O2 and O3 regeneration of PtReSn/Al2O 3 and PtReGe/Al2O3 naphtha reforming catalysts prepared by catalytic reduction

Autores
D'Ippolito, Silvana A.; Especel, Catherine; Epron, Florence; Marécot, Patrice; Pieck, Carlos Luis
Año de publicación
2010
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The deactivation and regeneration of naphtha reforming PtReGe/Al 2O3 and PtReSn/Al2O3 catalysts prepared by catalytic reduction were studied. The extent and nature of coke deposition as determined by TPO were related to catalyst properties such as dispersion, acidity and Cl content. The PtReSn catalyst was the most resistant to coke deactivation. Regeneration was performed by calcination in oxygen at 450 °C or ozone at 125 °C at variable regeneration times. Regenerated catalysts were evaluated by cyclopentane hydrogenolysis, cyclohexane dehydrogenation and n-heptane reaction tests. Regeneration by oxygen burning-off was the most effective for decoking. However, oxygen combustion produced more segregation of the metal function than ozone regeneration. With the regeneration conditions used in this work, the original acidity of the catalysts cannot be recovered.
Fil: D'Ippolito, Silvana A.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Especel, Catherine. Université de Poitiers; Francia
Fil: Epron, Florence. Université de Poitiers; Francia
Fil: Marécot, Patrice. Université de Poitiers; Francia
Fil: Pieck, Carlos Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Materia
Naphtha
Ptrege/Al2o 3
Ptresn/Al2o3
Reforming
Regeneration
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/54037
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling O2 and O3 regeneration of PtReSn/Al2O 3 and PtReGe/Al2O3 naphtha reforming catalysts prepared by catalytic reductionD'Ippolito, Silvana A.Especel, CatherineEpron, FlorenceMarécot, PatricePieck, Carlos LuisNaphthaPtrege/Al2o 3Ptresn/Al2o3ReformingRegenerationhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The deactivation and regeneration of naphtha reforming PtReGe/Al 2O3 and PtReSn/Al2O3 catalysts prepared by catalytic reduction were studied. The extent and nature of coke deposition as determined by TPO were related to catalyst properties such as dispersion, acidity and Cl content. The PtReSn catalyst was the most resistant to coke deactivation. Regeneration was performed by calcination in oxygen at 450 °C or ozone at 125 °C at variable regeneration times. Regenerated catalysts were evaluated by cyclopentane hydrogenolysis, cyclohexane dehydrogenation and n-heptane reaction tests. Regeneration by oxygen burning-off was the most effective for decoking. However, oxygen combustion produced more segregation of the metal function than ozone regeneration. With the regeneration conditions used in this work, the original acidity of the catalysts cannot be recovered.Fil: D'Ippolito, Silvana A.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Especel, Catherine. Université de Poitiers; FranciaFil: Epron, Florence. Université de Poitiers; FranciaFil: Marécot, Patrice. Université de Poitiers; FranciaFil: Pieck, Carlos Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaElsevier Science2010-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/54037D'Ippolito, Silvana A.; Especel, Catherine; Epron, Florence; Marécot, Patrice; Pieck, Carlos Luis; O2 and O3 regeneration of PtReSn/Al2O 3 and PtReGe/Al2O3 naphtha reforming catalysts prepared by catalytic reduction; Elsevier Science; Applied Catalysis A: General; 388; 1-2; 11-2010; 272-2770926-860XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/journal/0926860Xinfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2010.09.001info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:58:50Zoai:ri.conicet.gov.ar:11336/54037instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:58:50.478CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv O2 and O3 regeneration of PtReSn/Al2O 3 and PtReGe/Al2O3 naphtha reforming catalysts prepared by catalytic reduction
title O2 and O3 regeneration of PtReSn/Al2O 3 and PtReGe/Al2O3 naphtha reforming catalysts prepared by catalytic reduction
spellingShingle O2 and O3 regeneration of PtReSn/Al2O 3 and PtReGe/Al2O3 naphtha reforming catalysts prepared by catalytic reduction
D'Ippolito, Silvana A.
Naphtha
Ptrege/Al2o 3
Ptresn/Al2o3
Reforming
Regeneration
title_short O2 and O3 regeneration of PtReSn/Al2O 3 and PtReGe/Al2O3 naphtha reforming catalysts prepared by catalytic reduction
title_full O2 and O3 regeneration of PtReSn/Al2O 3 and PtReGe/Al2O3 naphtha reforming catalysts prepared by catalytic reduction
title_fullStr O2 and O3 regeneration of PtReSn/Al2O 3 and PtReGe/Al2O3 naphtha reforming catalysts prepared by catalytic reduction
title_full_unstemmed O2 and O3 regeneration of PtReSn/Al2O 3 and PtReGe/Al2O3 naphtha reforming catalysts prepared by catalytic reduction
title_sort O2 and O3 regeneration of PtReSn/Al2O 3 and PtReGe/Al2O3 naphtha reforming catalysts prepared by catalytic reduction
dc.creator.none.fl_str_mv D'Ippolito, Silvana A.
Especel, Catherine
Epron, Florence
Marécot, Patrice
Pieck, Carlos Luis
author D'Ippolito, Silvana A.
author_facet D'Ippolito, Silvana A.
Especel, Catherine
Epron, Florence
Marécot, Patrice
Pieck, Carlos Luis
author_role author
author2 Especel, Catherine
Epron, Florence
Marécot, Patrice
Pieck, Carlos Luis
author2_role author
author
author
author
dc.subject.none.fl_str_mv Naphtha
Ptrege/Al2o 3
Ptresn/Al2o3
Reforming
Regeneration
topic Naphtha
Ptrege/Al2o 3
Ptresn/Al2o3
Reforming
Regeneration
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The deactivation and regeneration of naphtha reforming PtReGe/Al 2O3 and PtReSn/Al2O3 catalysts prepared by catalytic reduction were studied. The extent and nature of coke deposition as determined by TPO were related to catalyst properties such as dispersion, acidity and Cl content. The PtReSn catalyst was the most resistant to coke deactivation. Regeneration was performed by calcination in oxygen at 450 °C or ozone at 125 °C at variable regeneration times. Regenerated catalysts were evaluated by cyclopentane hydrogenolysis, cyclohexane dehydrogenation and n-heptane reaction tests. Regeneration by oxygen burning-off was the most effective for decoking. However, oxygen combustion produced more segregation of the metal function than ozone regeneration. With the regeneration conditions used in this work, the original acidity of the catalysts cannot be recovered.
Fil: D'Ippolito, Silvana A.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Especel, Catherine. Université de Poitiers; Francia
Fil: Epron, Florence. Université de Poitiers; Francia
Fil: Marécot, Patrice. Université de Poitiers; Francia
Fil: Pieck, Carlos Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
description The deactivation and regeneration of naphtha reforming PtReGe/Al 2O3 and PtReSn/Al2O3 catalysts prepared by catalytic reduction were studied. The extent and nature of coke deposition as determined by TPO were related to catalyst properties such as dispersion, acidity and Cl content. The PtReSn catalyst was the most resistant to coke deactivation. Regeneration was performed by calcination in oxygen at 450 °C or ozone at 125 °C at variable regeneration times. Regenerated catalysts were evaluated by cyclopentane hydrogenolysis, cyclohexane dehydrogenation and n-heptane reaction tests. Regeneration by oxygen burning-off was the most effective for decoking. However, oxygen combustion produced more segregation of the metal function than ozone regeneration. With the regeneration conditions used in this work, the original acidity of the catalysts cannot be recovered.
publishDate 2010
dc.date.none.fl_str_mv 2010-11
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/54037
D'Ippolito, Silvana A.; Especel, Catherine; Epron, Florence; Marécot, Patrice; Pieck, Carlos Luis; O2 and O3 regeneration of PtReSn/Al2O 3 and PtReGe/Al2O3 naphtha reforming catalysts prepared by catalytic reduction; Elsevier Science; Applied Catalysis A: General; 388; 1-2; 11-2010; 272-277
0926-860X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/54037
identifier_str_mv D'Ippolito, Silvana A.; Especel, Catherine; Epron, Florence; Marécot, Patrice; Pieck, Carlos Luis; O2 and O3 regeneration of PtReSn/Al2O 3 and PtReGe/Al2O3 naphtha reforming catalysts prepared by catalytic reduction; Elsevier Science; Applied Catalysis A: General; 388; 1-2; 11-2010; 272-277
0926-860X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/journal/0926860X
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2010.09.001
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846782304550125568
score 12.982451

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