Thermodynamic analysis of Glycerol steam reforming

Autores
Dieuzeide, María Laura; Amadeo, Norma Elvira
Año de publicación
2010
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A thermodynamic analysis of steam reforming of glycerol using the stoichiometric method has been performed. Since the aim of this work is to study product distribution and coke formation in equilibrium, two different models have been proposed: (a) CO as primary product and (b) CO2 as primary product. Moreover, substantial information regarding the behavior of the different reactions could be acquired. Product distribution at equilibrium has been investigated in a broad range of conditions: temperature (600-1200 K), water-to-glycerol feed molar ratio (0:1-10:1), and pressure (1-9 atm). Glycerol conversion results completely over the whole range of the mentioned conditions. Consequently, product distribution at equilibrium is determined by water gas shift (WGS) and methanation or methane steam reforming reactions. Finally, high temperatures and a high water-to-glycerol feed molar ratio favor hydrogen production and decrease both methane and coke.
Fil: Dieuzeide, María Laura. Universidad de Buenos Aires. Facultad de Ingeniería. Departamento de Ingeniería Química. Laboratorio de Procesos Catalíticos; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Amadeo, Norma Elvira. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Facultad de Ingeniería. Departamento de Ingeniería Química. Laboratorio de Procesos Catalíticos; Argentina
Materia
GLYCEROL
STEAM REFORMING
THERMODYNAMIC ANALYSIS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/186463
Acceder
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network_acronym_str CONICETDig
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network_name_str CONICET Digital (CONICET)
spelling Thermodynamic analysis of Glycerol steam reformingDieuzeide, María LauraAmadeo, Norma ElviraGLYCEROLSTEAM REFORMINGTHERMODYNAMIC ANALYSIShttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2A thermodynamic analysis of steam reforming of glycerol using the stoichiometric method has been performed. Since the aim of this work is to study product distribution and coke formation in equilibrium, two different models have been proposed: (a) CO as primary product and (b) CO2 as primary product. Moreover, substantial information regarding the behavior of the different reactions could be acquired. Product distribution at equilibrium has been investigated in a broad range of conditions: temperature (600-1200 K), water-to-glycerol feed molar ratio (0:1-10:1), and pressure (1-9 atm). Glycerol conversion results completely over the whole range of the mentioned conditions. Consequently, product distribution at equilibrium is determined by water gas shift (WGS) and methanation or methane steam reforming reactions. Finally, high temperatures and a high water-to-glycerol feed molar ratio favor hydrogen production and decrease both methane and coke.Fil: Dieuzeide, María Laura. Universidad de Buenos Aires. Facultad de Ingeniería. Departamento de Ingeniería Química. Laboratorio de Procesos Catalíticos; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Amadeo, Norma Elvira. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Facultad de Ingeniería. Departamento de Ingeniería Química. Laboratorio de Procesos Catalíticos; ArgentinaWiley VCH Verlag2010-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/186463Dieuzeide, María Laura; Amadeo, Norma Elvira; Thermodynamic analysis of Glycerol steam reforming; Wiley VCH Verlag; Chemical Enginnering Technology; 33; 1; 1-2010; 89-961521-41250930-7516CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/ceat.200900260/abstractinfo:eu-repo/semantics/altIdentifier/doi/10.1002/ceat.200900260info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:10:02Zoai:ri.conicet.gov.ar:11336/186463instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:10:02.329CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Thermodynamic analysis of Glycerol steam reforming
title Thermodynamic analysis of Glycerol steam reforming
spellingShingle Thermodynamic analysis of Glycerol steam reforming
Dieuzeide, María Laura
GLYCEROL
STEAM REFORMING
THERMODYNAMIC ANALYSIS
title_short Thermodynamic analysis of Glycerol steam reforming
title_full Thermodynamic analysis of Glycerol steam reforming
title_fullStr Thermodynamic analysis of Glycerol steam reforming
title_full_unstemmed Thermodynamic analysis of Glycerol steam reforming
title_sort Thermodynamic analysis of Glycerol steam reforming
dc.creator.none.fl_str_mv Dieuzeide, María Laura
Amadeo, Norma Elvira
author Dieuzeide, María Laura
author_facet Dieuzeide, María Laura
Amadeo, Norma Elvira
author_role author
author2 Amadeo, Norma Elvira
author2_role author
dc.subject.none.fl_str_mv GLYCEROL
STEAM REFORMING
THERMODYNAMIC ANALYSIS
topic GLYCEROL
STEAM REFORMING
THERMODYNAMIC ANALYSIS
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv A thermodynamic analysis of steam reforming of glycerol using the stoichiometric method has been performed. Since the aim of this work is to study product distribution and coke formation in equilibrium, two different models have been proposed: (a) CO as primary product and (b) CO2 as primary product. Moreover, substantial information regarding the behavior of the different reactions could be acquired. Product distribution at equilibrium has been investigated in a broad range of conditions: temperature (600-1200 K), water-to-glycerol feed molar ratio (0:1-10:1), and pressure (1-9 atm). Glycerol conversion results completely over the whole range of the mentioned conditions. Consequently, product distribution at equilibrium is determined by water gas shift (WGS) and methanation or methane steam reforming reactions. Finally, high temperatures and a high water-to-glycerol feed molar ratio favor hydrogen production and decrease both methane and coke.
Fil: Dieuzeide, María Laura. Universidad de Buenos Aires. Facultad de Ingeniería. Departamento de Ingeniería Química. Laboratorio de Procesos Catalíticos; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Amadeo, Norma Elvira. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Facultad de Ingeniería. Departamento de Ingeniería Química. Laboratorio de Procesos Catalíticos; Argentina
description A thermodynamic analysis of steam reforming of glycerol using the stoichiometric method has been performed. Since the aim of this work is to study product distribution and coke formation in equilibrium, two different models have been proposed: (a) CO as primary product and (b) CO2 as primary product. Moreover, substantial information regarding the behavior of the different reactions could be acquired. Product distribution at equilibrium has been investigated in a broad range of conditions: temperature (600-1200 K), water-to-glycerol feed molar ratio (0:1-10:1), and pressure (1-9 atm). Glycerol conversion results completely over the whole range of the mentioned conditions. Consequently, product distribution at equilibrium is determined by water gas shift (WGS) and methanation or methane steam reforming reactions. Finally, high temperatures and a high water-to-glycerol feed molar ratio favor hydrogen production and decrease both methane and coke.
publishDate 2010
dc.date.none.fl_str_mv 2010-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/186463
Dieuzeide, María Laura; Amadeo, Norma Elvira; Thermodynamic analysis of Glycerol steam reforming; Wiley VCH Verlag; Chemical Enginnering Technology; 33; 1; 1-2010; 89-96
1521-4125
0930-7516
CONICET Digital
CONICET
url http://hdl.handle.net/11336/186463
identifier_str_mv Dieuzeide, María Laura; Amadeo, Norma Elvira; Thermodynamic analysis of Glycerol steam reforming; Wiley VCH Verlag; Chemical Enginnering Technology; 33; 1; 1-2010; 89-96
1521-4125
0930-7516
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/ceat.200900260/abstract
info:eu-repo/semantics/altIdentifier/doi/10.1002/ceat.200900260
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley VCH Verlag
publisher.none.fl_str_mv Wiley VCH Verlag
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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