O2 and O3 regeneration of PtReSn/Al2O 3 and PtReGe/Al2O3 naphtha reforming catalysts prepared by catalytic reduction
- Autores
- D'Ippolito, Silvana A.; Especel, Catherine; Epron, Florence; Marécot, Patrice; Pieck, Carlos Luis
- Año de publicación
- 2010
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The deactivation and regeneration of naphtha reforming PtReGe/Al 2O3 and PtReSn/Al2O3 catalysts prepared by catalytic reduction were studied. The extent and nature of coke deposition as determined by TPO were related to catalyst properties such as dispersion, acidity and Cl content. The PtReSn catalyst was the most resistant to coke deactivation. Regeneration was performed by calcination in oxygen at 450 °C or ozone at 125 °C at variable regeneration times. Regenerated catalysts were evaluated by cyclopentane hydrogenolysis, cyclohexane dehydrogenation and n-heptane reaction tests. Regeneration by oxygen burning-off was the most effective for decoking. However, oxygen combustion produced more segregation of the metal function than ozone regeneration. With the regeneration conditions used in this work, the original acidity of the catalysts cannot be recovered.
Fil: D'Ippolito, Silvana A.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Especel, Catherine. Université de Poitiers; Francia
Fil: Epron, Florence. Université de Poitiers; Francia
Fil: Marécot, Patrice. Université de Poitiers; Francia
Fil: Pieck, Carlos Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina - Materia
-
Naphtha
Ptrege/Al2o 3
Ptresn/Al2o3
Reforming
Regeneration - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/54037
Ver los metadatos del registro completo
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O2 and O3 regeneration of PtReSn/Al2O 3 and PtReGe/Al2O3 naphtha reforming catalysts prepared by catalytic reductionD'Ippolito, Silvana A.Especel, CatherineEpron, FlorenceMarécot, PatricePieck, Carlos LuisNaphthaPtrege/Al2o 3Ptresn/Al2o3ReformingRegenerationhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The deactivation and regeneration of naphtha reforming PtReGe/Al 2O3 and PtReSn/Al2O3 catalysts prepared by catalytic reduction were studied. The extent and nature of coke deposition as determined by TPO were related to catalyst properties such as dispersion, acidity and Cl content. The PtReSn catalyst was the most resistant to coke deactivation. Regeneration was performed by calcination in oxygen at 450 °C or ozone at 125 °C at variable regeneration times. Regenerated catalysts were evaluated by cyclopentane hydrogenolysis, cyclohexane dehydrogenation and n-heptane reaction tests. Regeneration by oxygen burning-off was the most effective for decoking. However, oxygen combustion produced more segregation of the metal function than ozone regeneration. With the regeneration conditions used in this work, the original acidity of the catalysts cannot be recovered.Fil: D'Ippolito, Silvana A.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Especel, Catherine. Université de Poitiers; FranciaFil: Epron, Florence. Université de Poitiers; FranciaFil: Marécot, Patrice. Université de Poitiers; FranciaFil: Pieck, Carlos Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaElsevier Science2010-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/54037D'Ippolito, Silvana A.; Especel, Catherine; Epron, Florence; Marécot, Patrice; Pieck, Carlos Luis; O2 and O3 regeneration of PtReSn/Al2O 3 and PtReGe/Al2O3 naphtha reforming catalysts prepared by catalytic reduction; Elsevier Science; Applied Catalysis A: General; 388; 1-2; 11-2010; 272-2770926-860XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/journal/0926860Xinfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2010.09.001info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:26:07Zoai:ri.conicet.gov.ar:11336/54037instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:26:08.192CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
O2 and O3 regeneration of PtReSn/Al2O 3 and PtReGe/Al2O3 naphtha reforming catalysts prepared by catalytic reduction |
title |
O2 and O3 regeneration of PtReSn/Al2O 3 and PtReGe/Al2O3 naphtha reforming catalysts prepared by catalytic reduction |
spellingShingle |
O2 and O3 regeneration of PtReSn/Al2O 3 and PtReGe/Al2O3 naphtha reforming catalysts prepared by catalytic reduction D'Ippolito, Silvana A. Naphtha Ptrege/Al2o 3 Ptresn/Al2o3 Reforming Regeneration |
title_short |
O2 and O3 regeneration of PtReSn/Al2O 3 and PtReGe/Al2O3 naphtha reforming catalysts prepared by catalytic reduction |
title_full |
O2 and O3 regeneration of PtReSn/Al2O 3 and PtReGe/Al2O3 naphtha reforming catalysts prepared by catalytic reduction |
title_fullStr |
O2 and O3 regeneration of PtReSn/Al2O 3 and PtReGe/Al2O3 naphtha reforming catalysts prepared by catalytic reduction |
title_full_unstemmed |
O2 and O3 regeneration of PtReSn/Al2O 3 and PtReGe/Al2O3 naphtha reforming catalysts prepared by catalytic reduction |
title_sort |
O2 and O3 regeneration of PtReSn/Al2O 3 and PtReGe/Al2O3 naphtha reforming catalysts prepared by catalytic reduction |
dc.creator.none.fl_str_mv |
D'Ippolito, Silvana A. Especel, Catherine Epron, Florence Marécot, Patrice Pieck, Carlos Luis |
author |
D'Ippolito, Silvana A. |
author_facet |
D'Ippolito, Silvana A. Especel, Catherine Epron, Florence Marécot, Patrice Pieck, Carlos Luis |
author_role |
author |
author2 |
Especel, Catherine Epron, Florence Marécot, Patrice Pieck, Carlos Luis |
author2_role |
author author author author |
dc.subject.none.fl_str_mv |
Naphtha Ptrege/Al2o 3 Ptresn/Al2o3 Reforming Regeneration |
topic |
Naphtha Ptrege/Al2o 3 Ptresn/Al2o3 Reforming Regeneration |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
The deactivation and regeneration of naphtha reforming PtReGe/Al 2O3 and PtReSn/Al2O3 catalysts prepared by catalytic reduction were studied. The extent and nature of coke deposition as determined by TPO were related to catalyst properties such as dispersion, acidity and Cl content. The PtReSn catalyst was the most resistant to coke deactivation. Regeneration was performed by calcination in oxygen at 450 °C or ozone at 125 °C at variable regeneration times. Regenerated catalysts were evaluated by cyclopentane hydrogenolysis, cyclohexane dehydrogenation and n-heptane reaction tests. Regeneration by oxygen burning-off was the most effective for decoking. However, oxygen combustion produced more segregation of the metal function than ozone regeneration. With the regeneration conditions used in this work, the original acidity of the catalysts cannot be recovered. Fil: D'Ippolito, Silvana A.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina Fil: Especel, Catherine. Université de Poitiers; Francia Fil: Epron, Florence. Université de Poitiers; Francia Fil: Marécot, Patrice. Université de Poitiers; Francia Fil: Pieck, Carlos Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina |
description |
The deactivation and regeneration of naphtha reforming PtReGe/Al 2O3 and PtReSn/Al2O3 catalysts prepared by catalytic reduction were studied. The extent and nature of coke deposition as determined by TPO were related to catalyst properties such as dispersion, acidity and Cl content. The PtReSn catalyst was the most resistant to coke deactivation. Regeneration was performed by calcination in oxygen at 450 °C or ozone at 125 °C at variable regeneration times. Regenerated catalysts were evaluated by cyclopentane hydrogenolysis, cyclohexane dehydrogenation and n-heptane reaction tests. Regeneration by oxygen burning-off was the most effective for decoking. However, oxygen combustion produced more segregation of the metal function than ozone regeneration. With the regeneration conditions used in this work, the original acidity of the catalysts cannot be recovered. |
publishDate |
2010 |
dc.date.none.fl_str_mv |
2010-11 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/54037 D'Ippolito, Silvana A.; Especel, Catherine; Epron, Florence; Marécot, Patrice; Pieck, Carlos Luis; O2 and O3 regeneration of PtReSn/Al2O 3 and PtReGe/Al2O3 naphtha reforming catalysts prepared by catalytic reduction; Elsevier Science; Applied Catalysis A: General; 388; 1-2; 11-2010; 272-277 0926-860X CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/54037 |
identifier_str_mv |
D'Ippolito, Silvana A.; Especel, Catherine; Epron, Florence; Marécot, Patrice; Pieck, Carlos Luis; O2 and O3 regeneration of PtReSn/Al2O 3 and PtReGe/Al2O3 naphtha reforming catalysts prepared by catalytic reduction; Elsevier Science; Applied Catalysis A: General; 388; 1-2; 11-2010; 272-277 0926-860X CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/journal/0926860X info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2010.09.001 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science |
publisher.none.fl_str_mv |
Elsevier Science |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844614261841592320 |
score |
13.070432 |