Single stage H2 production, purification and heat supply by means of sorption-enhanced steam reforming of glycerol. A thermodynamic analysis

Autores
Wess, Robert J.; Nores Pondal, Federico Jose; Laborde, Miguel Ángel; Giunta, Pablo Daniel
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The effect of CO2 removal with CaO in the production and purification of fuel cell-grade H2 by glycerol steam reforming is studied from a thermodynamic point of view. Results obtained with the non-stoichiometric method show that CaO enables some improvements to the conventional steam reforming since four simultaneous processes take place at the same stage: H2 production, CO2 separation, CO elimination and heat supply: by separating the CO2 from the gaseous mixture, CaO also shifts the equilibrium towards the production of H2 compared to conventional reforming, and the operating temperature is lowered with respect to conventional steam reforming. The removal of CO2 not only enables higher H2 purity (close to 100% on dry basis) but reduces the amounts of CO as well. For temperatures below ca. 750K, a level lower than 20ppm (on dry basis) can be reached, thus avoiding the need of a purification stage. Since the reaction of CaO with CO2 is exothermic, the heat is supplied within the reactor. Finally, it was found that the system behavior was strongly dependent on the presence of Ca(OH)2.This four-in-one process can be a way of enhancing the efficiency of the overall system of production-purification of H2.
Fil: Wess, Robert J.. Institute of Chemical Process Engineering; Alemania
Fil: Nores Pondal, Federico Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Tecnologías del Hidrogeno y Energias Sostenibles. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías del Hidrogeno y Energias Sostenibles; Argentina
Fil: Laborde, Miguel Ángel. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Tecnologías del Hidrogeno y Energias Sostenibles. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías del Hidrogeno y Energias Sostenibles; Argentina
Fil: Giunta, Pablo Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Tecnologías del Hidrogeno y Energias Sostenibles. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías del Hidrogeno y Energias Sostenibles; Argentina
Materia
Glycerol Steam Reforming
H2 Production
Non-Stoichiometric Method
Pem Fuel Cell
Purification
Sorption-Enhanced Process
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/50065
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/50065
network_acronym_str CONICETDig
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network_name_str CONICET Digital (CONICET)
spelling Single stage H2 production, purification and heat supply by means of sorption-enhanced steam reforming of glycerol. A thermodynamic analysisWess, Robert J.Nores Pondal, Federico JoseLaborde, Miguel ÁngelGiunta, Pablo DanielGlycerol Steam ReformingH2 ProductionNon-Stoichiometric MethodPem Fuel CellPurificationSorption-Enhanced Processhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The effect of CO2 removal with CaO in the production and purification of fuel cell-grade H2 by glycerol steam reforming is studied from a thermodynamic point of view. Results obtained with the non-stoichiometric method show that CaO enables some improvements to the conventional steam reforming since four simultaneous processes take place at the same stage: H2 production, CO2 separation, CO elimination and heat supply: by separating the CO2 from the gaseous mixture, CaO also shifts the equilibrium towards the production of H2 compared to conventional reforming, and the operating temperature is lowered with respect to conventional steam reforming. The removal of CO2 not only enables higher H2 purity (close to 100% on dry basis) but reduces the amounts of CO as well. For temperatures below ca. 750K, a level lower than 20ppm (on dry basis) can be reached, thus avoiding the need of a purification stage. Since the reaction of CaO with CO2 is exothermic, the heat is supplied within the reactor. Finally, it was found that the system behavior was strongly dependent on the presence of Ca(OH)2.This four-in-one process can be a way of enhancing the efficiency of the overall system of production-purification of H2.Fil: Wess, Robert J.. Institute of Chemical Process Engineering; AlemaniaFil: Nores Pondal, Federico Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Tecnologías del Hidrogeno y Energias Sostenibles. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías del Hidrogeno y Energias Sostenibles; ArgentinaFil: Laborde, Miguel Ángel. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Tecnologías del Hidrogeno y Energias Sostenibles. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías del Hidrogeno y Energias Sostenibles; ArgentinaFil: Giunta, Pablo Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Tecnologías del Hidrogeno y Energias Sostenibles. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías del Hidrogeno y Energias Sostenibles; ArgentinaPergamon-Elsevier Science Ltd2015-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/50065Wess, Robert J. ; Nores Pondal, Federico Jose; Laborde, Miguel Ángel; Giunta, Pablo Daniel; Single stage H2 production, purification and heat supply by means of sorption-enhanced steam reforming of glycerol. A thermodynamic analysis; Pergamon-Elsevier Science Ltd; Chemical Engineering Science; 134; 9-2015; 86-950009-2509CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.ces.2015.04.002info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0009250915002407info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:40:49Zoai:ri.conicet.gov.ar:11336/50065instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:40:49.741CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Single stage H2 production, purification and heat supply by means of sorption-enhanced steam reforming of glycerol. A thermodynamic analysis
title Single stage H2 production, purification and heat supply by means of sorption-enhanced steam reforming of glycerol. A thermodynamic analysis
spellingShingle Single stage H2 production, purification and heat supply by means of sorption-enhanced steam reforming of glycerol. A thermodynamic analysis
Wess, Robert J.
Glycerol Steam Reforming
H2 Production
Non-Stoichiometric Method
Pem Fuel Cell
Purification
Sorption-Enhanced Process
title_short Single stage H2 production, purification and heat supply by means of sorption-enhanced steam reforming of glycerol. A thermodynamic analysis
title_full Single stage H2 production, purification and heat supply by means of sorption-enhanced steam reforming of glycerol. A thermodynamic analysis
title_fullStr Single stage H2 production, purification and heat supply by means of sorption-enhanced steam reforming of glycerol. A thermodynamic analysis
title_full_unstemmed Single stage H2 production, purification and heat supply by means of sorption-enhanced steam reforming of glycerol. A thermodynamic analysis
title_sort Single stage H2 production, purification and heat supply by means of sorption-enhanced steam reforming of glycerol. A thermodynamic analysis
dc.creator.none.fl_str_mv Wess, Robert J.
Nores Pondal, Federico Jose
Laborde, Miguel Ángel
Giunta, Pablo Daniel
author Wess, Robert J.
author_facet Wess, Robert J.
Nores Pondal, Federico Jose
Laborde, Miguel Ángel
Giunta, Pablo Daniel
author_role author
author2 Nores Pondal, Federico Jose
Laborde, Miguel Ángel
Giunta, Pablo Daniel
author2_role author
author
author
dc.subject.none.fl_str_mv Glycerol Steam Reforming
H2 Production
Non-Stoichiometric Method
Pem Fuel Cell
Purification
Sorption-Enhanced Process
topic Glycerol Steam Reforming
H2 Production
Non-Stoichiometric Method
Pem Fuel Cell
Purification
Sorption-Enhanced Process
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The effect of CO2 removal with CaO in the production and purification of fuel cell-grade H2 by glycerol steam reforming is studied from a thermodynamic point of view. Results obtained with the non-stoichiometric method show that CaO enables some improvements to the conventional steam reforming since four simultaneous processes take place at the same stage: H2 production, CO2 separation, CO elimination and heat supply: by separating the CO2 from the gaseous mixture, CaO also shifts the equilibrium towards the production of H2 compared to conventional reforming, and the operating temperature is lowered with respect to conventional steam reforming. The removal of CO2 not only enables higher H2 purity (close to 100% on dry basis) but reduces the amounts of CO as well. For temperatures below ca. 750K, a level lower than 20ppm (on dry basis) can be reached, thus avoiding the need of a purification stage. Since the reaction of CaO with CO2 is exothermic, the heat is supplied within the reactor. Finally, it was found that the system behavior was strongly dependent on the presence of Ca(OH)2.This four-in-one process can be a way of enhancing the efficiency of the overall system of production-purification of H2.
Fil: Wess, Robert J.. Institute of Chemical Process Engineering; Alemania
Fil: Nores Pondal, Federico Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Tecnologías del Hidrogeno y Energias Sostenibles. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías del Hidrogeno y Energias Sostenibles; Argentina
Fil: Laborde, Miguel Ángel. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Tecnologías del Hidrogeno y Energias Sostenibles. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías del Hidrogeno y Energias Sostenibles; Argentina
Fil: Giunta, Pablo Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Tecnologías del Hidrogeno y Energias Sostenibles. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías del Hidrogeno y Energias Sostenibles; Argentina
description The effect of CO2 removal with CaO in the production and purification of fuel cell-grade H2 by glycerol steam reforming is studied from a thermodynamic point of view. Results obtained with the non-stoichiometric method show that CaO enables some improvements to the conventional steam reforming since four simultaneous processes take place at the same stage: H2 production, CO2 separation, CO elimination and heat supply: by separating the CO2 from the gaseous mixture, CaO also shifts the equilibrium towards the production of H2 compared to conventional reforming, and the operating temperature is lowered with respect to conventional steam reforming. The removal of CO2 not only enables higher H2 purity (close to 100% on dry basis) but reduces the amounts of CO as well. For temperatures below ca. 750K, a level lower than 20ppm (on dry basis) can be reached, thus avoiding the need of a purification stage. Since the reaction of CaO with CO2 is exothermic, the heat is supplied within the reactor. Finally, it was found that the system behavior was strongly dependent on the presence of Ca(OH)2.This four-in-one process can be a way of enhancing the efficiency of the overall system of production-purification of H2.
publishDate 2015
dc.date.none.fl_str_mv 2015-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/50065
Wess, Robert J. ; Nores Pondal, Federico Jose; Laborde, Miguel Ángel; Giunta, Pablo Daniel; Single stage H2 production, purification and heat supply by means of sorption-enhanced steam reforming of glycerol. A thermodynamic analysis; Pergamon-Elsevier Science Ltd; Chemical Engineering Science; 134; 9-2015; 86-95
0009-2509
CONICET Digital
CONICET
url http://hdl.handle.net/11336/50065
identifier_str_mv Wess, Robert J. ; Nores Pondal, Federico Jose; Laborde, Miguel Ángel; Giunta, Pablo Daniel; Single stage H2 production, purification and heat supply by means of sorption-enhanced steam reforming of glycerol. A thermodynamic analysis; Pergamon-Elsevier Science Ltd; Chemical Engineering Science; 134; 9-2015; 86-95
0009-2509
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ces.2015.04.002
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0009250915002407
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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