnetic properties of nanocrystalline Bi1-xLaxFeO3 (0.0 ≤ x ≤ 0.4) synthesized by a mechanochemical route
dc.creator.none.fl_str_mv Cristobal, Adrian Alberto
Ramos, Cinthia Paula
Conconi, María Susana
Bercoff, Paula Gabriela
Botta, Pablo Martín
author Cristobal, Adrian Alberto
author_facet Cristobal, Adrian Alberto
Ramos, Cinthia Paula
Conconi, María Susana
Bercoff, Paula Gabriela
Botta, Pablo Martín
author_role author
author2 Ramos, Cinthia Paula
Conconi, María Susana
Bercoff, Paula Gabriela
Botta, Pablo Martín
author2_role author
author
author
author
dc.subject.none.fl_str_mv Mechanochemistry
Multiferroics
Bi1-xLaxFe2O4
topic Mechanochemistry
Multiferroics
Bi1-xLaxFe2O4
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Bi1-xLaxFeO3 (0.0 ≤ x ≤ 0.4) powders were prepared by means of a solid acid-base reaction induced by mechanochemical energy. Bi, La and Fe chlorides were high-energy ball-milled with NaOH, yielding a mixture of Bi1-xLaxFeO3 and NaCl. After heating and washing, nanoparticles of Bi1-xLaxFeO3 were obtained as a main product, with low contents of secondary phases. Structural characterization was performed by X-ray diffraction (Rietveld refinement) and Raman spectroscopy. The hyperfine magnetic behavior was analyzed by means of Mössbauer spectroscopy and the microstructure of the particles was evaluated by transmission electron microscopy. Differential scanning calorimetry was employed to investigate the thermal behavior of the samples and magnetic measurements at room temperature were also carried out. Crystal structure transitions as a function of composition were identified. Moreover, an intricate magnetic behavior was observed, which was explained on the basis of the concomitant contribution of two different canting levels of the antiparallel spins.
Fil: Cristobal, Adrian Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Ramos, Cinthia Paula. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes. Gerencia de Investigación y Aplicaciones; Argentina
Fil: Conconi, María Susana. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina
Fil: Bercoff, Paula Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina
Fil: Botta, Pablo Martín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
description Bi1-xLaxFeO3 (0.0 ≤ x ≤ 0.4) powders were prepared by means of a solid acid-base reaction induced by mechanochemical energy. Bi, La and Fe chlorides were high-energy ball-milled with NaOH, yielding a mixture of Bi1-xLaxFeO3 and NaCl. After heating and washing, nanoparticles of Bi1-xLaxFeO3 were obtained as a main product, with low contents of secondary phases. Structural characterization was performed by X-ray diffraction (Rietveld refinement) and Raman spectroscopy. The hyperfine magnetic behavior was analyzed by means of Mössbauer spectroscopy and the microstructure of the particles was evaluated by transmission electron microscopy. Differential scanning calorimetry was employed to investigate the thermal behavior of the samples and magnetic measurements at room temperature were also carried out. Crystal structure transitions as a function of composition were identified. Moreover, an intricate magnetic behavior was observed, which was explained on the basis of the concomitant contribution of two different canting levels of the antiparallel spins.
publishDate 2017
dc.date.none.fl_str_mv 2017-11
info:eu-repo/date/embargoEnd/2019-12-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/65081
Cristobal, Adrian Alberto; Ramos, Cinthia Paula; Conconi, María Susana; Bercoff, Paula Gabriela; Botta, Pablo Martín; Structural and magnetic properties of nanocrystalline Bi1-xLaxFeO3 (0.0 ≤ x ≤ 0.4) synthesized by a mechanochemical route; Pergamon-Elsevier Science Ltd; Materials Research Bulletin; 95; 11-2017; 292-299
0025-5408
CONICET Digital
CONICET
url http://hdl.handle.net/11336/65081
identifier_str_mv Cristobal, Adrian Alberto; Ramos, Cinthia Paula; Conconi, María Susana; Bercoff, Paula Gabriela; Botta, Pablo Martín; Structural and magnetic properties of nanocrystalline Bi1-xLaxFeO3 (0.0 ≤ x ≤ 0.4) synthesized by a mechanochemical route; Pergamon-Elsevier Science Ltd; Materials Research Bulletin; 95; 11-2017; 292-299
0025-5408
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0025540816324023
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.materresbull.2017.07.035
dc.rights.none.fl_str_mv info:eu-repo/semantics/embargoedAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv embargoedAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.22299

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