Influence of Time and Temperature on the Regeneration of PtReIn/Al2O3 Naphtha Reforming Catalysts

Autores
Vicerich, Maria Ana; Oportus, Marcelo; Benitez, Viviana Monica; Reyes, Patricio; Pieck, Carlos Luis
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The influence of temperature (450–500 °C) and time (1–4 h) of coke combustion on the catalytic properties of PtReIn/Al2O3 were studied. The results of the cyclohexane dehydrogenation and cyclopentane hydrogenolysis reactions show that the regeneration treatment with diluted oxygen can fully recover the activity of the metal function despite some observed segregation of Re and In. In the case of the n-heptane reforming reaction, the regenerated catalysts had lower activity and stability than the fresh ones. The experiments at high temperature in air showed that In prevents the sintering of Pt and Re but at 650 °C a segregation of Re from the Pt–Re phase occurs.
Fil: Vicerich, Maria Ana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Oportus, Marcelo. Universidad de Concepción; Chile
Fil: Benitez, Viviana Monica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Reyes, Patricio. Universidad de Concepción; Chile
Fil: Pieck, Carlos Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Materia
Ptrein/Al2o3
Naphtha Reforming
Regeneration
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/31063
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Influence of Time and Temperature on the Regeneration of PtReIn/Al2O3 Naphtha Reforming CatalystsVicerich, Maria AnaOportus, MarceloBenitez, Viviana MonicaReyes, PatricioPieck, Carlos LuisPtrein/Al2o3Naphtha ReformingRegenerationhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The influence of temperature (450–500 °C) and time (1–4 h) of coke combustion on the catalytic properties of PtReIn/Al2O3 were studied. The results of the cyclohexane dehydrogenation and cyclopentane hydrogenolysis reactions show that the regeneration treatment with diluted oxygen can fully recover the activity of the metal function despite some observed segregation of Re and In. In the case of the n-heptane reforming reaction, the regenerated catalysts had lower activity and stability than the fresh ones. The experiments at high temperature in air showed that In prevents the sintering of Pt and Re but at 650 °C a segregation of Re from the Pt–Re phase occurs.Fil: Vicerich, Maria Ana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Oportus, Marcelo. Universidad de Concepción; ChileFil: Benitez, Viviana Monica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Reyes, Patricio. Universidad de Concepción; ChileFil: Pieck, Carlos Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaSpringer2014-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/31063Pieck, Carlos Luis; Reyes, Patricio; Benitez, Viviana Monica; Oportus, Marcelo; Vicerich, Maria Ana; Influence of Time and Temperature on the Regeneration of PtReIn/Al2O3 Naphtha Reforming Catalysts; Springer; Catalysis Letters; 144; 7; 6-2014; 1178-11871011-372X1572-879XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1007/s10562-014-1282-9info:eu-repo/semantics/altIdentifier/url/https://link.springer.com/article/10.1007/s10562-014-1282-9info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:44:08Zoai:ri.conicet.gov.ar:11336/31063instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:44:08.879CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Influence of Time and Temperature on the Regeneration of PtReIn/Al2O3 Naphtha Reforming Catalysts
title Influence of Time and Temperature on the Regeneration of PtReIn/Al2O3 Naphtha Reforming Catalysts
spellingShingle Influence of Time and Temperature on the Regeneration of PtReIn/Al2O3 Naphtha Reforming Catalysts
Vicerich, Maria Ana
Ptrein/Al2o3
Naphtha Reforming
Regeneration
title_short Influence of Time and Temperature on the Regeneration of PtReIn/Al2O3 Naphtha Reforming Catalysts
title_full Influence of Time and Temperature on the Regeneration of PtReIn/Al2O3 Naphtha Reforming Catalysts
title_fullStr Influence of Time and Temperature on the Regeneration of PtReIn/Al2O3 Naphtha Reforming Catalysts
title_full_unstemmed Influence of Time and Temperature on the Regeneration of PtReIn/Al2O3 Naphtha Reforming Catalysts
title_sort Influence of Time and Temperature on the Regeneration of PtReIn/Al2O3 Naphtha Reforming Catalysts
dc.creator.none.fl_str_mv Vicerich, Maria Ana
Oportus, Marcelo
Benitez, Viviana Monica
Reyes, Patricio
Pieck, Carlos Luis
author Vicerich, Maria Ana
author_facet Vicerich, Maria Ana
Oportus, Marcelo
Benitez, Viviana Monica
Reyes, Patricio
Pieck, Carlos Luis
author_role author
author2 Oportus, Marcelo
Benitez, Viviana Monica
Reyes, Patricio
Pieck, Carlos Luis
author2_role author
author
author
author
dc.subject.none.fl_str_mv Ptrein/Al2o3
Naphtha Reforming
Regeneration
topic Ptrein/Al2o3
Naphtha Reforming
Regeneration
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The influence of temperature (450–500 °C) and time (1–4 h) of coke combustion on the catalytic properties of PtReIn/Al2O3 were studied. The results of the cyclohexane dehydrogenation and cyclopentane hydrogenolysis reactions show that the regeneration treatment with diluted oxygen can fully recover the activity of the metal function despite some observed segregation of Re and In. In the case of the n-heptane reforming reaction, the regenerated catalysts had lower activity and stability than the fresh ones. The experiments at high temperature in air showed that In prevents the sintering of Pt and Re but at 650 °C a segregation of Re from the Pt–Re phase occurs.
Fil: Vicerich, Maria Ana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Oportus, Marcelo. Universidad de Concepción; Chile
Fil: Benitez, Viviana Monica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Reyes, Patricio. Universidad de Concepción; Chile
Fil: Pieck, Carlos Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
description The influence of temperature (450–500 °C) and time (1–4 h) of coke combustion on the catalytic properties of PtReIn/Al2O3 were studied. The results of the cyclohexane dehydrogenation and cyclopentane hydrogenolysis reactions show that the regeneration treatment with diluted oxygen can fully recover the activity of the metal function despite some observed segregation of Re and In. In the case of the n-heptane reforming reaction, the regenerated catalysts had lower activity and stability than the fresh ones. The experiments at high temperature in air showed that In prevents the sintering of Pt and Re but at 650 °C a segregation of Re from the Pt–Re phase occurs.
publishDate 2014
dc.date.none.fl_str_mv 2014-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/31063
Pieck, Carlos Luis; Reyes, Patricio; Benitez, Viviana Monica; Oportus, Marcelo; Vicerich, Maria Ana; Influence of Time and Temperature on the Regeneration of PtReIn/Al2O3 Naphtha Reforming Catalysts; Springer; Catalysis Letters; 144; 7; 6-2014; 1178-1187
1011-372X
1572-879X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/31063
identifier_str_mv Pieck, Carlos Luis; Reyes, Patricio; Benitez, Viviana Monica; Oportus, Marcelo; Vicerich, Maria Ana; Influence of Time and Temperature on the Regeneration of PtReIn/Al2O3 Naphtha Reforming Catalysts; Springer; Catalysis Letters; 144; 7; 6-2014; 1178-1187
1011-372X
1572-879X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1007/s10562-014-1282-9
info:eu-repo/semantics/altIdentifier/url/https://link.springer.com/article/10.1007/s10562-014-1282-9
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Springer
publisher.none.fl_str_mv Springer
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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